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US3941612A Expired / Lapsed US ⏱️ 0.0 years remaining

Cathode composition for electrochemical cell

Assignee: Energy Research and Development Administration ERDA
•
Filing: 1975-03-04
•
Granted: 1976-03-02
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Expires: 1995-03-04
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Abstract

Abstract A high-temperature, secondary electrochemical cell includes a negative electrode containing an alkali metal such as lithium, an electrolyte of molten salt containing ions of that alkali metal and a positive electrode containing a mixture of metallic sulfides. The positive electrode composition is contained within a porous structure that permits permeation of molten electrolyte and includes a mixture of about 5% to 30% by weight Cu2S in FeS.

Inventors

  • 👤 Robert K. Steunenberg
  • 👤 Allan E. Martin
  • 👤 Zygmunt Tomczuk

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-28 15:36
CPC Classifications
H; H01; H01M; H01M10/00; H01M10/36; H01M10/39; H01M10/399; H01M4/00; H01M4/02; H01M4/36; H01M4/58; H01M4/581; Y; Y02; Y02E; Y02E60/00; Y02E60/10

Claims Analysis

Total Claims: 8
Claim 1
Independent Claim 60 words
In a secondary, high-temperature electrochemical cell including an alkali metal reactant in the anode, a cathode reactant composition including a chalcogen compound in the cathode and an electrolyte containing ions of said alkali metal, the improvement wherein said cathode reactant composition comprises a mixture of a major proportion by weight FeS and a minor proportion by weight Cu 2 S.
Claim 2
Dependent Claim 60 words
In a secondary, high-temperature electrochemical cell including an alkali metal reactant in the anode, a cathode reactant composition including a chalcogen compound in the cathode and an electrolyte containing ions of said alkali metal, the improvement wherein said cathode reactant composition comprises a mixture of a major proportion by weight FeS and a minor proportion by weight Cu 2 S.
Claim 3
Dependent Claim 24 words
The improvement of claim 1 wherein said cathode reactant composition comprises 80% to 84% FeS and 16% to 20% Cu 2 S by weight.
Claim 4
Dependent Claim 22 words
The improvement of claim 1 wherein said cathode reactant composition comprises a powdered mixture of FeS particles and Cu 2 S particles.
Claim 5
Dependent Claim 47 words
The improvement of claim 1 wherein said cathode reactant composition is a powder of about 100 to 400 microns individual particle size, and wherein most of said individual particles comprises a solid solution of Cu 2 S in FeS, and ternary phases of Fe, Cu and S.
Claim 6
Dependent Claim 70 words
The improvement of claim 1 wherein said cathode reactant composition is a uniform mixture of FeS and Cu 2 S formed by melting said FeS and Cu 2 S together at 1200°C., uniformly blending said melt, cooling to less than about 900°C. in less than about 3 minutes to solidify said melt into an ingot and grinding said ingot into a powder of less than 400 microns average particle size.
Claim 7
Dependent Claim 22 words
The improvement of claim 1 wherein said cathode composition includes an inert, electrically conductive material contacting said FeS and Cu 2 S.
Claim 8
Dependent Claim 13 words
The improvement of claim 6 wherein said inert, electrically conductive material is iron.

References Cited (Backward Citations)

US3639174A Cited
US3716409A Cited
US3827910A Cited
US3887396A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1979-03-02 1979-09-01 1980-03-02 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1983-03-02 1983-09-01 1984-03-02 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1987-03-02 1987-09-01 1988-03-02 $7700.00 Window Closed / Lapsed

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