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US3940428A Expired / Lapsed US ⏱️ 0.0 years remaining

Methanol production

Assignee: Imperial Chemical Industries Ltd
•
Filing: 1972-12-07
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Granted: 1976-02-24
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Expires: 1992-12-07
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Abstract

Abstract In a process for producing methanol from a gaseous hydrocarbon feedstock, such as natural gas, containing more than the stoichiometric ratio of hydrogen to carbon, the hydrocarbon is subjected to steam reforming to give synthesis gas, the synthesis gas is incompletely reacted over a catalyst to give methanol, methanol is removed from the gas, the unreacted gas is treated to remove carbon monoxide or carbon dioxide from it, and the carbon monoxide or carbon dioxide or both is recycled to the methanol synthesis. By this means the concentration of carbon monoxide or carbon dioxide or both in the gas passing over the synthesis catalyst is kept at a higher level, thus increasing the efficiency of the synthesis and wastage of feedstock is avoided. At the same time a useful high-purity by-product hydrogen stream is produced.

Inventors

  • 👤 Anthony John Connell
  • 👤 Alwyn Pinto

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-27 09:31
CPC Classifications
C; C07; C07C; C07C29/00; C07C29/15; C07C29/151; C07C29/153; C07C29/154; C07C29/1516; C07C29/1518

Claims Analysis

Total Claims: 8
Claim 1
Independent Claim 221 words
In a process for producing methanol from a gaseous aliphatic hydrocarbon feedstock of empirical formula CH x where x is between 2 and 4 which comprises steam reforming the feedstock to give a synthesis gas containing hydrogen and at least one carbon oxide selected from the group consisting of carbon monoxide and carbon dioxide, the amount of hydrogen in the resulting synthesis gas being in excess of the stoichiometric amount necessary to form methanol, and reacting the synthesis gas in a catalytic synthesis stage using a copper catalyst to obtain methanol, the improvement which comprises reacting the synthesis gas incompletely in said catalytic synthesis stage to give a reaction product of methanol and unreacted hydrogen and carbon oxide, separating methanol from the remaining gas in said reaction product, recycling the remaining gas comprising unreacted hydrogen and carbon oxide to said synthesis stage for further reaction to form more methanol, and controlling the amount of hydrogen thereby recycled to said synthesis stage to prevent undesired build-up of hydrogen in said synthesis stage by withdrawing a part of said remaining gas before it is recycled to said synthesis stage, separating the carbon oxide from the hydrogen in this withdrawn part and recycling only the separated carbon oxide from said withdrawn part to said synthesis stage for reaction with hydrogen to form further methanol.
Claim 2
Dependent Claim 221 words
In a process for producing methanol from a gaseous aliphatic hydrocarbon feedstock of empirical formula CH x where x is between 2 and 4 which comprises steam reforming the feedstock to give a synthesis gas containing hydrogen and at least one carbon oxide selected from the group consisting of carbon monoxide and carbon dioxide, the amount of hydrogen in the resulting synthesis gas being in excess of the stoichiometric amount necessary to form methanol, and reacting the synthesis gas in a catalytic synthesis stage using a copper catalyst to obtain methanol, the improvement which comprises reacting the synthesis gas incompletely in said catalytic synthesis stage to give a reaction product of methanol and unreacted hydrogen and carbon oxide, separating methanol from the remaining gas in said reaction product, recycling the remaining gas comprising unreacted hydrogen and carbon oxide to said synthesis stage for further reaction to form more methanol, and controlling the amount of hydrogen thereby recycled to said synthesis stage to prevent undesired build-up of hydrogen in said synthesis stage by withdrawing a part of said remaining gas before it is recycled to said synthesis stage, separating the carbon oxide from the hydrogen in this withdrawn part and recycling only the separated carbon oxide from said withdrawn part to said synthesis stage for reaction with hydrogen to form further methanol.
Claim 3
Dependent Claim 22 words
A process according to claim 1 in which the total carbon oxides content of the remaining gas is in the range 10-15%.
Claim 4
Dependent Claim 25 words
A process according to claim 1 in which carbon monoxide and carbon dioxide are removed from the remaining gas by scrubbing with a cuprammonium solution.
Claim 5
Dependent Claim 33 words
A process according to claim 1 in which the remaining gas is subjected to shift reaction with steam to convert any carbon monoxide therein to carbon dioxide before separating carbon dioxide from it.
Claim 6
Dependent Claim 19 words
A process according to claim 1 in which there is used a shift stage upstream of the synthesis stage.
Claim 7
Dependent Claim 39 words
A process according to claim 1 in which methanol synthesis is effected by a copper-based catalyst containing copper, zinc oxide and a metal oxide component selected from chromium and metals from Groups II to IV of the Periodic Table.
Claim 8
Dependent Claim 15 words
A process according to claim 6 in which the synthesis pressure is below 150 atmospheres.

References Cited (Backward Citations)

US2198553A Cited
US2281228A Cited
US2904575A Cited
US3064029A Cited
GB1010871A Cited
US3337291A Cited
GB1104628A Cited
US3382045A Cited
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USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1979-02-23 1979-08-25 1980-02-24 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1983-02-23 1983-08-25 1984-02-24 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1987-02-23 1987-08-25 1988-02-24 $7700.00 Window Closed / Lapsed

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