US3937759A
Expired / Lapsed
US
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Hydrogenation process
Assignee: Shell USA Inc
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Filing: 1974-05-01
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Granted: 1976-02-10
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Expires: 1994-05-01
Abstract
Abstract The process of hydrogenating olefin compounds utilizing certain hydrogenation catalysts can be interrupted or halted by the addition to the reaction mixture of an organometallic reducing agent. Hydrogenation can be resumed by subsequent addition of an alcohol or other compound capable of reacting with the reducing agent.
Inventors
- 👤 Herman J. Baumgartner
- 👤 Jaroslav G. Balas
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-10-29 23:13
CPC Classifications
B; B01; B01J; B01J31/00; B01J31/02; B01J31/04; B01J31/0201; B01J31/0211; B01J31/0212; B01J31/12; B01J31/14; B01J31/143; C; C07; C07C; C07C5/00; C07C5/02; C07C5/03; C08; C08C; C08C19/00; C08C19/02; C08F; C08F8/00; C08F8/04; B01J2231/00; B01J2231/60; B01J2231/64; B01J2231/641; B01J2231/645; C10; C10G; C10G2400/00; C10G2400/20; Y; Y10; Y10S; Y10S525/00; Y10S525/94
Claims Analysis
Total Claims: 11
Claim 1
Independent Claim
88 words
In the process for the hydrogenation of polymers of olefinically unsaturated hydrocarbons wherein the hydrocarbons are hydrogenated in the presence of a catalyst comprising the reaction product of 1.0-5.0 moles of an aluminum trihydrocarbyl per mole of an alkoxide or carboxylate of a metal of the group consisting of cobalt, nickel, iron or mixtures thereof, the improvement comprising hydrogenating the hydrocarbon and thereafter reversibly interrupting the hydrogenation by injection of supplementary aluminum trihydrocarbyl in an amount between 0.75 and 2.5 moles per mole of cobalt, nickel or iron.
Claim 2
Dependent Claim
88 words
In the process for the hydrogenation of polymers of olefinically unsaturated hydrocarbons wherein the hydrocarbons are hydrogenated in the presence of a catalyst comprising the reaction product of 1.0-5.0 moles of an aluminum trihydrocarbyl per mole of an alkoxide or carboxylate of a metal of the group consisting of cobalt, nickel, iron or mixtures thereof, the improvement comprising hydrogenating the hydrocarbon and thereafter reversibly interrupting the hydrogenation by injection of supplementary aluminum trihydrocarbyl in an amount between 0.75 and 2.5 moles per mole of cobalt, nickel or iron.
Claim 3
Dependent Claim
60 words
A process according to claim 1 wherein the hydrogenation catalyst is the reaction product of an aluminum trihydrocarbyl and a carboxylate of cobalt, iron or nickel and hydrogenation is reactivated subsequent to interruption by injecton of at least one carboxylate of cobalt, nickel or iron in an amount between about 0.4 and 1.5 moles per mole of supplementary aluminum trihydrocarbyl.
Claim 4
Dependent Claim
41 words
A process according to claim 1 wherein hydrogenation is reactivated subsequent to interruption by injection of an aliphatic monohydric alcohol that is soluble in the reaction medium in an amount between 0.75 and 2.5 moles per mole of supplementary aluminum trihydrocarbyl.
Claim 5
Dependent Claim
14 words
A process according to claim 1 wherein the polymer comprises a polymerized conjugated diene.
Claim 6
Dependent Claim
23 words
A process according to claim 4 wherein the polymer comprises a copolymer of at least one monoalkenylarene and at least one conjugated diene.
Claim 7
Dependent Claim
13 words
A process according to claim 5 wherein the copolymer is a block copolymer.
Claim 8
Dependent Claim
19 words
A process according to claim 3 wherein the alcohol is an aliphatic alcohol having 2-14 carbon atoms per molecule.
Claim 9
Dependent Claim
25 words
A process according to claim 4 wherein hydrogenation is interrupted after at least about 90% of the olefinic double bonds have been reduced by hydrogenation.
Claim 10
Dependent Claim
17 words
A process according to claim 6 wherein the polymer is a block copolymer having the structure polystyrene-polyisoprene.
Claim 11
Dependent Claim
17 words
A process according to claim 6 wherein the polymer is a block copolymer having the structure polystyrene-polybutadiene-polystyrene.
References Cited (Backward Citations)
USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1979-02-09 | 1979-08-11 | 1980-02-10 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1983-02-09 | 1983-08-11 | 1984-02-10 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1987-02-09 | 1987-08-11 | 1988-02-10 | $7700.00 | Window Closed / Lapsed |