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US3936309A Expired / Lapsed US ⏱️ 0.0 years remaining

Heat-sensitive recording composition and sheet

Assignee: Mitsubishi Paper Mills Ltd
•
Filing: 1973-07-18
•
Granted: 1976-02-03
•
Expires: 1993-07-18
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Abstract

Abstract A heat-sensitive recording composition comprising a normally colorless or pale-colored chromogenic substance, a phenolic substance capable of developing the color of said chromogenic substance at an elevated temperature, and a water-soluble binder is not water resistant, but when incorporated with a compound having 2 to 10 1,2-epoxy ring structures O ANGLE >C--C< in one molecule as a hardner for said binder, the composition is rendered highly water resistant. Further, a coating liquid containing the said composition is prevented from coloration, and a recording sheet prepared by coating the said coating liquid on a support is prevented from coloration in texture.

Inventors

  • 👤 Isao Kohmura
  • 👤 Kiyoshi Futaki
  • 👤 Yukio Tahara

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-08 03:53
CPC Classifications
B; B41; B41M; B41M5/00; B41M5/26; B41M5/30; B41M5/337; B41M5/3372

Claims Analysis

Total Claims: 15
Claim 1
Independent Claim 55 words
In a heat-sensitive recording composition comprising a normally colorless or somewhat pale-colored chromogenic substance, a phenolic substance capable of developing the color of said chromogenic substance at an elevated temperature, and a water-soluble binder, the improvement wherein a compound having 2 to 10 1,2-epoxy ring structures ##EQU4## is added as a hardener to the composition.
Claim 2
Dependent Claim 55 words
In a heat-sensitive recording composition comprising a normally colorless or somewhat pale-colored chromogenic substance, a phenolic substance capable of developing the color of said chromogenic substance at an elevated temperature, and a water-soluble binder, the improvement wherein a compound having 2 to 10 1,2-epoxy ring structures ##EQU4## is added as a hardener to the composition.
Claim 3
Dependent Claim 27 words
A composition according to claim 1, wherein the compound having epoxy ring structures is selected from the group consisting of: ##EQU5## ##SPC4## ##EQU6## ##SPC5## ##EQU7## ##SPC6## ##EQU8##
Claim 4
Dependent Claim 27 words
A composition according to claim 1, wherein the amount of the hardener is 0.1 to 30 % by weight based on the weight of the water-soluble binder.
Claim 5
Dependent Claim 27 words
A composition according to claim 1, wherein the amount of the hardener is 0.5 to 20 % by weight based on the weight of the water-soluble binder.
Claim 6
Dependent Claim 19 words
A composition according to claim 1, wherein the phenolic substance has at least two hydroxy groups in one molecule.
Claim 7
Dependent Claim 19 words
A heat-sensitive recording sheet which comprises a support and, coated thereon, the heat-sensitive recording composition defined in claim 1.
Claim 8
Dependent Claim 29 words
A heat-sensitive recording sheet according to claim 6, wherein the compound having epoxy ring structures is selected from the group consisting of: ##EQU9## ##SPC7## ##EQU10## ##SPC8## ##EQU11## ##SPC9## ##EQU12##
Claim 9
Dependent Claim 29 words
A heat-sensitive recording sheet according to claim 6, wherein the amount of the hardener is 0.5 to 30 % by weight based on the weight of the water-soluble binder.
Claim 10
Dependent Claim 29 words
A heat-sensitive recording sheet according to claim 6, wherein the amount of the hardener is 0.5 to 20 % by weight based on the weight of the water-soluble binder.
Claim 11
Dependent Claim 21 words
A heat-sensitive recording sheet according to claim 6, wherein the phenolic substance has at least two hydroxy groups in one molecule.
Claim 12
Dependent Claim 32 words
A composition according to claim 1, wherein the water-soluble binder is selected from the group consisting of polyvinyl alcohol, methyl cellulose, hydroxyethyl cellulose, gum arabic, gelatin, styrene-maleic anhydride copolymer and acrylic resin.
Claim 13
Dependent Claim 26 words
A composition according to claim 11, wherein the amount of the hardener is 0.1 to 30% by weight based on the weight of the water-soluble binder.
Claim 14
Dependent Claim 14 words
A composition according to claim 11, wherein the water soluble binder is hydroxyethyl cellulose.
Claim 15
Dependent Claim 15 words
A composition according to claim 11, wherein the water soluble binder is styrene-maleic anhydride copolymer.

References Cited (Backward Citations)

US2479037A Cited
US3560229A Cited
US3450613A Cited
US3357831A Cited
US3497353A Cited
US3695904A Cited
US3770602A Cited
US3654193A Cited
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US3721617A Cited
US3761270A Cited
US3829401A Cited
US3859112A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1979-02-02 1979-08-04 1980-02-03 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1983-02-02 1983-08-04 1984-02-03 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1987-02-02 1987-08-04 1988-02-03 $7700.00 Window Closed / Lapsed

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