Process for the oxidation of olefine compounds

Claim 2

Process for the production of acetone by oxidising propylene in an oxygen-free atmosphere, in the gas phase, in the absence of water or in the presence of up to 5% by weight of water, using, as oxidising agent, an oxy-metal compound containing one or more oxygen atoms directly bonded to the metal and not bonded to an organic radical, selected from an oxo-metal compound of the general formula: [[(L).sub.x (O).sub.n M-Q].sub.p M(O).sub.n (L).sub.x ].sup.m A (I) in which M represents V, L represents a monodentate or polydentate ligand, A represents an organic or inorganic anion or cation, Q represents oxygen or sulphur, x is an integer greater than or equal to zero, p is equal to zero or one, m is a positive or negative integer and n is an integer greater than or equal to zero such that there is one or more oxygen atoms directly bonded to the metal and not bonded to an organic radical.

Claim 3

Process for the production of acetone by oxidising propylene in an oxygen-free atmosphere, in the gas phase, in the absence of water or in the presence of up to 5% by weight of water, using, as oxidizing agent, an oxy-metal compound containing one or more oxygen atoms directly bonded to the metal and not bonded to an organic radical, selected from uranium oxide, hafnium oxide an oxo-metal compound of the general formula: [[(L).sub.x (O).sub.n M--Q].sub.p M(O).sub.n (L).sub.x ].sup.m A (I) in which M represents Ti, Zr, Hf, V, Nb, Ta, Mo, W or U, L represents a monodentate or polydentate ligand, A represents an organic or inorganic anion or cation, Q represents oxygen or sulphur, x is an integer greater than or equal to zero, p is equal to zero or one, m is a positive or negative integer and n is an integer greater than or equal to zero such that there is one or more oxygen atoms directly bonded to the metal and not bonded to an organic radical.

Claim 4

Process for the production of acetone by oxidising propylene in an oxygen-free atmosphere, in the gas phase, in the absence of water or in the presence of up to 5% by weight of water, using, as oxidizing agent, an oxy-metal compound containing one or more oxygen atoms directly bonded to the metal and not bonded to an organic radical, selected from uranium oxide, hafnium oxide an oxo-metal compound of the general formula: [[(L).sub.x (O).sub.n M--Q].sub.p M(O).sub.n (L).sub.x ].sup.m A (I) in which M represents Ti, Zr, Hf, V, Nb, Ta, Mo, W or U, L represents a monodentate or polydentate ligand, A represents an organic or inorganic anion or cation, Q represents oxygen or sulphur, x is an integer greater than or equal to zero, p is equal to zero or one, m is a positive or negative integer and n is an integer greater than or equal to zero such that there is one or more oxygen atoms directly bonded to the metal and not bonded to an organic radical.

Claim 5

Process according to claim 1 wherein the oxidising agent is a compound of formula (I) in which x is equal to zero, m is a positive integer and A represents an inorganic or organic anion which forms a salt which may be chelated with the oxo-metal cation.

Claim 6

Process according to claim 3, wherein the oxidising agent is a compound of formula (I) which is a salt of a monocarboxylic or polycarboxylic acid, a β-diketonate or diketimine-diketonate.

Claim 7

Process according to claim 4 wherein the oxidising agent is a tungstyl-, vanadyl-, molybdyl-, molybdenyl- zirconyl-, titanyl-, uranyl- or hafnyl-β-diketonate.

Claim 8

Process according to claim 5 wherein the oxidising agent is a tungstyl-, vanadyl-, molybdyl-, molybdenyl-, zirconyl-, titanyl-, uranyl- or hafnyl- acetylacetonate; a tungstyl-, vanadyl-, molybdyl-, molybdenyl-, zirconyl-, titanyl-, uranyl- or hafnyl-ethylene- diimineacetylacetone; bis-(pivaloylmethane)-oxovanadium or vanadyl benzoylacetonate.

Claim 9

Process according to claim 1 wherein the reaction is carried out at a temperature of 20° to 300°C, at atmospheric or super atmospheric pressure.

Claim 10

Process for the production of acetone by oxidising propylene in an oxygen-free atmosphere, in an organic liquid in the absence of water or in the presence of up to 5% by weight of water, using, as oxidising agent, an oxy-metal compound containing one or more oxygen atoms directly bonded to the metal and not bonded to an organic radical, selected from uranium oxide, hafnium oxide an oxo-metal compound of the general formula: [[(L).sub.x (O).sub.n M--Q].sub.p M(O).sub.n (L).sub.x ].sup.m A (I) in which M represents Ti, Zr, Hf, V, Nb, Ta, Mo, W or U, L represents a monodentate or polydentate ligand, A represents an organic or inorganic anion or cation, Q represents oxygen or sulphur, x is an integer greater than or equal to zero, p is equal to zero or one, m is a positive or negative integer and n is an integer greater than or equal to zero such that there is one or more oxygen atoms directly bonded to the metal and not bonded to an organic radical.

Claim 11

Process for the production of acetone by oxidising propylene in an oxygen-free atmosphere, in an organic liquid in the absence of water or in the presence of up to 5% by weight of water, using, as oxidising agent, an oxy-metal compound containing one or more oxygen atoms directly bonded to the metal and not bonded to an organic radical, selected from uranium oxide, hafnium oxide an oxo-metal compound of the general formula: [[(L).sub.x (O).sub.n M--Q].sub.p M(O).sub.n (L).sub.x ].sup.m A (I) in which M represents Ti, Zr, Hf, V, Nb, Ta, Mo, W or U, L represents a monodentate or polydentate ligand, A represents an organic or inorganic anion or cation, Q represents oxygen or sulphur, x is an integer greater than or equal to zero, p is equal to zero or one, m is a positive or negative integer and n is an integer greater than or equal to zero such that there is one or more oxygen atoms directly bonded to the metal and not bonded to an organic radical.

Claim 12

Process for the production of acetone by oxidising propylene in an oxygen-free atmosphere, in an organic liquid in the absence of water or in the presence of up to 5% by weight of water, using, as oxidising agent, an oxy-metal compound containing one or more oxygen atoms directly bonded to the metal and not bonded to an organic radical, selected from an oxo-metal compound of the general formula: [[(L).sub.x (O).sub.n M--Q].sub.p M(O).sub.n (L).sub.x ].sup.m A (I) in which M represents V, L represents a monodentate or polydentate ligand, A represents an organic or inorganic anion or cation, Q represents oxygen or sulphur, x is an integer greater than or equal to zero, p is equal to zero or one, m is a positive or negative integer and n is an integer greater than or equal to zero such that there is one or more oxygen atoms directly bonded to the metal and not bonded to an organic radical.

Claim 13

Process for the production of acetone by oxidising propylene in an oxygen-free atmosphere, in an organic liquid in the absence of water or in the presence of up to 5% by weight of water, using, as oxidising agent, an oxy-metal compound containing one or more oxygen atoms directly bonded to the metal and not bonded to an organic radical, selected from an oxo-metal compound of the general formula: [[(L).sub.x (O).sub.n M--Q].sub.p M(O).sub.n (L).sub.x ].sup.m A (I) in which M represents V, L represents a monodentate or polydentate ligand, A represents an organic or inorganic anion or cation, Q represents oxygen or sulphur, x is an integer greater than or equal to zero, p is equal to zero or one, m is a positive or negative integer and n is an integer greater than or equal to zero such that there is one or more oxygen atoms directly bonded to the metal and not bonded to an organic radical.

Claim 14

Process according to claim 9 wherein the oxidising agent is a compound of formula (I) in which x is equal to zero, m is a positive integer and A represents an inorganic or organic anion which forms a salt which may be chelated with the oxometal cation.

Claim 15

Process according to claim 10, wherein the oxidising agent is a compound of formula (I) which is a salt of a monocarboxylic or polycarboxylic acid, a β-diketonate or diketiminediketonate.

Claim 16

Process according to claim 11 wherein the oxidising agent is a tungstyl-, vanadyl-, molybdyl-, molybdenyl-, zirconyl-, titanyl-, uranyl- or hafnyl-β-diketonate.

Claim 17

process according to claim 12 wherein the oxidising agent is a tungstyl-, vanadyl-, molybdyl-, molybdenyl-, zirconyl-, titanyl-, uranyl- or hafnyl-acetylacetonate; a tungstyl-, vanadyl-, molybdyl-, molybdenyl-, zirconyl-, titanyl-, uranyl-, or hafnyl-ethylene-diimineacetylacetone; bis-(pivaloymethane)-oxovanadium or vanadyl benzoylacetonate.

Claim 18

Process according to claim 9 wherein the reaction is carried out at a temperature of 20° to 300°C., at atmospheric or super atmospheric pressure.

Claim 19

Process according to claim 9 wherein the oxidation is carried out in the presence of an organic solvent for the olefinic compound.