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US3933754A Expired / Lapsed US ⏱️ 0.0 years remaining

Insoluble chloroprene polymer

Assignee: Denka Co Ltd
•
Filing: 1974-07-24
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Granted: 1976-01-20
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Expires: 1994-07-24
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Abstract

Abstract A toluene-insoluble gel polymer having a crosslinking density of at least 2.4 × 10 - 6 obtained by polymerizing chloroprene or a mixture of chloroprene with a small amount of at least one copolymerizable monomer to a monomer conversion of at least 80 percent in the presence of a crosslinking agent selected from the group consisting of a compound represented by the following formula: ##EQU1## wherein n is integer of from 1 to 8, ##EQU2## wherein n is integer of from 2 to 4, divinylbenzene and diallyl phthalate and a process for the preparation thereof.

Inventors

  • 👤 Chojiro Kitagawa
  • 👤 Ichiro Fukuoka
  • 👤 Takashi Kadowaki
  • 👤 Shoji Kimura
  • 👤 Takehiko Nishimura
  • 👤 Kanehisa Hanabusa

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-02 05:57
CPC Classifications
C; C08; C08F; C08F36/00; C08F36/02; C08F36/04; C08F36/14; C08F36/16; C08F36/18

Claims Analysis

Total Claims: 22
Claim 1
Independent Claim 88 words
A toluene-insoluble gel polymer having a crosslinking density of at least 2.4 × 10 - 6 obtained by polymerizing chloroprene or a mixture of chloroprene with a small amount of at least one copolymerizable monomer to a monomer conversion of at least 80 percent in the presence of a crosslinking agent selected from the group consisting of a compound represented by the following formula: ##EQU7## wherein n is integer of from 1 to 8, ##EQU8## wherein n is integer of from 2 to 4, divinylbenzene and diallyl phthalate.
Claim 2
Dependent Claim 88 words
A toluene-insoluble gel polymer having a crosslinking density of at least 2.4 × 10 - 6 obtained by polymerizing chloroprene or a mixture of chloroprene with a small amount of at least one copolymerizable monomer to a monomer conversion of at least 80 percent in the presence of a crosslinking agent selected from the group consisting of a compound represented by the following formula: ##EQU7## wherein n is integer of from 1 to 8, ##EQU8## wherein n is integer of from 2 to 4, divinylbenzene and diallyl phthalate.
Claim 3
Dependent Claim 15 words
A toluene-insoluble gel polymer of claim 1, wherein the crosslinking agent is ethylene glycol dimethacrylate.
Claim 4
Dependent Claim 15 words
A toluene-insoluble gel polymer of claim 1, wherein the crosslinking agent is trimethylene glycol dimethacrylate.
Claim 5
Dependent Claim 15 words
A toluene-insoluble gel polymer of claim 1, wherein the crosslinking agent is tetramethylene glycol dimethacrylate.
Claim 6
Dependent Claim 15 words
A toluene-insoluble gel polymer of claim 1, wherein the crosslinking agent is diethylene glycol dimethacrylate.
Claim 7
Dependent Claim 15 words
A toluene-insoluble gel polymer of claim 1, wherein the crosslinking agent is triethylene glycol dimethacrylate.
Claim 8
Dependent Claim 15 words
A toluene-insoluble gel polymer of claim 1, wherein the crosslinking agent is tetraethylene glycol dimethacrylate.
Claim 9
Dependent Claim 40 words
A toluene-insoluble gel polymer of claim 1, wherein the monomer copolymerizable with chloroprene is a monomer selected from the group consisting of styrene, vinyltoluene, butadiene, isoprene, 2,3-dichlorobutadiene-1,3, methyl vinyl ketone, methyl acrylate, ethyl acrylate, methyl methacrylate, ethyl methacrylate and acrylonitrile.
Claim 10
Dependent Claim 15 words
A toluene-insoluble gel polymer of claim 1, wherein the monomer copolymerizable with chloroprene is styrene.
Claim 11
Dependent Claim 15 words
A toluene-insuluble gel polymer of claim 1, wherein the monomer copolymerizable with chloroprene is 2,3-dichlorobutadiene-1,3.
Claim 12
Dependent Claim 90 words
A process for preparing a toluene-insoluble gel polymer comprising polymerizing chloroprene or a mixture of chloroprene with a small amount of at least one copolymerizable monomer in the presence of a cross-linking agent selected from the group consisting of a compound represented by the following formula: ##EQU9## wherein n is integer of from 1 to 8, ##EQU10## wherein n is integer of from 2 to 4, divinylbenzene and diallylphthalate to a crosslinking density of at least 2.4 × 10 - 6 and a monomer conversion of at least 80 percent.
Claim 13
Dependent Claim 90 words
A process for preparing a toluene-insoluble gel polymer comprising polymerizing chloroprene or a mixture of chloroprene with a small amount of at least one copolymerizable monomer in the presence of a cross-linking agent selected from the group consisting of a compound represented by the following formula: ##EQU9## wherein n is integer of from 1 to 8, ##EQU10## wherein n is integer of from 2 to 4, divinylbenzene and diallylphthalate to a crosslinking density of at least 2.4 × 10 - 6 and a monomer conversion of at least 80 percent.
Claim 14
Dependent Claim 13 words
A process of claim 11, wherein the crosslinking agent is ethylene glycol dimethacrylate.
Claim 15
Dependent Claim 13 words
A process of claim 11, wherein the crosslinking agent is trimethylene glycol dimethacrylate.
Claim 16
Dependent Claim 13 words
A process of claim 11, wherein the crosslinking agent is tetramethylene glycol dimethacrylate.
Claim 17
Dependent Claim 13 words
A process to claim 11, wherein the crosslinking agent is diethylene glycol dimethacrylate.
Claim 18
Dependent Claim 13 words
A process of claim 11, wherein the crosslinking agent is triethylene glycol dimethacrylate.
Claim 19
Dependent Claim 13 words
A process of claim 11, wherein the crosslinking agent is tetraethylene glycol dimethacrylate.
Claim 20
Dependent Claim 38 words
A process of claim 11, wherein the monomer copolymerizable with chloroprene is a monomer selected from the group consisting of styrene, vinyltoluene, butadiene, isoprene, 2,3-dichlorobutadiene-1,3, methyl vinyl ketone, methyl acrylate, ethyl acrylate, methyl methacrylate, ethyl methacrylate and acrylonitrile.
Claim 21
Dependent Claim 13 words
A process of claim 11, wherein the monomer copolymerizable with chloroprene is styrene.
Claim 22
Dependent Claim 13 words
A process of claim 11, wherein the monomer copolymerizable with chloroprene is 2,3-dichlorobutadiene-1,3.

References Cited (Backward Citations)

US1967860A Cited
US2628210A Cited
US3300433A Cited
US3719649A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1979-01-19 1979-07-21 1980-01-20 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1983-01-19 1983-07-21 1984-01-20 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1987-01-19 1987-07-21 1988-01-20 $7700.00 Window Closed / Lapsed

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