US3932689A
Expired / Lapsed
US
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Flexible adhesive composition and method for utilizing same and article formed therefrom
Assignee: Sumitomo Bakelite Co Ltd
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Filing: 1974-02-21
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Granted: 1976-01-13
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Expires: 1994-02-21
Abstract
Abstract This invention provides an adhesive composition for use in flexible printed circuits, comprising a phenol-formaldehyde resin, a polyepoxy compound, an acrylonitrile-butadiene copolymer and/or a polyvinylacetal resin, and a styrenic copolymer containing as structural units maleic anhydride and/or an alkyl maleate. Being excellent in adhesive strength, flow property, rapid curability, and heat resistance after curing, the present composition is especially suitable for the continuous bonding of insulating plastic films, particularly a polyimide film, to conductor foils by use of a roll-laminator and gives heat-resistant metal-clad laminates excellent for flexible printed circuits which can be soldered at high temperatures. This invention further provides an adhesive composition having added thereto a compound consisting of an anhydride or a half-ester of cyclohexenepolycarboxylic acid in order to increase the flow property and adhesive strength of the adhesive composition at the time of bonding by means of a roll-laminator. All of the aforesaid adhesive composition not only permit the economical and technically advantageous production of laminates for heat resistant flexible printed circuits, but also can serve as an adhesive for either an overlay film for use in highly heat-resistant flexible printed circuits or an interlayer adhesive film.
Inventors
- 👤 Tsutomu Watanabe
- 👤 Sigenori Yamaoka
- 👤 Kochi Tanaka
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-10-25 03:54
CPC Classifications
C; C08; C08L; C08L57/00; C08L57/06; C08L57/10; B; B32; B32B; B32B7/00; B32B7/04; B32B7/12; B32B15/00; B32B15/04; B32B15/08; B32B15/088; B32B15/09; B32B15/20; B32B27/00; B32B27/28; B32B27/281; B32B27/34; B32B27/36; C09; C09J; C09J109/00; C09J109/02; C09J161/00; C09J161/04; C09J161/06; C09J163/00; H; H05; H05K; H05K3/00; H05K3/38; H05K3/386; B32B2367/00; B32B2377/00; B32B2379/00; B32B2379/08; B32B2457/00; B32B2457/08; C08L25/00; C08L2666/00; C08L2666/02; C08L29/00; C08L29/14; C08L63/00; C08L9/00; C08L9/02; H05K1/00; H05K1/02; H05K1/03; H05K1/0393; H05K2201/00; H05K2201/03; H05K2201/0332; H05K2201/0335; H05K2201/0355; Y; Y10; Y10T; Y10T428/00; Y10T428/31504; Y10T428/31511; Y10T428/31529; Y10T428/31678; Y10T428/31688; Y10T428/31692; Y10T428/31696; Y10T428/31721
Claims Analysis
Total Claims: 31
Claim 1
Independent Claim
94 words
An adhesive composition for flexible printed circuits comprising a mixture of ( 1) a fusible and soluble phenol-formaldehyde resin, (2) a polyepoxy compound having at least two epoxy groups in its molecule, (3) at least one polymer selected from the group consisting of acrylonitrile-butadiene copolymers and polyvinylacetal resins, and (4) at least one copolymer selected from the group consisting of (a) partial alkyl esters of copolymers of aromatic vinyl compounds and maleic anhydride, (b) copolymers of aromatic vinyl compounds and alkyl maleates, and (c) copolymers of aromatic vinyl compounds, maleic anhydride, and alkyl maleates.
Claim 2
Dependent Claim
94 words
An adhesive composition for flexible printed circuits comprising a mixture of ( 1) a fusible and soluble phenol-formaldehyde resin, (2) a polyepoxy compound having at least two epoxy groups in its molecule, (3) at least one polymer selected from the group consisting of acrylonitrile-butadiene copolymers and polyvinylacetal resins, and (4) at least one copolymer selected from the group consisting of (a) partial alkyl esters of copolymers of aromatic vinyl compounds and maleic anhydride, (b) copolymers of aromatic vinyl compounds and alkyl maleates, and (c) copolymers of aromatic vinyl compounds, maleic anhydride, and alkyl maleates.
Claim 3
Dependent Claim
73 words
An adhesive composition for flexible printed circuits according to claim 1, wherein the mixture contains, in addition, at least one compound selected from the group consisting of derivatives of cyclohexene-polycarboxylic acids represented by the general formulas, E and F, ##SPC2## wherein X and Z are hydrogen atoms or alkyl groups having 1 to 10 carbon atoms and Y is hydrogen atom, carboxyl group, or a carboxyalkyl group having 2 to 11 carbon atoms.
Claim 4
Dependent Claim
41 words
An adhesive composition for flexible printed circuits according to claim 1, wherein the fusible and soluble phenol-formaldehyde resin is a resol-type phenol-formaldehyde resin obtained by using as catalyst at least one member selected from the group consisting of ammonia and amines.
Claim 5
Dependent Claim
41 words
An adhesive composition for flexible printed circuits according to claim 2, wherein the fusible and soluble phenol-formaldehyde resin is a resol-type phenol-formaldehyde resin obtained by using as catalyst at least one member selected from the group consisting of ammonia and amines.
Claim 6
Dependent Claim
52 words
An adhesive composition for flexible printed circuits according to claim 1, wherein the polyexpoxy compound having at least 2 epoxy groups in its molecule is a polyether-type diepoxy compound obtained by condensation reaction between an epihalohydrin and a dihydric alcohol formed from the addition reaction between a bisphenol and an alkylene oxide.
Claim 7
Dependent Claim
50 words
An adhesive composition for flexible printed circuits according to claim 2, wherein the polyepoxy compound having at least 2 epoxy groups in its molecule is a polyether-type diepoxy compound obtained by condensing an epihalohydrin with a dihydric alcohol formed from the addition reaction between a bisphenol and an alkylene oxide.
Claim 8
Dependent Claim
29 words
An adhesive composition for flexible printed circuits according to claim 1, wherein the acrylonitrile-butadiene copolymer is a high-nitrile copolymer containing 25 to 50% by weight of the acrylonitrile component.
Claim 9
Dependent Claim
29 words
An adhesive composition for flexible printed circuits according to claim 2, wherein the acrylonitrile-butadiene copolymer is a high-nitrile copolymer containing 25 to 50% by weight of the acrylonitrile component.
Claim 10
Dependent Claim
31 words
An adhesive composition for flexible printed circuits according to claim 1, wherein the polyvinyl-acetal resin is a partially acetalized product having a degree of acetalization of 50 to 80 mol percent.
Claim 11
Dependent Claim
31 words
An adhesive composition for flexible printed circuits according to claim 2, wherein the polyvinyl-acetal resin is a partially acetalized product having a degree of acetalization of 50 to 80 mol percent.
Claim 12
Dependent Claim
109 words
An adhesive composition for flexible printed circuits according to claim 1, wherein the mixing proportions of the components based on the total amount of the adhesive compositions are 5 to 50% by weight concerning the fusible and soluble phenol-formaldehyde resin, 5 to 70% by weight concerning the polyepoxy compound having at least 2 epoxy groups in its molecule, 5 to 60% by weight concerning the at least one polymer selected from the group consisting of acrylonitrile-butadiene copolymers and polyvinyl-acetal resins, and 5 to 50% by weight concerning the at least one copolymer selected from the group consisting of the copolymers (a), (b) and (c) as specified in claim 1.
Claim 13
Dependent Claim
138 words
An adhesive composition for flexible printed circuits according to claim 2, wherein the mixing proportions of the components based on the total amount of the adhesive composition are 5 to 50% by weight concering the fusible and soluble phenol-formaldehyde resin, 5 to 70% by weight concerning the polyepoxy compound having at least 2 epoxy groups in its molecule, 5 to 60% by weight concerning the at least one polymer selected from the group consisting of acrylonitrile-butadiene copolymers and polyvinyl-acetal resins, 5 to 50% by weight concerning the at least one copolymer selected from the group consisting of the copolymers (a), (b) and (c) as specified in claim 1, and 2 to 30% by weight concerning the at least one compound selected from the group consisting of derivatives of cyclohexenepolycarboxylic acids represented by the general formulas E and F.
Claim 14
Dependent Claim
48 words
A method for manufacturing a metal-clad laminate for flexible printed circuits, which comprises applying the adhesive composition according to claim 1 to a plastic film or a metal foil or both of them and bonding the plastic film to the metal foil by application of heat and pressure.
Claim 15
Dependent Claim
41 words
A method for manufacturing a metal-clad laminate for flexible printed circuits, which comprises interposing the adhesive composition according to claim 2 between a plastic film and a metal foil and bonding the latter two materials by application of heat and pressure.
Claim 16
Dependent Claim
42 words
A method for manufacturing a metal-clad laminate for flexible printed circuits, which comprises interposing the adhesive composition according to claim 1 between a polyimide film and a metal foil and bonding the film to the foil by application of heat and pressure.
Claim 17
Dependent Claim
42 words
A method for manufacturing a metal-clad laminate for flexible printed circuits, which comprises interposing the adhesive composition according to claim 2 between a polyimide film and a metal foil and bonding the film to the foil by application of heat and pressure.
Claim 18
Dependent Claim
42 words
A method for manufacturing a metal-clad laminate for flexible printed circuits, which comprises interposing the adhesive composition according to claim 1 between a polyamide-imide film and a metal foil and bonding the film to the foil by application of heat and pressure.
Claim 19
Dependent Claim
42 words
A method for manufacturing a metal-clad laminate for flexible printed circuits, which comprises interposing the adhesive composition according to claim 2 between a polyamide-imide film and a metal foil and bonding the film to the foil by application of heat and pressure.
Claim 20
Dependent Claim
132 words
A method for manufacturing a metal-clad laminate for flexible printed circuits, which comprises interposing the adhesive composition according to claim 1 between a plastic film and a metal foil, passing the resulting assembly between a pair of pressing rolls of a laminating equipment, one of the rolls being a metal roll and the other being a rubber roll, in such a manner that the plastic film and the metal foil contact with the metal roll and the rubber roll, respectively, and the metal foil is allowed to wrap around the rubber roll from the position on the circumference of the rubber roll for π/4 or more radians toward the contact line of both rolls, and effecting the bonding by application of heat and pressure while passing through said pair of pressing rolls.
Claim 21
Dependent Claim
132 words
A method for manufacturing a metal-clad laminate for flexible printed circuits, which comprises interposing the adhesive composition according to claim 2 between a plastic film and a metal foil, passing the resulting assembly between a pair of pressing rolls of a laminating equipment, one of the rolls being a metal roll and the other being a rubber roll, in such a manner that the plastic film and the metal foil contact with the metal roll and the rubber roll, respectively, and the metal foil is allowed to wrap around the rubber roll from the position on the circumference of the rubber roll for π/4 or more radians toward the contact line of both rolls, and effecting the bonding by application of heat and pressure while passing through said pair of pressing rolls.
Claim 22
Dependent Claim
132 words
A method for manufacturing a metal-clad laminate for flexible printed circuits, which comprises interposing the adhesive composition according to claim 11 between a plastic film and a metal foil, passing the resulting assembly between a pair of pressing rolls of a laminating equipment, one of the rolls being a metal roll and the other being a rubber roll, in such a manner that the plastic film and the metal foil contact with the metal roll and the rubber roll, respectively, and the metal foil is allowed to wrap around the rubber roll from the position on the circumference of the rubber roll for π/4 or more radians toward the contact line of both rolls, and effecting the bonding by application of heat and pressure while passing through said pair of pressing rolls.
Claim 23
Dependent Claim
131 words
A method for manufacturing a metal-clad laminate for flexible printed circuits, which comprises interposing the adhesive composition according to claim 12 between a plastic film and a metal foil, passing the resulting assembly between a pair of pressing rolls of a laminating equipment, one of the rolls being a metal roll and the other being a rubber roll, in such a manner that the plastic film and the metal foil contact with the metal roll and the rubber roll, respectively, and the metal foil is allowed to wrap around the rubber roll from the position on the circumference of the rubber roll for π/4 or more radians toward the contact of both rolls, and effecting the bonding by application of heat and pressure while passing through said pair of pressing rolls.
Claim 24
Dependent Claim
15 words
A metal-clad laminate for flexible printed circuits obtained by the method according to claim 15.
Claim 25
Dependent Claim
15 words
A metal-clad laminate for flexible printed circuits obtained by the method according to claim 16.
Claim 26
Dependent Claim
15 words
A metal-clad laminate for flexible printed circuits obtained by the method according to claim 17,
Claim 27
Dependent Claim
15 words
A metal-clad laminate for flexible printed circuits obtained by the method according to claim 18.
Claim 28
Dependent Claim
14 words
A method according to claim 19, wherein the plastic film is a polyimide film.
Claim 29
Dependent Claim
14 words
A method according to claim 20, wherein the plastic film is a polyimide film.
Claim 30
Dependent Claim
17 words
A metal-clad laminate for flexible printed circuits obtained by any of the methods according to claim 13.
Claim 31
Dependent Claim
17 words
A metal-clad laminate for flexible printed circuits obtained by any of the methods according to claim 14.
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USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1979-01-12 | 1979-07-14 | 1980-01-13 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1983-01-12 | 1983-07-14 | 1984-01-13 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1987-01-12 | 1987-07-14 | 1988-01-13 | $7700.00 | Window Closed / Lapsed |