Radical-initiated polymerization reactions and mixture

Claim 3

A method as claimed in claim 1 wherein the silyl-ether is of the formula ##EQU2## in which A, B, D and E are each a member selected from the group consisting of an unsubstituted 2-naphthyl radical, an unsubstituted phenyl radical, a phenyl radical substituted in at least one of the 2-, 3-, 4-, 5- and 6-positions by chlorine or bromine, a phenyl radical having 6-18 carbon atoms substituted in at least one of the 2-, 3-, 4-, 5- and 6-positions by alkyl having up to 4 carbon atoms, a phenyl radical having 6-18 carbon atoms substituted in at least one of the 2-, 3-, 4-, 5- and 6-positions by alkoxy having up to 4 carbon atoms, a phenyl radical with 12 to 18 carbon atoms substituted in at least one of the 3-, 4- and 5-positions by phenyl, in which A and B and D and E may form together with the carbon atom to which they are attached the fluorenylidene radical, and in which X and Y are trialkyl-siloxy or triaryl-siloxy radicals.

Claim 4

A method as claimed in claim 2 wherein the silylether is of the formula ##SPC1## in which R 1 is hydrogen, methyl, ethyl or methoxy; R 2 is hydrogen, methyl or ethyl; R 3 is hydrogen or methyl and R 4 is methyl.

Claim 5

A method as claimed in claim 1 wherein the polymerization is conducted at a temperature above 50°C.

Claim 6

A method as claimed in claim 1 wherein the silyl-ether is present in an amount of 0.05 to 0.2% by weight, based on the weight of the polymerizable substance.

Claim 7

A method as claimed in claim 1 wherein the polymerizable substance is a member selected from the group consisting of a monoolefin, a conjugated diolefin, a vinyl-substituted benzene or a derivative thereof, a N-vinyl heterocycle, an α,β-olefinically unsaturated carboxylic acid or an ester, amide or nitrile thereof, a vinyl ester, a vinyl ketone, an allyl ester, a di(allylphenyl) carbonate, a vinyl halide, a vinylidene halide, a di(vinylphenyl) carbonate, a polyol acrylate, a polyol methacrylate, a N,N'-methylene-bis-acrylamide and a N,N'-methylene-bis-methylacrylamide.

Claim 8

A method as claimed in claim 1 wherein the polymerizable substance is a mixture of an unsaturated polyester of a dihydric alcohol and an α,β-unsaturated dicarboxylic acid and a copolymerizable ethylenically unsaturated monomer.

Claim 9

A method as claimed in claim 7 wherein the silyl-ether is tetra-(4-tolyl)-1,2-bis-(trimethylsiloxy)-ethane.

Claim 10

A method as claimed in claim 1 wherein the polymerizable substance is methyl methacrylate and the silyl-ether is bis-fluorenyl-1,2-bis-(trimethylsiloxy)-ethane.

Claim 11

A polymerizable mixture comprising a substance containing polymerizable carbon-carbon bonds and a silyl-ether of a tetraaryl-1,2-glycol.

Claim 12

A polymerizable mixture comprising a substance containing polymerizable carbon-carbon bonds and a silyl-ether of a tetraaryl-1,2-glycol.

Claim 13

A mixture as claimed in claim 10 wherein the silyl-ether is of the formula ##EQU3## in which A, B, D and E are each a member selected from the group consisting of an unsubstituted 2-naphthyl radical, an unsubstituted phenyl radical, a phenyl radical substituted in at least one of the 2-, 3-, 4-, 5- and 6-positions by chlorine or bromine, a phenyl radical having 6-18 carbon atoms substituted in at least one of the 2-, 3-, 4-, 5- and 6-positions by alkyl having up to 4 carbon atoms, a phenyl radical having 6-18 carbon atoms substituted in at least one of the 2-, 3-, 4-, 5- and 6-positions by alkoxy having up to 4 carbon atoms, a phenyl radical with 12 to 18 carbon atoms substituted in at least one of the 3-, 4- and 5-positions by phenyl, in which A and B and D and E may form together with the carbon atom to which they are attached the fluorenylidene radical, and in which X and Y are trialkyl-siloxy or triaryl-siloxy radicals.

Claim 14

A mixture as claimed in claim 11 wherein the silyl-ether is of the formula ##SPC2## in which R 1 is hydrogen, methyl, ethyl or methoxy; R 2 is hydrogen, methyl or ethyl; R 3 is hydrogen or methyl and R 4 is methyl.

Claim 15

A mixture as claimed in claim 11 wherein the silyl-ether is present in an amount of 0.05 to 0.08% by weight, based on the weight of the polymerizable substance.

Claim 16

A mixture as claimed in claim 11 wherein the polymerizable substance is a member selected from the group consisting of a mono-olefin, a conjugated diolefin, a vinyl-substituted benzene or a derivative thereof, a N-vinyl heterocycle, an α,β-olefinically unsaturated carboxylic acid or an ester, amide or nitrile thereof, a vinyl ester, a vinyl ketone, an allyl ester, a di(allylphenyl) carbonate, a vinyl halide, a vinylidene halide, a di(vinylphenyl) carbonate, a polyolacrylate, a polyol methacrylate, a N,N'-methylene-bis-acrylamide and a N,N'-methylene-bis-methacrylamide.

Claim 17

A mixture as claimed in claim 11 wherein the polymerizable substance is a mixture of an unsaturated polyester of a dihydric alcohol and α,β-unsaturated dicarboxylic acid and a copolymerizable ethylenically unsaturated monomer.

Claim 18

A mixture as claimed in claim 15 wherein the silyl-ether is tetra-(4-tolyl)-1,2-bis-(trimethylsiloxy)-ethane or diphenyl-di-(4-tolyl)-1,2-bis-(trimethylsiloxy)-ethane.

Claim 19

A mixture as claimed in claim 15 in the form of a molding or coating composition.

Claim 20

A mixture as claimed in claim 10 comprising methyl methacrylate and bis-fluorenyl-1,2-bis-(trimethylsiloxy)-ethane.