US3931249A
Expired / Lapsed
US
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Epoxidation using phthalocyanine catalysts
Assignee: Celanese Corp
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Filing: 1974-02-13
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Granted: 1976-01-06
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Expires: 1994-02-13
Abstract
Abstract A process for the epoxidation of ethylenically unsaturated compounds with organic hydroperoxides using metal-free phthalocyanines or metal phthalocyanines as catalysts. Suitable metals include those of the metals Ni, Cu, Ag, Ti, V, Zr, Mo. Re, or U.
Inventors
- 👤 Adin Lee Stautzenberger
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-11-09 08:54
CPC Classifications
C; C07; C07D; C07D301/00; C07D301/02; C07D301/03; C07D301/19; C07D303/00; C07D303/02; C07D303/04
Claims Analysis
Total Claims: 7
Claim 1
Independent Claim
138 words
In a process for the catalytic reaction of an organic hydroperoxide with an ethylenically unsaturated hydrocarbon of 3 to about 20 carbon atoms which is free of acetylenic unsaturation so as to introduce an oxirane oxygen at the site of an ethylenic double bond in said hydrocarbon, the improvement which comprises employing nickel phthalocyanine as catalyst for said reaction, the reaction being conducted in a reaction zone containing a liquid reaction medium consisting essentially of ethylenically-unsaturated hydrocarbon or mixtures of ethylenically-unsaturated hydrocarbon with an unreactive reaction solvent, together with said hydroperoxide and said catalyst, the reaction temperature being about 80° to 150°C, the reaction pressure being one which is high enough to keep said reaction medium in the liquid phase, and the concentration of nickel phthalocyanine in said reaction medium being at least about 10 - 6 molar.
Claim 2
Dependent Claim
138 words
In a process for the catalytic reaction of an organic hydroperoxide with an ethylenically unsaturated hydrocarbon of 3 to about 20 carbon atoms which is free of acetylenic unsaturation so as to introduce an oxirane oxygen at the site of an ethylenic double bond in said hydrocarbon, the improvement which comprises employing nickel phthalocyanine as catalyst for said reaction, the reaction being conducted in a reaction zone containing a liquid reaction medium consisting essentially of ethylenically-unsaturated hydrocarbon or mixtures of ethylenically-unsaturated hydrocarbon with an unreactive reaction solvent, together with said hydroperoxide and said catalyst, the reaction temperature being about 80° to 150°C, the reaction pressure being one which is high enough to keep said reaction medium in the liquid phase, and the concentration of nickel phthalocyanine in said reaction medium being at least about 10 - 6 molar.
Claim 3
Dependent Claim
21 words
The process of claim 1 wherein the hydrocarbon is an aliphatic or alicyclic hydrocarbon of 3 to about 20 carbon atoms.
Claim 4
Dependent Claim
32 words
The process of claim 1 wherein there are introduced into said reaction zone as reaction feedstocks about 0.8 to 10 ethylenic double bond moieties per mole of said organic hydroperoxide introduced thereinto.
Claim 5
Dependent Claim
36 words
The process of claim 3 wherein said organic hydroperoxide is of the formula R 2 --OOH wherein R 2 is a hydrocarbon, halo-substituted hydrocarbon, hydroxyl-substituted hydrocarbon, or nitro-substituted hydrocarbon of 3 to about 20 carbon atoms.
Claim 6
Dependent Claim
36 words
The process of claim 4 wherein said organic hydroperoxide is of the formula R 2 --OOH wherein R 2 is a hydrocarbon radical of 3 to about 20 carbon atoms free of ethylenic and acetylenic unsaturation.
Claim 7
Dependent Claim
30 words
The process of claim 5 wherein said ethylenically-unsaturated hydrocarbon is an aliphatic or alicyclic hydrocarbon of 3 to about 20 carbon atoms having in the molecule a single double bond.
References Cited (Backward Citations)
USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1979-01-05 | 1979-07-07 | 1980-01-06 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1983-01-05 | 1983-07-07 | 1984-01-06 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1987-01-05 | 1987-07-07 | 1988-01-06 | $7700.00 | Window Closed / Lapsed |