US3930792A
Expired / Lapsed
US
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Hair dyeing and conditioning compositions
Assignee: P&G Hair Care Holding Inc
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Filing: 1974-10-31
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Granted: 1976-01-06
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Expires: 1994-10-31
Abstract
Abstract A semi-permanent hair dye composition that simultaneously dyes and conditions hair to make it more manageable including a direct dyeing nitro dye capable of dyeing hair, certain quaternary amine compounds and certain N-oxyalkylated fatty acid amides.
Inventors
- 👤 George Alperin
- 👤 Richard DeMarco
- 👤 Raymond Feinland
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-11-02 13:25
CPC Classifications
A; A61; A61Q; A61Q5/00; A61Q5/06; A61Q5/065; A61K; A61K8/00; A61K8/18; A61K8/30; A61K8/40; A61K8/41; A61K8/416; A61K8/418; A61K8/45; A61Q5/12
Claims Analysis
Total Claims: 18
Claim 1
Independent Claim
176 words
An aqueous hair dye composition of the semi-permanent type comprising a. a tinctorial amount of a direct-dyeing nitroaminobenzene hair dye having good affinity for hair when applied at ambient temperatures; b. from about 0.1% to 3% by weight based on the total weight of the compositions of a hair-substantive quarternary amine compound of formula: ##EQU10## in which: i. R 1 , R 2 and R 3 are alkyl having from 1 to 3 carbons; ii. R is a long chain hydrocarbon having from 12 to 24 carbons; and iii. X is an anion; and c. from 0.2% to 3.5% by weight based on the total weight of the composition of a hair-substantive N-oxyalkylated fatty acid amide of formula: ##EQU11## in which: i. R 4 is a long chain hydrocarbon having from 12 to 24 carbons; ii. R 5 is hydrogen or (A'--O) x H in which A and A' are the same or different divalent alkylene having 2 to 4 carbons; and x and y are the same or different whole numbers from 1 to 100.
Claim 2
Dependent Claim
176 words
An aqueous hair dye composition of the semi-permanent type comprising a. a tinctorial amount of a direct-dyeing nitroaminobenzene hair dye having good affinity for hair when applied at ambient temperatures; b. from about 0.1% to 3% by weight based on the total weight of the compositions of a hair-substantive quarternary amine compound of formula: ##EQU10## in which: i. R 1 , R 2 and R 3 are alkyl having from 1 to 3 carbons; ii. R is a long chain hydrocarbon having from 12 to 24 carbons; and iii. X is an anion; and c. from 0.2% to 3.5% by weight based on the total weight of the composition of a hair-substantive N-oxyalkylated fatty acid amide of formula: ##EQU11## in which: i. R 4 is a long chain hydrocarbon having from 12 to 24 carbons; ii. R 5 is hydrogen or (A'--O) x H in which A and A' are the same or different divalent alkylene having 2 to 4 carbons; and x and y are the same or different whole numbers from 1 to 100.
Claim 3
Dependent Claim
13 words
A composition according to claim 1 in which anion X is ethyl sulfate.
Claim 4
Dependent Claim
17 words
A composition according to claim 1 in which the said quaternary amine compound is lauryldimethylethylammonium ethyl sulfate.
Claim 5
Dependent Claim
194 words
An aqueous hair dye composition of the semi-permanent type comprising a. a tinctorial amount of a direct-dyeing nitroaminobenzene hair dye having good affinity for hair when applied at ambient temperatures; b. from about 0.1% to 3% by weight based on the total weight of the composition of a hair-substantive quaternary amine compound of formula: ##EQU12## in which: i. R 1 , R 2 and R 3 are alkyl having from 1 to 3 carbons; ii. R is long chain hydrocarbon having from 12 to 24 carbons; and iii. X is an anion selected from the group consisting of hydroxide, chloride, bromide, iodide, fluoride, sulfate, nitrate, methyl sulfate, phosphate, acetate and sulfonate; and c. from 0.2% to 3.5% by weight based on the total weight of the composition of a hair-substantive N-oxyalkylated fatty acid amide of formula: ##EQU13## in which: i. R 4 is a long chain hydrocarbon having from 12 to 24 carbons; ii. R 5 is hydrogen or (A'--O) x H in which A and A' are the same or different divalent alkylene having 2 to 4 carbons; and x and y are the same or different whole numbers from 1 to 100.
Claim 6
Dependent Claim
194 words
An aqueous hair dye composition of the semi-permanent type comprising a. a tinctorial amount of a direct-dyeing nitroaminobenzene hair dye having good affinity for hair when applied at ambient temperatures; b. from about 0.1% to 3% by weight based on the total weight of the composition of a hair-substantive quaternary amine compound of formula: ##EQU12## in which: i. R 1 , R 2 and R 3 are alkyl having from 1 to 3 carbons; ii. R is long chain hydrocarbon having from 12 to 24 carbons; and iii. X is an anion selected from the group consisting of hydroxide, chloride, bromide, iodide, fluoride, sulfate, nitrate, methyl sulfate, phosphate, acetate and sulfonate; and c. from 0.2% to 3.5% by weight based on the total weight of the composition of a hair-substantive N-oxyalkylated fatty acid amide of formula: ##EQU13## in which: i. R 4 is a long chain hydrocarbon having from 12 to 24 carbons; ii. R 5 is hydrogen or (A'--O) x H in which A and A' are the same or different divalent alkylene having 2 to 4 carbons; and x and y are the same or different whole numbers from 1 to 100.
Claim 7
Dependent Claim
18 words
A composition according to claim 4 wherein R of said quaternary amine compound contains 16 to 18 carbons.
Claim 8
Dependent Claim
24 words
A composition according to claim 5 wherein a mixture of quaternary amine compounds of formula (1) in claim 4 is contained in the composition.
Claim 9
Dependent Claim
56 words
A composition according to claim 4 wherein the N-oxyalkylated fatty acid amide is of the polyoxyethylated type of formula: ##EQU14## in which R 4 has the same value ascribed to it in claim 4 and x and y are whole numbers, the sum of x + y being in the range of from 40 to 100.
Claim 10
Dependent Claim
18 words
A composition according to claim 4 wherein the nitroaminobenzene dye is N 4 ,N 4 -bis(2'-hydroxyethyl)-N 1 -methyl-2-nitro-p-phenylenediamine.
Claim 11
Dependent Claim
12 words
A composition according to claim 4 wherein the nitroaminobenzene dye is 1-anilino-4-amino-2-nitrobenzene.
Claim 12
Dependent Claim
12 words
A composition according to claim 4 wherein the nitroaminobenzene dye is N(2'-hydroxyethyl)-2-nitroaniline.
Claim 13
Dependent Claim
14 words
A composition according to claim 4 wherein the nitroaminobenzene dye is N 1 -(2'-hydroxyethyl)-2-nitro-p-phenylenediamine.
Claim 14
Dependent Claim
12 words
A composition according to claim 4 wherein the nitroaminobenzene dye is N,N-bis(2'-hydroxyethyl)-2-amino-5-nitrophenol.
Claim 15
Dependent Claim
18 words
A composition according to claim 4 wherein the nitroaminobenzene dye is N 1 ,N 4 ,N 4 -tris(2'-hydroxyethyl)-2-nitro-p-phenylenediamine.
Claim 16
Dependent Claim
56 words
A process for simultaneously dyeing conditioning hair which comprises applying the composition of claim 4 to hair and allowing said composition to remain in contact therewith for sufficient time to impart color to said hair and to condition the same whereby said hair becomes more manageable and there is an improvement in its sheen and texture.
Claim 17
Dependent Claim
213 words
An aqueous hair dye composition of the semi-permanent type comprising a. a tinctorial amount of a direct-dyeing nitroaminobenzene hair dye having good affinity for hair when applied at ambient temperatures; b. from about 0.1% to 3% by weight based on the total weight of the composition of a hair-substantive quaternary amine compound of formula: ##EQU15## in which: i. R 1 , R 2 and R 3 are alkyl having from 1 to 3 carbons; ii. R is long chain hydrocarbon selected from the group consisting of lauryl, myristyl, n-hexadecyl, oleyl, n-octadecyl, n-octadecenyl, n-octadecadienyl, arachidyl, behenyl and lignoceryl; iii. X is an anion selected from the group consisting of hydroxide, chloride, bromide, iodide, fluoride, sulfate, nitrate, methyl sulfate, phosphate, acetate and sulfonate; and c. from about 0.2% to 3.5% by weight based on the total weight of the composition of a hair-substantive N-oxyalkylated fatty acid amide of formula: ##EQU16## in which: i. R 4 is a long hydrocarbon selected from the group consisting of laurly, myristyl, palmityl, stearyl, behenyl, oleyl, linolyl, linolenyl; and ii. R 5 is hydrogen or (A'--O) x H in which A and A' are the same or different divalent alkylene having 2 to 4 carbons; and x and y are the same or different whole numbers from 1 to 100.
Claim 18
Dependent Claim
213 words
An aqueous hair dye composition of the semi-permanent type comprising a. a tinctorial amount of a direct-dyeing nitroaminobenzene hair dye having good affinity for hair when applied at ambient temperatures; b. from about 0.1% to 3% by weight based on the total weight of the composition of a hair-substantive quaternary amine compound of formula: ##EQU15## in which: i. R 1 , R 2 and R 3 are alkyl having from 1 to 3 carbons; ii. R is long chain hydrocarbon selected from the group consisting of lauryl, myristyl, n-hexadecyl, oleyl, n-octadecyl, n-octadecenyl, n-octadecadienyl, arachidyl, behenyl and lignoceryl; iii. X is an anion selected from the group consisting of hydroxide, chloride, bromide, iodide, fluoride, sulfate, nitrate, methyl sulfate, phosphate, acetate and sulfonate; and c. from about 0.2% to 3.5% by weight based on the total weight of the composition of a hair-substantive N-oxyalkylated fatty acid amide of formula: ##EQU16## in which: i. R 4 is a long hydrocarbon selected from the group consisting of laurly, myristyl, palmityl, stearyl, behenyl, oleyl, linolyl, linolenyl; and ii. R 5 is hydrogen or (A'--O) x H in which A and A' are the same or different divalent alkylene having 2 to 4 carbons; and x and y are the same or different whole numbers from 1 to 100.
References Cited (Backward Citations)
GB741334A
Cited
FR1137922A
Cited
GB889327A
Cited
GB956401A
Cited
US3555584A
Cited
US3629330A
Cited
US3577528A
Cited
USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1979-01-05 | 1979-07-07 | 1980-01-06 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1983-01-05 | 1983-07-07 | 1984-01-06 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1987-01-05 | 1987-07-07 | 1988-01-06 | $7700.00 | Window Closed / Lapsed |