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US3929974A Expired / Lapsed US ⏱️ 0.0 years remaining

Production of chlorine dioxide

Assignee: Sterling Canada Inc
•
Filing: 1973-11-19
•
Granted: 1975-12-30
•
Expires: 1993-11-19
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Abstract

Abstract A continuous cyclic process for the production of chlorine dioxide includes the formation of a gaseous mixture of chlorine dioxide, chlorine and steam from an aqueous reaction medium containing an alkali metal chlorate and hydrochloric acid. Chlorine dioxide is recovered from the gaseous mixture. An alkali metal chloride is formed in the reaction and is removed from the reaction vessel either as an aqueous solution with unreacted chlorate and hydrochloric acid or as deposited solid. The alkali metal chloride is electrolyzed in aqueous solution to alkali metal chlorate which is recycled to the reaction vessel.

Inventors

  • 👤 John D Winfield

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-29 14:15
CPC Classifications
C; C01; C01B; C01B7/00; C01B7/01; C01B7/012; C01B11/00; C01B11/02; C01B11/022; C01B11/023; C01B11/025; C01B7/03; C01B7/04

Claims Analysis

Total Claims: 5
Claim 1
Independent Claim 250 words
A PROCESS FOR THE PRODUCTION OF CHLORINE DIOXIDE WHICH COMPRISES CONTINUOUSLY FEEDING AN AQUEOUS SOLUTION OF AN ALKALI METAL CHLORATE AND HYDROCHLORIC ACID TO A REACTION ZONE TO MAINTAIN AN AQUEOUS REACTION MEDIUM IN SAID REACTION ZONE CONTAINING AN ALKALI METAL CHLORATE AND HYDROCHLORIC ACID AND HAVING AN ACIDITY OF ABOUT 0.05 TO ABOUT IN, CONTINUOUSLY FORMING CHLORINE DIOXIDE AND CHLORINE BY REACTION BETWEEN SAID ALKALI METAL CHLORATE AND SAID HYDROCHLORIC ACID IN SAID REACTION MEDIUM, CONTINUOUSLY MAINTAINING SAID REACTION ZONE UNDER A REDUCED PRESSURE, CONTINUOUSLY MAINTAINING SAID REACTION MEDIUM AT ITS BOILING POINT TO EVAPORATE WATER FROM SAID REACTION MEDIUM TO FORM CONTINUOUSLY A GASEOUS PHASE IN SAID REACTION ZONE CONSISTING OF A MIXTURE OF CHLORINE DIOXIDE, CHLORINE AND WATER VAPOR, AND TO DEPOSIT ALKALI METAL CHLORIDE IN SAID REACTION ZONE, CONTINUOUSLY CONDUCTING SAID GASEOUS PHASE MIXTURE OUT OF SAID REACTION ZONE, CONTINUOUSLY RECOVERING CHLORINE DIOXIDE FROM SAID MIXTURE, REMOVING DEPOSITED ALKALI METAL CHLORIDE FROM SAID REACTION ZONE, FORMING AN AQUEOUS SOLUTION FROM SAID REMOVED ALKALI METAL CHLORIDE, CONTINUOUSLY ELECTROLYZING SAID LATTER AQUEOUS SOLUTION TO CONVERT THE ALKALI METAL CHLORIDE AT LEAST PARTIALLY TO ALKALI METAL CHLORATE AND TO GENERATE HYDROGEN GAS, CONTINUOUSLY FEEDING AT LEAST THE ALKALI METAL CHLORATE CONTENT OF THE ALKALI METAL CHLORATE-CONTAINING SOLUTION TO SAID REACTION ZONE, CONTINUOUSLY REACTING AT LEAST PART OF SAID HYDROGEN GAS WITH CHLORINE GAS TO GENERATE HYDROGEN CHLORIDE, CONTINUOUSLY FORMING HYDROCHLORIC ACID FROM SAID HYDROGEN CHLORIDE AND CONTINUOUSLY FEEDING AT LEAST PART OF SAID HYDROCHLORIC ACID TO SAID REACTION ZONE.
Claim 2
Dependent Claim 250 words
A PROCESS FOR THE PRODUCTION OF CHLORINE DIOXIDE WHICH COMPRISES CONTINUOUSLY FEEDING AN AQUEOUS SOLUTION OF AN ALKALI METAL CHLORATE AND HYDROCHLORIC ACID TO A REACTION ZONE TO MAINTAIN AN AQUEOUS REACTION MEDIUM IN SAID REACTION ZONE CONTAINING AN ALKALI METAL CHLORATE AND HYDROCHLORIC ACID AND HAVING AN ACIDITY OF ABOUT 0.05 TO ABOUT IN, CONTINUOUSLY FORMING CHLORINE DIOXIDE AND CHLORINE BY REACTION BETWEEN SAID ALKALI METAL CHLORATE AND SAID HYDROCHLORIC ACID IN SAID REACTION MEDIUM, CONTINUOUSLY MAINTAINING SAID REACTION ZONE UNDER A REDUCED PRESSURE, CONTINUOUSLY MAINTAINING SAID REACTION MEDIUM AT ITS BOILING POINT TO EVAPORATE WATER FROM SAID REACTION MEDIUM TO FORM CONTINUOUSLY A GASEOUS PHASE IN SAID REACTION ZONE CONSISTING OF A MIXTURE OF CHLORINE DIOXIDE, CHLORINE AND WATER VAPOR, AND TO DEPOSIT ALKALI METAL CHLORIDE IN SAID REACTION ZONE, CONTINUOUSLY CONDUCTING SAID GASEOUS PHASE MIXTURE OUT OF SAID REACTION ZONE, CONTINUOUSLY RECOVERING CHLORINE DIOXIDE FROM SAID MIXTURE, REMOVING DEPOSITED ALKALI METAL CHLORIDE FROM SAID REACTION ZONE, FORMING AN AQUEOUS SOLUTION FROM SAID REMOVED ALKALI METAL CHLORIDE, CONTINUOUSLY ELECTROLYZING SAID LATTER AQUEOUS SOLUTION TO CONVERT THE ALKALI METAL CHLORIDE AT LEAST PARTIALLY TO ALKALI METAL CHLORATE AND TO GENERATE HYDROGEN GAS, CONTINUOUSLY FEEDING AT LEAST THE ALKALI METAL CHLORATE CONTENT OF THE ALKALI METAL CHLORATE-CONTAINING SOLUTION TO SAID REACTION ZONE, CONTINUOUSLY REACTING AT LEAST PART OF SAID HYDROGEN GAS WITH CHLORINE GAS TO GENERATE HYDROGEN CHLORIDE, CONTINUOUSLY FORMING HYDROCHLORIC ACID FROM SAID HYDROGEN CHLORIDE AND CONTINUOUSLY FEEDING AT LEAST PART OF SAID HYDROCHLORIC ACID TO SAID REACTION ZONE.
Claim 3
Dependent Claim 13 words
the process of claim 1 wherein said alkali metal chlorate is sodium chlorate.
Claim 4
Dependent Claim 29 words
The process of claim 1 including recovering chlorine from said gaseous mixture and utilizing said recovered chlorine as part of said chlorine reacting with hydrogen to generate hydrogen chloride.
Claim 5
Dependent Claim 16 words
The process of claim 1 wherein said acidity is from about 0.1 to about 0.2 normal.

References Cited (Backward Citations)

US2654656A Cited
US2664341A Cited
US3446584A Cited
US3404952A Cited
US3442778A Cited
US3516790A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1978-12-29 1979-06-30 1979-12-30 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1982-12-29 1983-06-30 1983-12-30 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1986-12-29 1987-06-30 1987-12-30 $7700.00 Window Closed / Lapsed

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