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US3929624A Expired / Lapsed US ⏱️ 0.0 years remaining

Reforming process using a uranium-containing catalyst

Assignee: BP PLC
•
Filing: 1973-01-26
•
Granted: 1975-12-30
•
Expires: 1993-01-26
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Abstract

Abstract A catalyst suitable for gasoline reforming has 0.01-5% wt of a Pt group metal and 0.01-5% wt of uranium on a silica-free alumina having a surface area of at least 150 m2 /g. Alkali metals, alkaline earth metals and Group VI A metals (other than U) are absent, but 0.01-5% wt of rhenium may also be present as may 0.01-5% wt of chlorine. Reforming using such catalysts is also claimed at 300*-600*C, 1-70 bars gauge, 0.01-10 v/v/hr and 0.0120:1 hydrogen: hydrogen mole ratio. The presence of uranium improves catalyst activity and stability to deactivation.

Inventors

  • 👤 Evan Ellis Davies
  • 👤 Christopher Ronald Pout

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-01 15:41
CPC Classifications
B; B01; B01J; B01J23/00; B01J23/38; B01J23/54; B01J23/56; B01J23/64; B01J23/656; B01J23/6567; B01J23/63; C; C10; C10G; C10G35/00; C10G35/04; C10G35/06; C10G35/085; C10G35/09

Claims Analysis

Total Claims: 5
Claim 1
Independent Claim 100 words
A PROCESS FOR THE REFORMING OF HYDROCARBONS BOILING IN THE RANGE 15*-204*C COMPRISING CONTACTING THE HYDROCARBONS UNDER REFORMING CONDITIONS OF 300* TO 600*C, 1 TO 70 BARS GAUGE, 0.1 TO 10 V/V/HR AND 0.1 TO 20:1 HYDROGEN: HYDROCARBON MOLE RATIO WITH A CATALYST COMPRISING FROM 0.01 TO 5% WT. OF A PLATINUM GROUP METAL, 0.01 TO 5% WT. OF URANIUM, 0.1 TO 2% WT. OF RHENIUM, AND A SILICA-FREE ALUMINA HAVING A SURFACE AREA OF AT LEAST 150 M2/G, SAID CATALYST BEING FREE OF ALKALI METALS AND ALKALINE EARTH METALS AND OTHER METALS OF GROUP VIA OF THE PERIODIC TABLE.
Claim 2
Dependent Claim 100 words
A PROCESS FOR THE REFORMING OF HYDROCARBONS BOILING IN THE RANGE 15*-204*C COMPRISING CONTACTING THE HYDROCARBONS UNDER REFORMING CONDITIONS OF 300* TO 600*C, 1 TO 70 BARS GAUGE, 0.1 TO 10 V/V/HR AND 0.1 TO 20:1 HYDROGEN: HYDROCARBON MOLE RATIO WITH A CATALYST COMPRISING FROM 0.01 TO 5% WT. OF A PLATINUM GROUP METAL, 0.01 TO 5% WT. OF URANIUM, 0.1 TO 2% WT. OF RHENIUM, AND A SILICA-FREE ALUMINA HAVING A SURFACE AREA OF AT LEAST 150 M2/G, SAID CATALYST BEING FREE OF ALKALI METALS AND ALKALINE EARTH METALS AND OTHER METALS OF GROUP VIA OF THE PERIODIC TABLE.
Claim 3
Dependent Claim 26 words
A process as claimed in claim 1 wherein the catalyst comprises from 0.1 to 2% wt of platinum and from 0.1 to 2% wt of uranium.
Claim 4
Dependent Claim 18 words
A process as claimed in claim 1 wherein the catalyst contains from 0.1 to 3% wt of chlorine.
Claim 5
Dependent Claim 30 words
A process as claimed in claim 1 which is operated at 400* to 550*C, 3 to 35 bars gauge, 0.5 to 5 v/v/hr and 1 to 10:1 hydrogen:hydrocarbon mole ratio.

References Cited (Backward Citations)

US2500146A Cited
US2861959A Cited
US2939837A Cited
US3042628A Cited
US2915515A Cited
US3619127A Cited
US3579589A Cited
US3617491A Cited
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USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1978-12-29 1979-06-30 1979-12-30 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1982-12-29 1983-06-30 1983-12-30 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1986-12-29 1987-06-30 1987-12-30 $7700.00 Window Closed / Lapsed

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