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US3929615A Expired / Lapsed US ⏱️ 0.0 years remaining

Production of hydrocarbon gases from oil shale

Assignee: American Gas Association Inc
•
Filing: 1973-10-26
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Granted: 1975-12-30
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Expires: 1993-10-26
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Abstract

Abstract A process for the production of hydrocarbon gases from oil shale comprising the steps of gradually preheating oil shale in a preheat and prehydrogenation zone to a temperature of about 700* to about 950* F. in the presence of hydrogen-rich gas without substantial production of liquid or gas in the preheat and prehydrogenation zone, then hydrogasifying the preheated and prehydrogenated oil shale in a hydrogasification zone at a temperature of about 1,200* to about 1,500* F. in the presence of hydrogen-rich gas to form predominately low molecular weight paraffinic hydrocarbon gases from the preheated and prehydrogenated organic hydrocarbon portion of the oil shale. The hydrogen-rich gas may be passed countercurrent in thermal exchange relation to the spent shale to recover heat from the spent shale heating the hydrogen-rich gas for passage countercurrent and in thermal exchange relation to fresh oil shale in the preheat and prehydrogenation zone. The improvement of this process lies in the exceptionally high conversion of the organic component of oil shale to products of high value having high content of low molecular weight paraffinic hydrocarbon gases.

Inventors

  • 👤 Henry R Linden
  • 👤 Paul B Tarman
  • 👤 Harlan L Feldkirchner

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-30 19:01
CPC Classifications
C; C10; C10B; C10B53/00; C10B53/06

Claims Analysis

Total Claims: 13
Claim 1
Independent Claim 246 words
IN THE PROCESS FOR THE PRODUCTION OF PIPELINE QUALITY GAS BY GASIFICATION OF ORGANIC COMPONENTS OF OIL SHALE WHEREIN ABOVE ABOUT 77 PERCENT OF THE ORGANIC CARBON IN SAID OIL SHALE IS CONVERTED TO LIQUIDS AND GASES THE IMPROVEMENT COMPRISING: INTRODUCING FRESH OIL SHALE INTO A PREHEAT AND PREHYDROGENATION ZONE; GRADUALLY PREHEATING OIL SHALE IN A PREHEAT AND PREHYDROGENATION ZONE TO A TEMPERATURE OF ABOUT 700* TO ABOUT 950*F. IN THE PRESENCE OF HYDROGEN-RICH GAS WITH LESS THAN ABOUT 20 WEIGHT PERCENT OF THE ORGANIC COMPONENT OF OIL SHALE CONVERTED TO LIQUID AND GAS IN SAID PREHEAT AND PREHYDROGENATION ZONE, SAID OF LESS THAN ABOUT 50*F. PER MINUTE ABOVE AND ABOUT 500* TO 600*F. AND SAID HYDROGEN-RICH GAS AND SHALE PASSING COUNTERCURRENTLY IN SAID PREHEAT AND PREHYDROGENATION ZONE; HYDROGASIFYING THE PREHATED AND PREHYDROGENATED ORGANIC COMPONENTS OF OIL SHALE IN A HYDROGASIFICATION ZONE AT A TEMPERATURE OF ABOUT 1200* TO ABOUT 1500*F. IN HE PRESENCE OF AT LEAST A STOICHIOMETRIC AMOUNT OF HYDROGEN-RICH GAS TO FORM LOW MOLECULAR WEIGHT PARRAFINIC GASES AND LIQUID HYDROCARBONS FROM THE PREHEATED AND PREHYDROGENATED ORGANIC PORTION OF SAID OIL SHALE; SAID HYDROGEN-RICH GAS BEING SUPPLIED TO SAID PREHEAT AND PREHYDROGENATION ZONE IN LARGER VOLUMES THAN THE HYDROGEN-RICH GAS SUUPPLIED TO SAID HYDROGASIFICATION ZONE SEPAREMOVING SPENT SHALE FROM THE HYDROGASIFICATION ZONE SEPARATE FROM SAID GASES; AND PURIFYING AND UPGRADING SAID GASES BY REMOVING LIQUIDS AND UNDESIRED STEAM, CARBON MONOXIDE, CARBON DIOXIDDE, AMMONIA AND HYDROGEN SULFIDE FOLLOWED BY METHANATION TO PROVIDE PIPELINE QUALITY GAS.
Claim 2
Dependent Claim 246 words
IN THE PROCESS FOR THE PRODUCTION OF PIPELINE QUALITY GAS BY GASIFICATION OF ORGANIC COMPONENTS OF OIL SHALE WHEREIN ABOVE ABOUT 77 PERCENT OF THE ORGANIC CARBON IN SAID OIL SHALE IS CONVERTED TO LIQUIDS AND GASES THE IMPROVEMENT COMPRISING: INTRODUCING FRESH OIL SHALE INTO A PREHEAT AND PREHYDROGENATION ZONE; GRADUALLY PREHEATING OIL SHALE IN A PREHEAT AND PREHYDROGENATION ZONE TO A TEMPERATURE OF ABOUT 700* TO ABOUT 950*F. IN THE PRESENCE OF HYDROGEN-RICH GAS WITH LESS THAN ABOUT 20 WEIGHT PERCENT OF THE ORGANIC COMPONENT OF OIL SHALE CONVERTED TO LIQUID AND GAS IN SAID PREHEAT AND PREHYDROGENATION ZONE, SAID OF LESS THAN ABOUT 50*F. PER MINUTE ABOVE AND ABOUT 500* TO 600*F. AND SAID HYDROGEN-RICH GAS AND SHALE PASSING COUNTERCURRENTLY IN SAID PREHEAT AND PREHYDROGENATION ZONE; HYDROGASIFYING THE PREHATED AND PREHYDROGENATED ORGANIC COMPONENTS OF OIL SHALE IN A HYDROGASIFICATION ZONE AT A TEMPERATURE OF ABOUT 1200* TO ABOUT 1500*F. IN HE PRESENCE OF AT LEAST A STOICHIOMETRIC AMOUNT OF HYDROGEN-RICH GAS TO FORM LOW MOLECULAR WEIGHT PARRAFINIC GASES AND LIQUID HYDROCARBONS FROM THE PREHEATED AND PREHYDROGENATED ORGANIC PORTION OF SAID OIL SHALE; SAID HYDROGEN-RICH GAS BEING SUPPLIED TO SAID PREHEAT AND PREHYDROGENATION ZONE IN LARGER VOLUMES THAN THE HYDROGEN-RICH GAS SUUPPLIED TO SAID HYDROGASIFICATION ZONE SEPAREMOVING SPENT SHALE FROM THE HYDROGASIFICATION ZONE SEPARATE FROM SAID GASES; AND PURIFYING AND UPGRADING SAID GASES BY REMOVING LIQUIDS AND UNDESIRED STEAM, CARBON MONOXIDE, CARBON DIOXIDDE, AMMONIA AND HYDROGEN SULFIDE FOLLOWED BY METHANATION TO PROVIDE PIPELINE QUALITY GAS.
Claim 3
Dependent Claim 58 words
The process of claim 1 wherein spent shale is passed from said hydrogasification zone to a heat recovery zone wherein hydrogen-rich gas recycled from said preheat and prehydrogenation zone passes countercurrent and in thermal exchange relation to said spent shale cooling the spent shale and heating the hydrogen-rich gas for introduction directly to said preheat and prehydrogenation zone.
Claim 4
Dependent Claim 26 words
The process of claim 2 wherein said heated hydrogen-rich gas is further heated during passage from said heat recovery zone to said preheat and prehydrogenation zone.
Claim 5
Dependent Claim 53 words
The process of claim 2 wherein the hydrogenrich gas stream leaving said preheat and prehydrogenation zone is split, with one portion, containing sufficient gas to provide at least the chemical hydrogen requirements in the hydrogasification zone, being passed to said hydrogasification zone and the other portion being recycled to said heat recovery zone.
Claim 6
Dependent Claim 22 words
The process of claim 4 wherein said one portion of hydrogen-rich gas stream is further heated during passage to said hydrogasification zone.
Claim 7
Dependent Claim 23 words
The process of claim 1 wherein the oil shale is preheated to about 750* to abOut 850*F. in said preheat and prehydrogenation zone.
Claim 8
Dependent Claim 24 words
The process of claim 1 wherein the preheated and prehydrogenated oil shale is heated to about 1300* to about 1400*F. in said hydrogasification zone.
Claim 9
Dependent Claim 16 words
The process of claim 7 wherein said hydrogasification zone is heated by methanation of carbon dioxide.
Claim 10
Dependent Claim 26 words
The process of claim 7 wherein the input hydrogen-rich gas to the hydrogasification zone is heated by thermal exchange with the output of the hydrogasification zone.
Claim 11
Dependent Claim 28 words
The process of claim 1 wherein the preheat and prehydrogenation zone and the hydrogasification zone is at a total gas pressure of about 100 to about 2000 psia.
Claim 12
Dependent Claim 17 words
The process of claim 10 wherein said total gas pressure is about 500 to about 1500 psia.
Claim 13
Dependent Claim 26 words
The process of claim 1 wherein the preheat and prehydrogenation zone and the hydrogasification zone is maintained at a hydrogen partial pressure above about 20 psia.

References Cited (Backward Citations)

US3118746A Cited
US2991164A Cited
US3347647A Cited
US3484364A Cited
US3556979A Cited
US3619405A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1978-12-29 1979-06-30 1979-12-30 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1982-12-29 1983-06-30 1983-12-30 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1986-12-29 1987-06-30 1987-12-30 $7700.00 Window Closed / Lapsed

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