Claims Analysis
Total Claims: 13
Claim 1
Independent Claim
246 words
IN THE PROCESS FOR THE PRODUCTION OF PIPELINE QUALITY GAS BY GASIFICATION OF ORGANIC COMPONENTS OF OIL SHALE WHEREIN ABOVE ABOUT 77 PERCENT OF THE ORGANIC CARBON IN SAID OIL SHALE IS CONVERTED TO LIQUIDS AND GASES THE IMPROVEMENT COMPRISING: INTRODUCING FRESH OIL SHALE INTO A PREHEAT AND PREHYDROGENATION ZONE; GRADUALLY PREHEATING OIL SHALE IN A PREHEAT AND PREHYDROGENATION ZONE TO A TEMPERATURE OF ABOUT 700* TO ABOUT 950*F. IN THE PRESENCE OF HYDROGEN-RICH GAS WITH LESS THAN ABOUT 20 WEIGHT PERCENT OF THE ORGANIC COMPONENT OF OIL SHALE CONVERTED TO LIQUID AND GAS IN SAID PREHEAT AND PREHYDROGENATION ZONE, SAID OF LESS THAN ABOUT 50*F. PER MINUTE ABOVE AND ABOUT 500* TO 600*F. AND SAID HYDROGEN-RICH GAS AND SHALE PASSING COUNTERCURRENTLY IN SAID PREHEAT AND PREHYDROGENATION ZONE; HYDROGASIFYING THE PREHATED AND PREHYDROGENATED ORGANIC COMPONENTS OF OIL SHALE IN A HYDROGASIFICATION ZONE AT A TEMPERATURE OF ABOUT 1200* TO ABOUT 1500*F. IN HE PRESENCE OF AT LEAST A STOICHIOMETRIC AMOUNT OF HYDROGEN-RICH GAS TO FORM LOW MOLECULAR WEIGHT PARRAFINIC GASES AND LIQUID HYDROCARBONS FROM THE PREHEATED AND PREHYDROGENATED ORGANIC PORTION OF SAID OIL SHALE; SAID HYDROGEN-RICH GAS BEING SUPPLIED TO SAID PREHEAT AND PREHYDROGENATION ZONE IN LARGER VOLUMES THAN THE HYDROGEN-RICH GAS SUUPPLIED TO SAID HYDROGASIFICATION ZONE SEPAREMOVING SPENT SHALE FROM THE HYDROGASIFICATION ZONE SEPARATE FROM SAID GASES; AND PURIFYING AND UPGRADING SAID GASES BY REMOVING LIQUIDS AND UNDESIRED STEAM, CARBON MONOXIDE, CARBON DIOXIDDE, AMMONIA AND HYDROGEN SULFIDE FOLLOWED BY METHANATION TO PROVIDE PIPELINE QUALITY GAS.
Claim 2
Dependent Claim
246 words
IN THE PROCESS FOR THE PRODUCTION OF PIPELINE QUALITY GAS BY GASIFICATION OF ORGANIC COMPONENTS OF OIL SHALE WHEREIN ABOVE ABOUT 77 PERCENT OF THE ORGANIC CARBON IN SAID OIL SHALE IS CONVERTED TO LIQUIDS AND GASES THE IMPROVEMENT COMPRISING: INTRODUCING FRESH OIL SHALE INTO A PREHEAT AND PREHYDROGENATION ZONE; GRADUALLY PREHEATING OIL SHALE IN A PREHEAT AND PREHYDROGENATION ZONE TO A TEMPERATURE OF ABOUT 700* TO ABOUT 950*F. IN THE PRESENCE OF HYDROGEN-RICH GAS WITH LESS THAN ABOUT 20 WEIGHT PERCENT OF THE ORGANIC COMPONENT OF OIL SHALE CONVERTED TO LIQUID AND GAS IN SAID PREHEAT AND PREHYDROGENATION ZONE, SAID OF LESS THAN ABOUT 50*F. PER MINUTE ABOVE AND ABOUT 500* TO 600*F. AND SAID HYDROGEN-RICH GAS AND SHALE PASSING COUNTERCURRENTLY IN SAID PREHEAT AND PREHYDROGENATION ZONE; HYDROGASIFYING THE PREHATED AND PREHYDROGENATED ORGANIC COMPONENTS OF OIL SHALE IN A HYDROGASIFICATION ZONE AT A TEMPERATURE OF ABOUT 1200* TO ABOUT 1500*F. IN HE PRESENCE OF AT LEAST A STOICHIOMETRIC AMOUNT OF HYDROGEN-RICH GAS TO FORM LOW MOLECULAR WEIGHT PARRAFINIC GASES AND LIQUID HYDROCARBONS FROM THE PREHEATED AND PREHYDROGENATED ORGANIC PORTION OF SAID OIL SHALE; SAID HYDROGEN-RICH GAS BEING SUPPLIED TO SAID PREHEAT AND PREHYDROGENATION ZONE IN LARGER VOLUMES THAN THE HYDROGEN-RICH GAS SUUPPLIED TO SAID HYDROGASIFICATION ZONE SEPAREMOVING SPENT SHALE FROM THE HYDROGASIFICATION ZONE SEPARATE FROM SAID GASES; AND PURIFYING AND UPGRADING SAID GASES BY REMOVING LIQUIDS AND UNDESIRED STEAM, CARBON MONOXIDE, CARBON DIOXIDDE, AMMONIA AND HYDROGEN SULFIDE FOLLOWED BY METHANATION TO PROVIDE PIPELINE QUALITY GAS.
Claim 3
Dependent Claim
58 words
The process of claim 1 wherein spent shale is passed from said hydrogasification zone to a heat recovery zone wherein hydrogen-rich gas recycled from said preheat and prehydrogenation zone passes countercurrent and in thermal exchange relation to said spent shale cooling the spent shale and heating the hydrogen-rich gas for introduction directly to said preheat and prehydrogenation zone.
Claim 4
Dependent Claim
26 words
The process of claim 2 wherein said heated hydrogen-rich gas is further heated during passage from said heat recovery zone to said preheat and prehydrogenation zone.
Claim 5
Dependent Claim
53 words
The process of claim 2 wherein the hydrogenrich gas stream leaving said preheat and prehydrogenation zone is split, with one portion, containing sufficient gas to provide at least the chemical hydrogen requirements in the hydrogasification zone, being passed to said hydrogasification zone and the other portion being recycled to said heat recovery zone.
Claim 6
Dependent Claim
22 words
The process of claim 4 wherein said one portion of hydrogen-rich gas stream is further heated during passage to said hydrogasification zone.
Claim 7
Dependent Claim
23 words
The process of claim 1 wherein the oil shale is preheated to about 750* to abOut 850*F. in said preheat and prehydrogenation zone.
Claim 8
Dependent Claim
24 words
The process of claim 1 wherein the preheated and prehydrogenated oil shale is heated to about 1300* to about 1400*F. in said hydrogasification zone.
Claim 9
Dependent Claim
16 words
The process of claim 7 wherein said hydrogasification zone is heated by methanation of carbon dioxide.
Claim 10
Dependent Claim
26 words
The process of claim 7 wherein the input hydrogen-rich gas to the hydrogasification zone is heated by thermal exchange with the output of the hydrogasification zone.
Claim 11
Dependent Claim
28 words
The process of claim 1 wherein the preheat and prehydrogenation zone and the hydrogasification zone is at a total gas pressure of about 100 to about 2000 psia.
Claim 12
Dependent Claim
17 words
The process of claim 10 wherein said total gas pressure is about 500 to about 1500 psia.
Claim 13
Dependent Claim
26 words
The process of claim 1 wherein the preheat and prehydrogenation zone and the hydrogasification zone is maintained at a hydrogen partial pressure above about 20 psia.