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US3928267A Expired / Lapsed US ⏱️ 0.0 years remaining

Liquid stabilizer system for polyvinyl chloride

Assignee: Henkel Corp
•
Filing: 1973-03-05
•
Granted: 1975-12-23
•
Expires: 1993-03-05
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Abstract

Abstract Homogeneous liquid stabilizer compositions are provided which are useful with polyvinyl chloride resins to impart improved antistatic and antifogging properties in addition to stabilizing the resins. The stabilizer solutions are obtained using a specific procedure for blending the individual stabilizer components.

Inventors

  • 👤 Philip H Rhodes
  • 👤 Robert L Ahr

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-27 15:35
CPC Classifications
C; C08; C08K; C08K5/00; C08K5/04; C08K5/15; C08K5/151; C08K5/1515; C08J; C08J3/00; C08J3/20; C08J3/22; C08K5/49; C08K5/51; C08K5/52; C08K5/524; C08J2357/00; Y; Y10; Y10S; Y10S524/00; Y10S524/91; Y10S524/912

Claims Analysis

Total Claims: 16
Claim 1
Independent Claim 19 words
A METHOD FOR STABILIZING VINYL POLYMER RESIN TO IMPART ANTIFOGGING AND ANTISTATIC PROPERTIES AND IMPROVE HEAT STABILITY WHICH COMPRISES:
Claim 2
Independent Claim 19 words
A METHOD FOR STABILIZING VINYL POLYMER RESIN TO IMPART ANTIFOGGING AND ANTISTATIC PROPERTIES AND IMPROVE HEAT STABILITY WHICH COMPRISES:
Claim 3
Dependent Claim 62 words
ADMIXING AT A TEMPERTURE OF 100*C TO 200*C UNTIL SOLUTION HAS BEEN EFFECTED (A) 5 TO 50 PARTS BY WEIGHT ALIPHATIC OR CYCLOALIPHATIC EPOXY COMPOUND CONTAINING FROM 10 TO 180 CARBON ATOMS, (B) 1 TO 35 PARTS POLYVALENT METAL SALT OF A MONOCARBOYLIC ACID CONTAINING FROM 6 TO 26 CARBON ATOMS AND (C) 10 TO 80 PARTS ORGANOPHOSPHOROUS COMPOUND OF THE FORMULA
Claim 4
Dependent Claim 62 words
ADMIXING AT A TEMPERTURE OF 100*C TO 200*C UNTIL SOLUTION HAS BEEN EFFECTED (A) 5 TO 50 PARTS BY WEIGHT ALIPHATIC OR CYCLOALIPHATIC EPOXY COMPOUND CONTAINING FROM 10 TO 180 CARBON ATOMS, (B) 1 TO 35 PARTS POLYVALENT METAL SALT OF A MONOCARBOYLIC ACID CONTAINING FROM 6 TO 26 CARBON ATOMS AND (C) 10 TO 80 PARTS ORGANOPHOSPHOROUS COMPOUND OF THE FORMULA
Claim 5
Dependent Claim 41 words
ADDING 35 TO 85 PARTS OF A PARTIAL ESTER OF A POLYGLYCEROL HAVING NOT MORE THAN 75% OF THE POLYGLYCEROL HYDROXYL GROUPS REACTED AND DERIVED FROM A C6-24 MONOCARBOXYLI ACID AND A POLYGLYCEROL CONTAINING 2 TO 30 CONDENSED GLYCEROL UNITS; AND
Claim 6
Dependent Claim 41 words
ADDING 35 TO 85 PARTS OF A PARTIAL ESTER OF A POLYGLYCEROL HAVING NOT MORE THAN 75% OF THE POLYGLYCEROL HYDROXYL GROUPS REACTED AND DERIVED FROM A C6-24 MONOCARBOXYLI ACID AND A POLYGLYCEROL CONTAINING 2 TO 30 CONDENSED GLYCEROL UNITS; AND
Claim 7
Dependent Claim 100 words
The method of claim 1 where in step (1) the temperature does not exceed 165*C, (a) contains from 20 to 150 carbon atoms, (b) is the zinc salf or a mixture of calcium and zinc salts of an aliphatic monocarboxylic acid containing from 12 to 20 carbon atoms, (c) is a phosphite compound with R groups containing 6 to 20 carbon atoms and the polyglycerol partial ester has less than 50% of the polyglycerol hydroxyl groups reacted and is derived from a fatty acid containing 8 to 18 carbon atoms and a polyglycerol containing 2 to 20 condensed glycerol units.
Claim 8
Dependent Claim 41 words
adding 35 to 85 parts of a partial ester of a polyglycerol having not more than 75% of the polyglycerol hydroxyl groups reacted and derived from a C6-24 monocarboxylic acid and a polyglycerol containing 2 to 30 condensed glycerol units; and
Claim 9
Dependent Claim 41 words
adding 35 to 85 parts of a partial ester of a polyglycerol having not more than 75% of the polyglycerol hydroxyl groups reacted and derived from a C6-24 monocarboxylic acid and a polyglycerol containing 2 to 30 condensed glycerol units; and
Claim 10
Dependent Claim 20 words
incorporating 0.5 to 25 parts by weight of the resulting liquid stabilizer into 100 parts polyvinyl chloride homopolymer or copolymer.
Claim 11
Dependent Claim 20 words
incorporating 0.5 to 25 parts by weight of the resulting liquid stabilizer into 100 parts polyvinyl chloride homopolymer or copolymer.
Claim 12
Dependent Claim 24 words
The method of claim 2 wherein 2 to 6 parts by weight of the liquid stabilizer is incorporated into a film-forming polyvinyl chloride polymer.
Claim 13
Dependent Claim 20 words
INCORPORATING 0.5 TO 25 PARTS BY WEIGHT OF THE RESULTING LIQUID STABILIZER INTO 100 PARTS POLYVINYL CHLORIDE HOMOPOLYMER OR COPOLYMER.
Claim 14
Dependent Claim 20 words
INCORPORATING 0.5 TO 25 PARTS BY WEIGHT OF THE RESULTING LIQUID STABILIZER INTO 100 PARTS POLYVINYL CHLORIDE HOMOPOLYMER OR COPOLYMER.
Claim 15
Dependent Claim 22 words
The method of claim 3 wherein (a) is an epoxidized naturally occuring oil, (b) is zinc stearate and (c) is tri(nonylphenyl) phosphite.
Claim 16
Dependent Claim 7 words
The stabilized resin composition of claim 1.

References Cited (Backward Citations)

US2711401A Cited
US2997454A Cited
US3255136A Cited
US3202622A Cited
US3558537A Cited
US3575905A Cited
US3640953A Cited
US3682853A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1978-12-22 1979-06-23 1979-12-23 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1982-12-22 1983-06-23 1983-12-23 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1986-12-22 1987-06-23 1987-12-23 $7700.00 Window Closed / Lapsed

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