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US3927142A Expired / Lapsed US ⏱️ 0.0 years remaining

Process for the preparation impact resistant styrene polymers

Assignee: Shell Internationale Research Maatschappij BV
•
Filing: 1973-12-19
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Granted: 1975-12-16
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Expires: 1993-12-19
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Abstract

Abstract An improved polymer and a process for the preparation of impact resistant styrene graft copolymers. Ethylene-propylenetercomponent-rubber is dissolved in styrene, then acrylonitrile is added to a styrene to acrylo-nitrile ratio of 6/1 to 4/1, the polymerization is carried out in the mass until the end of the phase transition, further acrylonitrile, and optionally further styrene, is added and the polymerization is completed in the mass or in suspension.

Inventors

  • 👤 Wolfgang Strobel
  • 👤 Ottokar Jaenicke
  • 👤 Horst-Dieter Schuddemage
  • 👤 Horst Jastrow

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-03 08:13
CPC Classifications
C; C08; C08F; C08F255/00; C08F255/02; C08F255/06

Claims Analysis

Total Claims: 8
Claim 1
Independent Claim 273 words
PROCESS FOR THE PREPARATION OF IMPACT RESISTANT STYRENE GRAFT COPOLYMERS BY POLYMERIZATION OF A. 98 TO 80 PERCENT BY WEIGHT OF A MIXTURE OF AA. 90 TO 70 PERCENT BY WEIGHT OF AT LEAST ONE MONOMER SELECTED FROM THE GROUP CONSISTING OF STYRENE, VINYL TOLUENE, VINYL XYLENE, CHLORO-STYRENE, BROMO-STYRENE, VINYLCYCLOHEXANE, METHYLVINYLCYCLOHEXANE AND HALOGENVINYL CYCLOHEXANE WITH AB. 10 TO 30 PERCENT BY WEIGHT OF AT LEAST ONE MONOMER SELECTED FROM THE GROUP CONSISTING OF ACRYLONITRILE, METHACRYLONITRILE, A LOW ALIPHATIC ALCOHOL ESTER OF ACRYLIC ACID, METHACRYLIC ACID, ITACONIC ACID, MALEIC ACID, AND FUMARIC ACID IN ADMIXTURE WITH B. 2 TO 20 PERCENT BY WEIGHT OF AN ETHYLENEPROPYLENE-TERCOMPONENT-RUBBER, (AA) AND (AB) BEING CALCULATED, IN PERCENT BY WEIGHT, ON THE TOTAL QUANTITY OF THE MONOMERS (AA) + (AB) AND (A) AND (B) ON THE TOTAL QUANTITY OF MONOMERS A) $(=AA) + (AB) + RUBBER (B), IN THE PRESENCE OF AT LEAST ONE MONOMER SOLUBLE, ORGANIC PEROXIDE IN THE MASS OR IN MASS/SUSPENSION, WHEREIN THE MIXTURE OF (AA) AND (AB) WITH (B) IS POLYMERIZED, AFTER DISSOLVING THE ETHYLENE-PROPYLENE-TER-COMPONENT-RUBBER IN AT LEAST ONE MEMBER OF SAID GROUP RECITED IN (AA), AND THEREAFTER ADDING AT LEAST ONE MEMBER OF SAID GROUP RECITED IN (AB) WITHIN AN (AA) / (AB) RATIO, IN PERCENT BY WEIGHT, OF 6/1 TO 4// AT A TEMPERATURE OF 85* TO 115*C, UNTIL THE END OF THE PHASE TRANSITION, AND THE POLYMERIZATION IS COMPLETED AFTER A FURTHER ADDITION OF I. AT LEAST ONE MONOMER FROM THE GROUP CONSISTING OF MONOMERS, RECITED IN (AA) OR (AB) OR II. A MIXTURE OF (AA) AND (AB) FOR THE POLYMERIZATION MASS TO FALL WITHIN THE RECITED RATIO OF AA) TO AB).
Claim 2
Dependent Claim 273 words
PROCESS FOR THE PREPARATION OF IMPACT RESISTANT STYRENE GRAFT COPOLYMERS BY POLYMERIZATION OF A. 98 TO 80 PERCENT BY WEIGHT OF A MIXTURE OF AA. 90 TO 70 PERCENT BY WEIGHT OF AT LEAST ONE MONOMER SELECTED FROM THE GROUP CONSISTING OF STYRENE, VINYL TOLUENE, VINYL XYLENE, CHLORO-STYRENE, BROMO-STYRENE, VINYLCYCLOHEXANE, METHYLVINYLCYCLOHEXANE AND HALOGENVINYL CYCLOHEXANE WITH AB. 10 TO 30 PERCENT BY WEIGHT OF AT LEAST ONE MONOMER SELECTED FROM THE GROUP CONSISTING OF ACRYLONITRILE, METHACRYLONITRILE, A LOW ALIPHATIC ALCOHOL ESTER OF ACRYLIC ACID, METHACRYLIC ACID, ITACONIC ACID, MALEIC ACID, AND FUMARIC ACID IN ADMIXTURE WITH B. 2 TO 20 PERCENT BY WEIGHT OF AN ETHYLENEPROPYLENE-TERCOMPONENT-RUBBER, (AA) AND (AB) BEING CALCULATED, IN PERCENT BY WEIGHT, ON THE TOTAL QUANTITY OF THE MONOMERS (AA) + (AB) AND (A) AND (B) ON THE TOTAL QUANTITY OF MONOMERS A) $(=AA) + (AB) + RUBBER (B), IN THE PRESENCE OF AT LEAST ONE MONOMER SOLUBLE, ORGANIC PEROXIDE IN THE MASS OR IN MASS/SUSPENSION, WHEREIN THE MIXTURE OF (AA) AND (AB) WITH (B) IS POLYMERIZED, AFTER DISSOLVING THE ETHYLENE-PROPYLENE-TER-COMPONENT-RUBBER IN AT LEAST ONE MEMBER OF SAID GROUP RECITED IN (AA), AND THEREAFTER ADDING AT LEAST ONE MEMBER OF SAID GROUP RECITED IN (AB) WITHIN AN (AA) / (AB) RATIO, IN PERCENT BY WEIGHT, OF 6/1 TO 4// AT A TEMPERATURE OF 85* TO 115*C, UNTIL THE END OF THE PHASE TRANSITION, AND THE POLYMERIZATION IS COMPLETED AFTER A FURTHER ADDITION OF I. AT LEAST ONE MONOMER FROM THE GROUP CONSISTING OF MONOMERS, RECITED IN (AA) OR (AB) OR II. A MIXTURE OF (AA) AND (AB) FOR THE POLYMERIZATION MASS TO FALL WITHIN THE RECITED RATIO OF AA) TO AB).
Claim 3
Dependent Claim 43 words
The process as defined in claim 1 and wherein the polymerization is completed after a further addition of at least one member of said group recited in (aa) or (ab) for the polymer to fall within the recited ratio of (aa) to (ab).
Claim 4
Dependent Claim 35 words
The process as claimed in claim 1, wherein a monomer component aa) a mixture of 95 to 60 percent by weight of styrene and 5 to 40 percent by weight of Alpha -methylstyrene is used.
Claim 5
Dependent Claim 32 words
The process defined in claim 1, wherein as mixture (a) a mixture of 80 to 70 percent by weight of (aa) is used with 20 to 30 percent by weight of (ab).
Claim 6
Dependent Claim 59 words
The process as defined in claim 1, wherein the mixture is polymerized after dissolving the ethylene-propylene-tercomponent rubber in at least one member of said group recited in (aa) and adding of at least one member of said group recited in (ab) to an (aa) / (ab) ration of 5.5/1 to 4.5/1, said ratio being based on percent by weight.
Claim 7
Dependent Claim 58 words
The process as defined in claim 1, wherein the mixture is polymerized after dissolving the ethylene-propylene tercomponent rubber in at least one member of said group recited in aa) and adding of at least one member of said group recited in ab) to an (aa) / (ab) ratio of 5/1, said ratio being based on percent by weight.
Claim 8
Dependent Claim 24 words
The process as defined in claim 1, and wherein the polymerization is carried out in the presence of at least one molecular weight regulator.

References Cited (Backward Citations)

US3489822A Cited
US3639511A Cited
US3461188A Cited
US3483273A Cited
US3538190A Cited
US3538191A Cited
US3538193A Cited
US3538192A Cited
US3642950A Cited
US3683050A Cited
US3719731A Cited
US3694522A Cited
US3657395A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1978-12-15 1979-06-16 1979-12-16 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1982-12-15 1983-06-16 1983-12-16 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1986-12-15 1987-06-16 1987-12-16 $7700.00 Window Closed / Lapsed

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