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US3926876A Expired / Lapsed US ⏱️ 0.0 years remaining

Flame-resistant resinous molding

Assignee: Mitsubishi Chemical Corp
•
Filing: 1974-06-21
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Granted: 1975-12-16
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Expires: 1994-06-21
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Abstract

Abstract Flame-resistant resinous molding of ethylene-vinyl alcohol copolymer, 5 to 50 parts of a halo-organocompound, 0.2 to 10 parts of a metallic soap and 0 to 30 parts of antimony trioxide, said parts being parts by weight per 100 parts by weight of ethylene-vinyl alcohol copolymer. The blending of a thermoplastic resin having a solubility parameter of 8 to 12 based on Small''s equation to the composition improves the molding property of the composition.

Inventors

  • 👤 Mitio Fukushima
  • 👤 Teruo Iwanami

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-03 09:34
CPC Classifications
C; C08; C08K; C08K13/00; C08K13/02; C08K3/00; C08K3/18; C08K3/20; C08K3/22; C08K5/00; C08K5/0008; C08K5/0066; C08K5/02; C08K5/04; C08K5/09; C08K5/13; C08K5/16; C08K5/34

Claims Analysis

Total Claims: 7
Claim 1
Independent Claim 73 words
A FLAME-RESTANT RESINOUS MOLDING COMPOSITION COMPRISING A. ETHYLENE-VINYL ALCOHOL COPOLYMER, B. 5 TO 50 PARTS AT LEAST HALO-ORGANOCOMPOUND SELECTED FROM THE GROUP CONSISTING OF HEXABROMOBENZENE, PERCHLOROPENTACYCLODECANE AND DERIVATIVES THEREOF, TETRABROMOBISPHENOL A, TETRACHLOROBISPHENOL A, TETRABROMOPHATHALIC ANHYDRIDE, TETRACHLOROPHATHALIC ANHYDRIDE AND DI(TETRABROMOPHENYL)IMIDE, C. 0.2 TO 10 PARTS OF A METALLIC SOAP, AND D. 0 TO 30 PARTS OF ANTIMONY TRIOXIDE, SAID PARTS OF (B), (C) AND (D) BEING PARTS BY WEIGHT PER 100 PARTS OF (A).
Claim 2
Dependent Claim 73 words
A FLAME-RESTANT RESINOUS MOLDING COMPOSITION COMPRISING A. ETHYLENE-VINYL ALCOHOL COPOLYMER, B. 5 TO 50 PARTS AT LEAST HALO-ORGANOCOMPOUND SELECTED FROM THE GROUP CONSISTING OF HEXABROMOBENZENE, PERCHLOROPENTACYCLODECANE AND DERIVATIVES THEREOF, TETRABROMOBISPHENOL A, TETRACHLOROBISPHENOL A, TETRABROMOPHATHALIC ANHYDRIDE, TETRACHLOROPHATHALIC ANHYDRIDE AND DI(TETRABROMOPHENYL)IMIDE, C. 0.2 TO 10 PARTS OF A METALLIC SOAP, AND D. 0 TO 30 PARTS OF ANTIMONY TRIOXIDE, SAID PARTS OF (B), (C) AND (D) BEING PARTS BY WEIGHT PER 100 PARTS OF (A).
Claim 3
Dependent Claim 89 words
The flame-resistant resinous molding of claim 1, in which said molding is further incorporated with 2 to 20 parts by weight of a thermoplastic resin having a solubility parameter of 8 to 12 per 100 parts by weight of the ethylene-vinyl alcohol copolymer, said solubility parameter being the value calculated in accordance with the following Small''s equation: delta Rho Sigma F/M wherein delta is a solubility parameter, Rho is a density, F is a molar-attraction constant of atom and radical, and M is a molecular weight of structural unit.
Claim 4
Dependent Claim 50 words
The flame-resistant resinous molding of claim 1, wherein said ethylene-vinyl alcohol copolymer consists of 15 to 50 % by mole of ethylene and 85 to 50 % by mole of vinyl acetate and of which degree of hydrolysis in vinyl acetate component is not less than 85 % by mole.
Claim 5
Dependent Claim 92 words
A process for preparing a flame-resistant molding composition made of ethylene-vinyl alcohol copolymer which comprises blending 5 to 50 parts by weight of at least one halo-organocompound selected from the group consisting of hexabromobenzene, perchloropentacyclodecane and derivatives thereof, tetrabromobisphenol A, tetrachlorobisphenol A, tetrabromophthalic anhydride, tetrachlorophthalic anhydride and di(tetrabromophenyl)imide, 0.2 to 10 parts by weight of a metallic soap, and 0 to 30 parts by weight of antimony trioxide to 100 parts by weight of ethylene-vinyl alcohol copolymer to give a composition, and melt-molding the composition at a temperature of 190* to 250*C.
Claim 6
Dependent Claim 92 words
A process for preparing a flame-resistant molding composition made of ethylene-vinyl alcohol copolymer which comprises blending 5 to 50 parts by weight of at least one halo-organocompound selected from the group consisting of hexabromobenzene, perchloropentacyclodecane and derivatives thereof, tetrabromobisphenol A, tetrachlorobisphenol A, tetrabromophthalic anhydride, tetrachlorophthalic anhydride and di(tetrabromophenyl)imide, 0.2 to 10 parts by weight of a metallic soap, and 0 to 30 parts by weight of antimony trioxide to 100 parts by weight of ethylene-vinyl alcohol copolymer to give a composition, and melt-molding the composition at a temperature of 190* to 250*C.
Claim 7
Dependent Claim 87 words
The process of claim 4, in which said composition is further blended with 2 to 20 parts by weight of a thermoplastic resin having a solubility parameter of 8 to 12 per 100 parts by weight of the ethylene-vinyl alcohol copolymer, said solubility parameter being the value calculated in accordance with the following Small''s equation: delta Rho Sigma F/M wherein delta is a solubility parameter, Rho is a density, F is a molar-attraction constant of atom and radical, and M is a molecular weight of structural unit.

References Cited (Backward Citations)

US2750348A Cited
US2782173A Cited
US3075944A Cited
US3141860A Cited
US3519597A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1978-12-15 1979-06-16 1979-12-16 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1982-12-15 1983-06-16 1983-12-16 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1986-12-15 1987-06-16 1987-12-16 $7700.00 Window Closed / Lapsed

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