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US3926856A Expired / Lapsed US ⏱️ 0.0 years remaining

Catalyst for the production of aromatic hetero-aromatic nitriles and process of preparing the catalyst

Assignee: Evonik Operations GmbH
•
Filing: 1973-06-22
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Granted: 1975-12-16
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Expires: 1993-06-22
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Abstract

Abstract A catalyst useful in preparing nitriles from alkyl substituted aromatic and heteroaromatic hydrocarbons comprises a mixture of antimony oxide and tungsten oxide which have been pretreated by heating from 650* to 1100* C. Compounds of manganese, chromium, iron, cobalt, nickel, copper or, preferably, vanadium can also be present.

Inventors

  • 👤 Theodor Lussling
  • 👤 Hans Schaefer
  • 👤 Wolfgang Weigert

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-06 13:50
CPC Classifications
C; C07; C07D; C07D213/00; C07D213/02; C07D213/04; C07D213/60; C07D213/78; C07D213/84; B; B01; B01J; B01J23/00; B01J23/16; B01J23/24; B01J23/30; B01J23/32; B01J23/34; B01J23/70; B01J23/76; B01J23/84; B01J23/85; B01J23/888; B01J37/00; B01J37/04; C07C; C07C253/00; C07C253/24; C07C253/28

Claims Analysis

Total Claims: 16
Claim 1
Independent Claim 126 words
A PROCESS OF PREPARING A CATALYST, SAID PROCESS CONSISTING ESSENTIALLY OF HEATING WITH OXYGEN AT 650* TO 1100*C. (1)(A) ANTIMONY OXIDE AND (B) TUNGSTEN OXIDE, THE ATOMIC RATIO OF ANTIMONY TO TUNGSTEN BEING FROM 1.1 TO 1 UP TO 50 1 OR (2)(A) ANTIMONY OXIDE (B) TUNGSTEN OXIDE AND (C) AN OXIDE OF A MEMBER OF THE GROUP CONSISTING OF MANGANESE, CHROMIUM, IRON, COBALT, NICKEL AND COPPER WHEREIN THE ATOMIC RATIO OF ANTIMONY TO TUNGSTEN IS FROM 1.1 TO 1 UP TO 50 TO 1, THE ATOMIC COBALT, NICKEL AND COPPER DOES NOT EXCEED THE ATOMIC PROPORTION OF TUNGSTEN AND THE ATOMIC RATIO OF ANTIMONY TO THE TOTAL OF MANGANESE CHROMIUN, IRON, COBALT, NICKEL AND COPPER IS FROM 4 TO 1 UP TO 20 TO 1.
Claim 2
Dependent Claim 126 words
A PROCESS OF PREPARING A CATALYST, SAID PROCESS CONSISTING ESSENTIALLY OF HEATING WITH OXYGEN AT 650* TO 1100*C. (1)(A) ANTIMONY OXIDE AND (B) TUNGSTEN OXIDE, THE ATOMIC RATIO OF ANTIMONY TO TUNGSTEN BEING FROM 1.1 TO 1 UP TO 50 1 OR (2)(A) ANTIMONY OXIDE (B) TUNGSTEN OXIDE AND (C) AN OXIDE OF A MEMBER OF THE GROUP CONSISTING OF MANGANESE, CHROMIUM, IRON, COBALT, NICKEL AND COPPER WHEREIN THE ATOMIC RATIO OF ANTIMONY TO TUNGSTEN IS FROM 1.1 TO 1 UP TO 50 TO 1, THE ATOMIC COBALT, NICKEL AND COPPER DOES NOT EXCEED THE ATOMIC PROPORTION OF TUNGSTEN AND THE ATOMIC RATIO OF ANTIMONY TO THE TOTAL OF MANGANESE CHROMIUN, IRON, COBALT, NICKEL AND COPPER IS FROM 4 TO 1 UP TO 20 TO 1.
Claim 3
Dependent Claim 13 words
A process according to claim 1 wherein the heating is 700* to 1000*C.
Claim 4
Dependent Claim 24 words
A process according to claim 2 wherein the atomic ratio of antimony to tungsten is from 1.1 to 1 up to 25 to 1.
Claim 5
Dependent Claim 13 words
A process according to claim 3 wherein the catalyst prepared is catalyst (2).
Claim 6
Dependent Claim 14 words
A process according to claim 2 wherein the heating is from 800* to 1000*C.
Claim 7
Dependent Claim 11 words
A process according to claim 1 wherein there is heated (1).
Claim 8
Dependent Claim 11 words
A process according to claim 1 wherein there is heated (2).
Claim 9
Dependent Claim 28 words
A process according to claim 7 wherein the ratio of antimony atoms to the metallic atoms in (c) is from 5 to 1 up to 10 to 1.
Claim 10
Dependent Claim 28 words
A process according to claim 8 wherein the ratio of antimony atoms to the metallic atoms in (c) is from 8 to 1 up to 10 to 1.
Claim 11
Dependent Claim 9 words
A catalyst prepared by the process of claim 1.
Claim 12
Dependent Claim 24 words
A catalyst according to claim 10 wherein the atomic ratio of antimony to tungsten is from 1.1 to 1 up to 25 to 1.
Claim 13
Dependent Claim 13 words
A catalyst according to claim 11 prepared by heating at 700* to 1000*C.
Claim 14
Dependent Claim 10 words
A catalyst according to claim 10 which is catalyst (1).
Claim 15
Dependent Claim 10 words
A catalyst according to claim 10 which is catalyst (2).
Claim 16
Dependent Claim 46 words
A catalyst according to claim 14 wherein the atomic ratio of antimony to tungsten is from 1.1 to 1 up to 25 to 1 and the ratio of antimony atoms to the metallic atoms in (c) is from 5 to 1 up to 10 to 1.

References Cited (Backward Citations)

US2833807A Cited
US3200081A Cited
US3579574A Cited
US3637797A Cited
US3544617A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1978-12-15 1979-06-16 1979-12-16 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1982-12-15 1983-06-16 1983-12-16 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1986-12-15 1987-06-16 1987-12-16 $7700.00 Window Closed / Lapsed

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