US3926769A
Expired / Lapsed
US
⏱️ 0.0 years remaining
Diaphragm cell chlorine production
Assignee: Dow Chemical Co
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Filing: 1974-08-01
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Granted: 1975-12-16
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Expires: 1994-08-01
Abstract
Abstract Improved apparatus and process to electrolytically produce chlorine gas and an alkali metal hydroxide in a diaphragm cell. The improved process comprises employing a cation exchange diaphragm and contacting a foraminous cathode with an oxidizing gas having a regulatably controlled moisture content, while substantially simultaneously regulating the anolyte and catholyte compositions.
Inventors
- 👤 Gerhard Gritzner
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-10-26 19:30
CPC Classifications
C; C25; C25B; C25B1/00; C25B1/01; C25B1/34; C25B1/46; C25B11/00; C25B11/04; C25B11/051; C25B11/073; C25B11/091; C25B11/095
Claims Analysis
Total Claims: 11
Claim 1
Independent Claim
277 words
AN ELECTROLYTIC CELL TO PRODUCE CHLORINE AND AN ALKALI METAL HYDROXIDE COMPRISING AN ANODE COMPARTMENE ADAPTED TO CONTAIN AN ANOLYTE CONTAINING AN ALKALI METAL CHLORIDE; A CATHODE COMPARTMENT ADAPTED TO CONTAIN A CHATOLYTE CONTAINING AN ALKALI METAL HYDROXIDE, SAID CATHODE COMPARTMENT BEING SPACED APART FROM SAID ANODE COMPARTMENT BY A CATION EXCHANGE DIAPHRAGM; A CATION EXCHANGE DIAPHRAGM SUITED TO PASS ALKALI METAL IONS FROM SAID ANODE COMPARTMENT TO SAID CATHODE COMPARTMENT, SAID DIAPHRAGM ADAPTED TO SEPARATE SAID ANODE COMPARTMENT FROM SAID CATHODE COMPARTMENT; AN ANODE POSITIONED IN SAID ANODE COMPARTMENT; A CATHODE POSITIONED IN SAID CATHODE COMPARTMENT AND SPACED APART FROM SAID DIAPHRAGM, SAID CATHODE HAVING A WALL PORTION ADAPTED TO BE IN CONTACT WITH THE CATHOLYTE AND ANOTHER WALL PORTION SUBSTANTIALLY SIMULTANEOUSLY ADAPTED TO BE IN CONTACT WITH AN OXIDIZING GAS; AN OXIDIZING GAS COMPARTMENT AT LEAST PARTIALLY DEFINED BY A SURFACE PORTION OF SAID CATHODE AND ADAPTED TO CONTAIN AN OXIDIZING GAS; A MEANS TO CONTROL THE MOISTURE CONTENT OF THE OXIDIZING GAS IN COMBINATION WITH AN OXIDIZING GAS SUPPLY MEANS AND SAID CATHODE; A MEANS TO CIRCULATE THE CATHOLYTE AT LEAST WITHIN SAID CATHODE COMPARTMENT IN COMBINATION WITH SAID CATHODE COMPARTMENT; A MEANS TO CONTROL AT LEAST THE ALKALI METAL ION CONCENTRATION OF THE ANOLYTE; A MEANS TO CONTROL THE ALKALI METAL HYDROXIDE CONCENTRATION OF THE CATHOLYTE; A CATHOLYTE HEAD CONTROL MEANS ADAPTED TO MAINTAIN THE CATHOLYTE UPPER SURFACE LEVEL AT LEAST EQUAL TO THE ANOLYTE UPPER SURFACE LEVEL; A MEANS TO REMOVE THE CHLORINE FROM SAID ANODE COMPARTMENT; A MEANS TO REMOVE THE ALKALI METAL HYDROXIDE FROM SAID CATHODE COMPARTMENT; AND A MEANS TO SUPPLY ELECTRICAL ENERGY TO SAID ANODE AND SAID CATHODE.
Claim 2
Dependent Claim
277 words
AN ELECTROLYTIC CELL TO PRODUCE CHLORINE AND AN ALKALI METAL HYDROXIDE COMPRISING AN ANODE COMPARTMENE ADAPTED TO CONTAIN AN ANOLYTE CONTAINING AN ALKALI METAL CHLORIDE; A CATHODE COMPARTMENT ADAPTED TO CONTAIN A CHATOLYTE CONTAINING AN ALKALI METAL HYDROXIDE, SAID CATHODE COMPARTMENT BEING SPACED APART FROM SAID ANODE COMPARTMENT BY A CATION EXCHANGE DIAPHRAGM; A CATION EXCHANGE DIAPHRAGM SUITED TO PASS ALKALI METAL IONS FROM SAID ANODE COMPARTMENT TO SAID CATHODE COMPARTMENT, SAID DIAPHRAGM ADAPTED TO SEPARATE SAID ANODE COMPARTMENT FROM SAID CATHODE COMPARTMENT; AN ANODE POSITIONED IN SAID ANODE COMPARTMENT; A CATHODE POSITIONED IN SAID CATHODE COMPARTMENT AND SPACED APART FROM SAID DIAPHRAGM, SAID CATHODE HAVING A WALL PORTION ADAPTED TO BE IN CONTACT WITH THE CATHOLYTE AND ANOTHER WALL PORTION SUBSTANTIALLY SIMULTANEOUSLY ADAPTED TO BE IN CONTACT WITH AN OXIDIZING GAS; AN OXIDIZING GAS COMPARTMENT AT LEAST PARTIALLY DEFINED BY A SURFACE PORTION OF SAID CATHODE AND ADAPTED TO CONTAIN AN OXIDIZING GAS; A MEANS TO CONTROL THE MOISTURE CONTENT OF THE OXIDIZING GAS IN COMBINATION WITH AN OXIDIZING GAS SUPPLY MEANS AND SAID CATHODE; A MEANS TO CIRCULATE THE CATHOLYTE AT LEAST WITHIN SAID CATHODE COMPARTMENT IN COMBINATION WITH SAID CATHODE COMPARTMENT; A MEANS TO CONTROL AT LEAST THE ALKALI METAL ION CONCENTRATION OF THE ANOLYTE; A MEANS TO CONTROL THE ALKALI METAL HYDROXIDE CONCENTRATION OF THE CATHOLYTE; A CATHOLYTE HEAD CONTROL MEANS ADAPTED TO MAINTAIN THE CATHOLYTE UPPER SURFACE LEVEL AT LEAST EQUAL TO THE ANOLYTE UPPER SURFACE LEVEL; A MEANS TO REMOVE THE CHLORINE FROM SAID ANODE COMPARTMENT; A MEANS TO REMOVE THE ALKALI METAL HYDROXIDE FROM SAID CATHODE COMPARTMENT; AND A MEANS TO SUPPLY ELECTRICAL ENERGY TO SAID ANODE AND SAID CATHODE.
Claim 3
Dependent Claim
68 words
THE ELECTROLYTIC CELL OF CLAIM 1 WHEREIN SAID CATHODE IS A FORAMINOUS BODY HAVING AT LEAST THE SURFACE COMPOSED OF A SUBSTANTIALLY INERT MATERIAL SELECTED FROM THE GROUP CONSISTING OF RU, RH, PD, AG, OS, IR, PT, AU AND NI WITH A COATING OF A MIXTURE OF PARTICULATE INERT METAL AND AN ORGANIC COMPONENT SELECTED FROM THE GROUP CONSISTING OF POLYTETRAFLUOROETHYLENE AND FLUORINATED COPOLYMERS OF HEAXFLUOROPROPYLENE AND TETRAFLUOROPROPYLENE.
Claim 4
Dependent Claim
13 words
The electrolytic cell of claim 2 wherein the foraminous body is a screen.
Claim 5
Dependent Claim
16 words
The electrolytic cell of claim 2 wherein the foraminous body is nickel or an alloy thereof.
Claim 6
Dependent Claim
57 words
The electrolytic cell of claim 1 wherein said cathode is a silver coated, woven copper screen with a mesh size of about 20 to about 50 with an overcoating of a mixture of platinum, silver, carbon or nickel particulate and an organic component selected from the group consisting of polytetrafluoroethylene, and fluorinated copolymers of hexafluoropropylene and tetrafluoroethylene.
Claim 7
Dependent Claim
14 words
The electrolytic cell of claim 1 wherein said cathode is at least partially nickel.
Claim 8
Dependent Claim
38 words
The electrolytic cell of claim 1 wherein the catholyte head control means is adapted to control the upper catholyte surface level at from about 1 inch to about 3 feet higher than the upper surface of the anolyte.
Claim 9
Dependent Claim
26 words
The electrolytic cell of claim 1 wherein the catholyte circulation means is a pump spaced apart from said cathode compartment and communicating with said cathode compartment.
Claim 10
Dependent Claim
30 words
The electrolytic cell of claim 1 wherein said moisture control means is adapted to control the moisture within the range of from about 50 to about 100 percent of saturation.
Claim 11
Dependent Claim
26 words
The electrolytic cell of claim 9 wherein the catholyte circulation means is a pump spaced apart from said cathode compartment and communicating with said cathode compartment.
References Cited (Backward Citations)
US2681887A
Cited
USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1978-12-15 | 1979-06-16 | 1979-12-16 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1982-12-15 | 1983-06-16 | 1983-12-16 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1986-12-15 | 1987-06-16 | 1987-12-16 | $7700.00 | Window Closed / Lapsed |