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US3925535A Expired / Lapsed US ⏱️ 0.0 years remaining

Catalytic product for the oxidative destruction of gaseous organic compounds and method for their preparation

Assignee: Compagnie Francaise Thomson Houston SA
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Filing: 1974-03-12
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Granted: 1975-12-09
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Expires: 1994-03-12
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Abstract

Abstract A method for the oxidative destruction of gaseous organic compounds consists essentially of passing the organic compounds and an excess of air at a temperature from about 180* C to about 800* C over a catalyst consisting essentially of from about 50 to about 85% by weight of manganese oxides, primarily in the form of rhombohedral manganese dioxide; up to about 30% by weight of manganese carbonate; from about 3% to about 10% by weight of cupric oxide; and up to about 15% by weight of nickel oxides in a refractory excipient. Organic compounds destroyed include xylenols, pyridine, methylpyrrolidone, thiophene, and the like.

Inventors

  • 👤 Christian Belliot
  • 👤 Etienne Cheylan
  • 👤 Serge Madelaine
  • 👤 Johannes Ebbing

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-02 16:59
CPC Classifications
B; B01; B01J; B01J23/00; B01J23/70; B01J23/76; B01J23/84; B01J23/889; B01J23/8892; B01D; B01D53/00; B01D53/34; B01D53/74; B01D53/86; B01D53/8668; B01D53/92; B01D53/94; B01D53/944; B01J37/00; B01J37/0009

Claims Analysis

Total Claims: 15
Claim 1
Independent Claim 111 words
A METHOD FOR THE OXIDATIVE DESTRUCTION OF GASES ORGANIC COMPOUNDS CONSISTING OF PASSING GASEOUS ORGANIC COMPOUNDS AND AT LEAST A FIVE-FOLD EXCESS OF AIR AT A TEMPERATURE FROM ABOUT 180* TO ABOUT 800*C OVER A CATALYST CONSISTING ESSENTIALLY OF FROM ABOUT 50 TO ABOUT 80% BY WEIGHT OF CATALYST COMPONENTS CONSISTING OF FROM ABOUT 50 TO ABOUT 85% BY WEIGHT OF MANGANESE OXIDES, SUBSTANTIALLY IN THE RHOMBOHEDRAL FORM; UP TO ABOUT 30% BY WEIGHT OF MANGANOUS CARBONATE; FROM ABOUT 3 TO ABOUT 10% BY WEIGHT OF CUPRIC OXIDE AND UP TO ABOUT 15% BY WEIGHT OF NICKEL OXIDES AND FROM ABOUT 50 TO ABOUT 20% BY WEIGHT OF COLD-SHAPABLE REFRACTORY EXCIPIENT.
Claim 2
Independent Claim 111 words
A METHOD FOR THE OXIDATIVE DESTRUCTION OF GASES ORGANIC COMPOUNDS CONSISTING OF PASSING GASEOUS ORGANIC COMPOUNDS AND AT LEAST A FIVE-FOLD EXCESS OF AIR AT A TEMPERATURE FROM ABOUT 180* TO ABOUT 800*C OVER A CATALYST CONSISTING ESSENTIALLY OF FROM ABOUT 50 TO ABOUT 80% BY WEIGHT OF CATALYST COMPONENTS CONSISTING OF FROM ABOUT 50 TO ABOUT 85% BY WEIGHT OF MANGANESE OXIDES, SUBSTANTIALLY IN THE RHOMBOHEDRAL FORM; UP TO ABOUT 30% BY WEIGHT OF MANGANOUS CARBONATE; FROM ABOUT 3 TO ABOUT 10% BY WEIGHT OF CUPRIC OXIDE AND UP TO ABOUT 15% BY WEIGHT OF NICKEL OXIDES AND FROM ABOUT 50 TO ABOUT 20% BY WEIGHT OF COLD-SHAPABLE REFRACTORY EXCIPIENT.
Claim 3
Dependent Claim 25 words
The method of claim 1, wherein the temperature at which gaseous organic catalyst compounds are passed over the catalyst is in excess of 300* C.
Claim 4
Dependent Claim 71 words
The method of claim 1, wherein the active catalyst components consist of from about 75 to about 85% of manganese oxides, substantially in the rhombohedral form; from about 5 to about 10% by weight of cupric oxide and from about 5 to about 15% by weight of nickel oxides and wherein the temperature at which gaseous organic compounds are passed over the catalyst is between about 300* and about 500* C.
Claim 5
Dependent Claim 35 words
The method of claim 1, wherein the gaseous organic compounds are selected from the group consisting of xylenols, cresols, pyridine, methyl isobutyl ketone, methyl pyrrolidone, thiophene, butyl acetate, ethylene glycol ethers and acetates, and hydrocarbons.
Claim 6
Dependent Claim 26 words
The method of claim 1, wherein the cold-shapable refractory excipient is selected from the group consisting of magnesia and siliceous cements and kaolinite and montmorillonite clays.
Claim 7
Dependent Claim 34 words
The method of claim 1, wherein the catalyst consists of from about 65 to about 75% by weight of catalyst components and from about 35 to about 25% by weight of cold-shapable refractory excipient.
Claim 8
Dependent Claim 78 words
The method of claim 1, wherein catalyst components consist of from about 40 to about 60% of substantially rhombohedral manganese oxides, from about 20 to about 30% by weight of manganous carbonate, from about 8 to about 12% by weight of nickel oxides and from about 5 to about 10% by weight of cupric oxide and wherein the temperature at which gaseous organic compounds are passed over the catalyst is between about 180* C and about 350* C.
Claim 9
Dependent Claim 15 words
The method of claim 1, wherein gaseous organic compounds are exhaust gases from varnishing installations.
Claim 10
Dependent Claim 15 words
The method of claim 1, wherein gaseous organic compounds are exhaust gases from plastic-treating installations.
Claim 11
Dependent Claim 18 words
The method of claim 1, wherein gaseous organic compounds are exhaust gases from the burning of household garbage.
Claim 12
Dependent Claim 16 words
The method of claim 1, wherein gaseous organic compounds are exhaust gases from internal combustion engines.
Claim 13
Dependent Claim 15 words
The method of claim 1, wherein gaseous organic compounds are exhaust gases from enameling kilns.
Claim 14
Independent Claim 125 words
A method for the oxidative destruction of carbon monoxide consisting of passing a gas stream containing carbon monoxide and at least a five-fold excess of air at a temperature above about -40* C over a catalyst consisting essentially of from about 50 to about 80% by weight of catalyst components consisting of from about 50 to about 85% by weight of manganese oxides, substantially in the rhombohedral form; up to about 30% by weight of manganese oxides, substantially in the rhombohedral form; up to about 30% by weight of manganous carbonate; from about 3 to about 10% by weight of cupric oxide and up to about 15% by weight of nickel oxides and from about 50 to about 20% by weight of cold-shapable refractory excipient.
Claim 15
Independent Claim 125 words
A method for the oxidative destruction of carbon monoxide consisting of passing a gas stream containing carbon monoxide and at least a five-fold excess of air at a temperature above about -40* C over a catalyst consisting essentially of from about 50 to about 80% by weight of catalyst components consisting of from about 50 to about 85% by weight of manganese oxides, substantially in the rhombohedral form; up to about 30% by weight of manganese oxides, substantially in the rhombohedral form; up to about 30% by weight of manganous carbonate; from about 3 to about 10% by weight of cupric oxide and up to about 15% by weight of nickel oxides and from about 50 to about 20% by weight of cold-shapable refractory excipient.

References Cited (Backward Citations)

US3150922A Cited
US3663457A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1978-12-08 1979-06-09 1979-12-09 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1982-12-08 1983-06-09 1983-12-09 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1986-12-08 1987-06-09 1987-12-09 $7700.00 Window Closed / Lapsed

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