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US3925074A Expired / Lapsed US ⏱️ 0.0 years remaining

Electrophotographic elements containing dielectric resins as binders

Assignee: Zeneca Inc
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Filing: 1974-10-10
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Granted: 1975-12-09
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Expires: 1994-10-10
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Abstract

Abstract Improved dielectric resins for use in electrographic and electrophotographic recording materials are disclosed. The resins are prepared by reacting a dicarboxylic acid with a polyol blend, said blend comprising a first polyol having the following general formula: WHEREIN R is an alkylidene group containing from 1 to 4 carbon atoms, a cycloalkylidene group containing 5 or 6 carbon atoms, oxygen, sulfur, or a radical having one of the following formulas: c is 0 or 1; X is halogen or an alkyl radical containing from 1 to 3 carbon atoms; N IS AN INTEGER EQUAL TO FROM 0 TO 4; R'' is an alkylene group containing from 2 to 4 carbon atoms or the radical CH2CH phi ; and A AND B ARE INTEGERS EACH OF WHICH IS EQUAL TO AT LEAST 1 AND THE SUM OF WHICH IS EQUAL TO ABOUT 2 AND A SECOND POLYOL HAVING THE FOLLOWING GENERAL FORMULA: WHEREIN R, c, X, R'', and n are as defined above and a and b are integers each of which is equal to at least 1 and the sum of which is equal to from about 4 to about 16. Electrographic and electrophotographic recording elements prepared from these resins have improved charge acceptance and charge retention properties and significantly reduced curl, particularly at elevated humidity levels.

Inventors

  • 👤 John R Wyhof

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-04 22:46
CPC Classifications
H; H01; H01B; H01B3/00; H01B3/18; H01B3/30; H01B3/42; H01B3/421; C; C08; C08G; C08G63/00; C08G63/66; C08G63/668; C08K; C08K3/00; C08K3/18; C08K3/20; C08K3/22; G; G03; G03G; G03G5/00; G03G5/02; G03G5/0202; G03G5/0205; G03G5/0211; G03G5/04; G03G5/05; G03G5/0528; G03G5/0557; G03G5/056

Claims Analysis

Total Claims: 12
Claim 1
Independent Claim 77 words
AN ELECTROPHOTOGRAPHIC RECORDING ELEMENT COMPRISING A BASE SUPPORT HAVING COATED THEREON LAYER COMPRISING A PHOTOCONDUCTIVE MATERIAL AND A DIELECTRIC RESIN SAID RESIN COMPRISING THE REACTION PRODUCT OF A. A DICARBOXYLIC ACID OR AN ANHYDRIDE THEREOF, PROVIDED THAT AT LEAST 80 MOL PERCENT OF SAID ACID OR ANHYDRIDE IS AN ALPHA UNSATURATED DICARBOXYLIC ACID, AN ANHYDRIDE THEREOF, AN AROMATIC DICARBOXYLIC ACID OR AN ANHYDRIDE THEREOF, AND B. A POLYOL BLEND COMPRISING A FIRST POLYOL HAVING THE FOLLOWING FORMULA:
Claim 2
Dependent Claim 77 words
AN ELECTROPHOTOGRAPHIC RECORDING ELEMENT COMPRISING A BASE SUPPORT HAVING COATED THEREON LAYER COMPRISING A PHOTOCONDUCTIVE MATERIAL AND A DIELECTRIC RESIN SAID RESIN COMPRISING THE REACTION PRODUCT OF A. A DICARBOXYLIC ACID OR AN ANHYDRIDE THEREOF, PROVIDED THAT AT LEAST 80 MOL PERCENT OF SAID ACID OR ANHYDRIDE IS AN ALPHA UNSATURATED DICARBOXYLIC ACID, AN ANHYDRIDE THEREOF, AN AROMATIC DICARBOXYLIC ACID OR AN ANHYDRIDE THEREOF, AND B. A POLYOL BLEND COMPRISING A FIRST POLYOL HAVING THE FOLLOWING FORMULA:
Claim 3
Dependent Claim 17 words
An electrophotographic recording element, as claimed in claim 1, wherein said base support is a conductivized paper.
Claim 4
Dependent Claim 54 words
An electrophotographic recording element, as claimed in claim 1, wherein said dicarboxylic acid is furmaric acid, said first polyol is a polyoxypropylene bis-2,2''(4-hydroxyphenyl)propane containing an average of 2.2 oxypropylene groups per mol of bis-2,2''(4-hydroxyphenyl)propane and said second polyol is a polyoxypropylene bis-2,2''(4-hydroxyphenyl)propane containing an average of about 9 oxypropylene groups per mol of bis-2,2''(4-hYdroxyphenyl)propane.
Claim 5
Dependent Claim 16 words
An electrophotographic recording element, as claimed in claim 1, wherein said photoconductive material is zinc oxide.
Claim 6
Dependent Claim 25 words
An electrophotographic recording element, as claimed in claim 1, wherein the sum of a and b in said second polyol is equal to about 6.
Claim 7
Dependent Claim 41 words
An electrophotographic recording element, as claimed in claim 1, wherein the amount of said second polyol in said blend is equal to from about 20 mol percent to about 45 mol percent of the total amount of polyols in said blend.
Claim 8
Dependent Claim 25 words
An electrophotographic recording element, as claimed in claim 1, wherein the sum of a and b in said second polyol is equal to about 9.
Claim 9
Dependent Claim 41 words
An electrophotographic recording element, as claimed in claim 7, wherein the amount of said second polyol in said blend is equal to from about 10 mol percent to about 25 mol percent of the total amount of polyols in said blend.
Claim 10
Dependent Claim 25 words
An electrophotographic recording element, as claimed in claim 1, wherein the sum of a and b in said second polyol is equal to about 16.
Claim 11
Dependent Claim 42 words
An electrophotographic recording element, as claimed in claim 9, wherein the amount of said second polyol in said blend is equal to from about 5 mol percent to about 7 mol percent based on the total amount of polyols in said blend.
Claim 12
Dependent Claim 23 words
An electrophotographic recording element, as claimed in claim 1, wherein the acid number of said resin is equal to up to about 30.

References Cited (Backward Citations)

US3703371A Cited
US3703372A Cited
US3865789A Cited
US3865869A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1978-12-08 1979-06-09 1979-12-09 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1982-12-08 1983-06-09 1983-12-09 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1986-12-08 1987-06-09 1987-12-09 $7700.00 Window Closed / Lapsed

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