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US3923524A Expired / Lapsed US ⏱️ 0.0 years remaining

Fogged direct positive silver halide emulsions containing photographic sensitizing dyes derived from substituted salicylaldehydes

Assignee: Eastman Kodak Co
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Filing: 1973-10-29
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Granted: 1975-12-02
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Expires: 1993-10-29
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Abstract

Abstract Cyanine and merocyanine photographic sensitizing dyes derived from substituted salicylaldehydes and light sensitive silver halide emulsions containing such dyes are disclosed. Also disclosed are certain reversible spiropyranmerocyanine dye systems, the stabilization of a dye in either the spiropyran form or the merocyanine form and observations of these photochromic materials when coated in polymeric matrices.

Inventors

  • 👤 Jan Raymond Haase

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-04 03:47
CPC Classifications
G; G03; G03C; G03C1/00; G03C1/005; G03C1/06; G03C1/08; G03C1/10; G03C1/12; G03C1/22; G03C1/685

Claims Analysis

Total Claims: 18
Claim 1
Independent Claim 23 words
A FOGGED DIRECT POSITIVE PHOTOGRAPHIC SILVER HALIDE EMULSION CONTAINING AT LEAST ONE PHOTOGRAPHIC SILVER HALIDE SENSITIZING DYE SELECTED FROM THOSE HAVING THE FORMULAS:
Claim 2
Dependent Claim 23 words
A FOGGED DIRECT POSITIVE PHOTOGRAPHIC SILVER HALIDE EMULSION CONTAINING AT LEAST ONE PHOTOGRAPHIC SILVER HALIDE SENSITIZING DYE SELECTED FROM THOSE HAVING THE FORMULAS:
Claim 3
Dependent Claim 18 words
A fogged direct positive photographic silver halide emulsion containing a photographic silver halide sensitizing dye of the formula:
Claim 4
Dependent Claim 18 words
A fogged direct positive photographic silver halide emulsion containing a photographic silver halide sensitizing dye of the formula:
Claim 5
Dependent Claim 18 words
A fogged direct positive photographic silver halide emulsion containing a photographic silver halide sensitizing dye of the formula:
Claim 6
Dependent Claim 18 words
A fogged direct positive photographic silver halide emulsion containing a photographic silver halide sensitizing dye of the formula:
Claim 7
Dependent Claim 17 words
A photographic silver halide emulsion as defined in claim 1 wherein said sensitizing dye is 1'',3''-diethyl-2'',3''-dihydro-6-nitrospiro(2H)-1-benzopyran-2,2''-1H -imidazo(4,5-b)quinoxaline.
Claim 8
Dependent Claim 17 words
A photographic silver halide emulsion as defined in claim 1 wherein said sensitizing dye is 6-((1-methylnaphtho-(1,2-d)thiazolin-2-ylidene)ethylidene)-4-nitro-2,4 -cyclohexadienone.
Claim 9
Dependent Claim 16 words
A photographic silver halide emulsion as defined in claim 1 wherein said sensitizing dye is 6((3-ethylbenzoselenazolinylidene)ethylidene)-4-nitro-2,4-cyclohexadienone.
Claim 10
Dependent Claim 17 words
A photographic silver halide emulsion as defined in claim 1 wherein said sensitizing dye is 6-((1-ethylnaphtho-( 2,3-d)thiazolin-2-ylidene)ethylidene)-4-nitro-2,4-cyclohexadienone.
Claim 11
Dependent Claim 17 words
A photographic silver halide emulsion as defined in claim 1 wherein said sensitizing dye is 6-((3-ethyl-2-benzothiazolinylidene)ethylidene)-4-nitro-2,4 -cyclohexadienone.
Claim 12
Dependent Claim 32 words
A photographic silver halide emulsion as defined in claim 1 wherein said sensitizing dye is selected from the group consisting of 6-((1-ethylnaphtho(1,2-d)thiazolin-2-ylidene)ethylidene)-4-nitro-2,4 -cyclohexadienone; 6-nitro-2'',3''-dihydro-1'',3'',3''-trimethylspiro(2H)-1-benzopyran2, 2''-(1H)-pyrrolo(2,3-b)pyridine; 6-((1,3-diethyl-2-benzimidazolinylidene)ethylidene)-4-nitro2,4 -cyclohexadienone; 6-((1-ethyl-4-(1H)-quinolylidene)ethylidene)-4-nitro-2,4-cyclohexadienone; 6-((5,6-dichloro-1,3-diethyl-2-benzimidazolinylidene)ethylidene)-4-nitro-2,4-cyclohexadienone; and 6-((3,4-diphenyl-4-thiazolin-2-ylidene)ethylidene)-4-nitro2,4 -cyclohexadienone.
Claim 13
Dependent Claim 34 words
A fogged direct positive photographic element comprising a support having thereon at least one layer of a photographic silver halide emulsion containing at least one photographic sensitizing dye selected from those having the formulas:
Claim 14
Dependent Claim 34 words
A fogged direct positive photographic element comprising a support having thereon at least one layer of a photographic silver halide emulsion containing at least one photographic sensitizing dye selected from those having the formulas:
Claim 15
Dependent Claim 31 words
A fogged direct positive photographic elEment comprising a support having thereon at least one layer of a photographic silver halide emulsion containing at least one photographic sensitizing dye of the formula:
Claim 16
Dependent Claim 31 words
A fogged direct positive photographic elEment comprising a support having thereon at least one layer of a photographic silver halide emulsion containing at least one photographic sensitizing dye of the formula:
Claim 17
Dependent Claim 31 words
A fogged direct positive photographic element comprising a support having thereon at least one layer of a photographic silver halide emulsion containing at least one photographic sensitizing dye of the formula:
Claim 18
Dependent Claim 31 words
A fogged direct positive photographic element comprising a support having thereon at least one layer of a photographic silver halide emulsion containing at least one photographic sensitizing dye of the formula:

References Cited (Backward Citations)

US2693416A Cited
US2944896A Cited
US3713832A Cited
US3660086A Cited
US3687674A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1978-12-01 1979-06-02 1979-12-02 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1982-12-01 1983-06-02 1983-12-02 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1986-12-01 1987-06-02 1987-12-02 $7700.00 Window Closed / Lapsed

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