US3922322A
Expired / Lapsed
US
⏱️ 0.0 years remaining
Process for dry polymerization of olefins
Assignee: BP Chimie SA
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Filing: 1973-11-15
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Granted: 1975-11-25
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Expires: 1993-11-15
Abstract
Abstract A dry process for polymerizing olefins to produce polymers having a molecular weight above 50,000 wherein the olefin or olefins to be polymerized are circulated with hydrogen upwardly through a reaction vessel for reaction in the presence of a solid catalyst which has been separately introduced into the reaction vessel with a stream of hydrogen and in which the catalyst is formed of a catalytically active solid compound of a transition metal of sub-groups IVa, Va and VIa of the periodic table of elements, and at least one co-catalyst formed of an organometallic compound of a metal of groups II or III of the periodic table.
Inventors
- 👤 Dormenval Roger
- 👤 Havas Laszlo
- 👤 Mangin Pierre
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-10-27 05:39
CPC Classifications
C; C08; C08F; C08F10/00; B; B01; B01J; B01J8/00; B01J8/0015; Y; Y10; Y10S; Y10S526/00; Y10S526/904; Y10S526/905
Claims Analysis
Total Claims: 13
Claim 1
Independent Claim
246 words
A PROCESS OF PRODUCING POLYMERS HAVING A MOLECULAR WEIGHT GENERALLY ABOVE 50,000, BY POLYMERIZATION OF OLEFINS HAVING THE GENERAL FORMULA CH2=CHR IN WHICH R IS SELECTED FROM THE GROUP CONSISTING OF A HYDROGEN ATOM AND AN ALKYL RADICAL HAVING UP TO 8 CARBON ATOMS, IN THE PRESENCE OF A PREPOLYMER CONTAINING A CATALYST FORMED OF A CATALYTICALLY ACTIVE SOLID COMPOUND OF A TRANSITION METAL OF SUB-GROUPS IVA, VA OR VIA OF THE PERIODIC TABLE OF ELEMENTS, AND AT LEAST ONE CO-CATALYST FORMED OF AN ORGANO-METALLIC COMPOUND OF A METAL OF GROUPS II OR III OF THE PERIODIC TABLE IN WHICH THE PREPOLYMER IS PREPARED BY POLYMERIZATION OF ONE OR MORE OLEFINS IN AN INET LIQUID AND A SOLID COMPOUND OF A TRANSITION METAL OF SUB-GROUPS IVA, VA AND VIA OF THE PERIODIC TABLE OF ELEMENTS AND A CO-CATALYST, COMPRISING PRESEVERING THE CATALYST CONTAINING PREPOLYMER SOLID IN A HYDROGEN ATMOSPHERE, SEPARATELY INTRODUCING INTO A REACTION VESSEL THE OLEFIN OR OLEFINS TO BE POLYMERIZED AND THE CATALYST CONTAINING PREPOLYMER SOLID; CIRCULATING UPWARDLY IN THE REACTION VESSEL CONTAINING POLYMER IN THE COURSE OF BEINF FORMED, A STREAM OF A GASEOUS MIXTURE CONTAINING THE OLEFIN OR THE OLEFINS TO BE POLYMERIZED, AND HYDROGEN, IN WHICH THE POLYMER IN THE REACTION VESSEL IS FLUIDIZED BY THE ASEOUS MIXTURE CONTAINING HYDROGEN AND THE OLEFIN OR OLEFINS TO BE POLYMERIZED, RECYCLING TO THE REACTION VESSEL THE GASES ISSUING THEREFROM; AND REMOVING AT LEAST A PART OF THE POLYMER CONTAINED IN THE REACTION VESSEL.
Claim 2
Dependent Claim
246 words
A PROCESS OF PRODUCING POLYMERS HAVING A MOLECULAR WEIGHT GENERALLY ABOVE 50,000, BY POLYMERIZATION OF OLEFINS HAVING THE GENERAL FORMULA CH2=CHR IN WHICH R IS SELECTED FROM THE GROUP CONSISTING OF A HYDROGEN ATOM AND AN ALKYL RADICAL HAVING UP TO 8 CARBON ATOMS, IN THE PRESENCE OF A PREPOLYMER CONTAINING A CATALYST FORMED OF A CATALYTICALLY ACTIVE SOLID COMPOUND OF A TRANSITION METAL OF SUB-GROUPS IVA, VA OR VIA OF THE PERIODIC TABLE OF ELEMENTS, AND AT LEAST ONE CO-CATALYST FORMED OF AN ORGANO-METALLIC COMPOUND OF A METAL OF GROUPS II OR III OF THE PERIODIC TABLE IN WHICH THE PREPOLYMER IS PREPARED BY POLYMERIZATION OF ONE OR MORE OLEFINS IN AN INET LIQUID AND A SOLID COMPOUND OF A TRANSITION METAL OF SUB-GROUPS IVA, VA AND VIA OF THE PERIODIC TABLE OF ELEMENTS AND A CO-CATALYST, COMPRISING PRESEVERING THE CATALYST CONTAINING PREPOLYMER SOLID IN A HYDROGEN ATMOSPHERE, SEPARATELY INTRODUCING INTO A REACTION VESSEL THE OLEFIN OR OLEFINS TO BE POLYMERIZED AND THE CATALYST CONTAINING PREPOLYMER SOLID; CIRCULATING UPWARDLY IN THE REACTION VESSEL CONTAINING POLYMER IN THE COURSE OF BEINF FORMED, A STREAM OF A GASEOUS MIXTURE CONTAINING THE OLEFIN OR THE OLEFINS TO BE POLYMERIZED, AND HYDROGEN, IN WHICH THE POLYMER IN THE REACTION VESSEL IS FLUIDIZED BY THE ASEOUS MIXTURE CONTAINING HYDROGEN AND THE OLEFIN OR OLEFINS TO BE POLYMERIZED, RECYCLING TO THE REACTION VESSEL THE GASES ISSUING THEREFROM; AND REMOVING AT LEAST A PART OF THE POLYMER CONTAINED IN THE REACTION VESSEL.
Claim 3
Dependent Claim
25 words
A process as claimed in claim 1 in which the catalyst containing prepolymer solid is introduced into the reaction vessel in a stream of hydrogen.
Claim 4
Dependent Claim
26 words
A process as claimed in claim 1 which includes the step of cooling the gaseous effluent from the reaction vessel before recycling to the reaction vessel.
Claim 5
Dependent Claim
35 words
A process as claimed in claim 1 in which the solid compound of a transition metal is selected from solid compounds of a metal selected from the group consisting of trivalent titanium and tetravalent titanium.
Claim 6
Dependent Claim
20 words
A process as claimed in claim 1 in which the pre-polymer is subjected to one or more solvent extraction steps.
Claim 7
Dependent Claim
16 words
A process as claimed in claim 5 in which the extraction solvent is an aliphatic hydrocarbon.
Claim 8
Dependent Claim
54 words
A process as claimed in claim 1 in which the co-catalysts are used in amounts such that the atomic ratio between the metals of groups II and III of the co-catalysts and the transition metals of sub-groups IVa, Va and VIa of the catalytically active solid, is within the range of 1 to 50.
Claim 9
Dependent Claim
65 words
A process as claimed in claim 1 in which the co-catalysts comprise at least one organo-aluminum compound having the mean formula AlRnX3 n, in which R represents an alkyl group having from 1 to 12 carbon atoms, X represents an atom selected from the group consisting of hydrogen and halogen, and n represents an integer or a fraction within the range of 1 to 3.
Claim 10
Dependent Claim
14 words
A process as claimed in claim 8 in which X is a chlorine atom.
Claim 11
Dependent Claim
73 words
A process as claimed in claim 1 which includes a cyclone separator and in which the reaction vessel comprises a polymer bed which is fluidized by the gaseous mixture containing hydrogen and the olefin or olefins to be polymerized, and means for introducing the gaseous mixture issuing from the reaction vessel into the cyclone separator for vapor solid separation, and means for returning the separated vapors from the separator to the reaction vessel.
Claim 12
Dependent Claim
42 words
A process as claimed in claim 1 in which the polymerized olefin is mainly ethylene, and in which the gaseous mixture is subjected to polymerization at a pressure within the range of 10-40 bars and a temperature within the range of 60*-115*C.
Claim 13
Dependent Claim
20 words
A process as claimed in claim 11 in which the gaseous mixture contains up to 80% by volume of hydrogen.
References Cited (Backward Citations)
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US3475517A
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US3514501A
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US3790550A
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US3779712A
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USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1978-11-24 | 1979-05-26 | 1979-11-25 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1982-11-24 | 1983-05-26 | 1983-11-25 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1986-11-24 | 1987-05-26 | 1987-11-25 | $7700.00 | Window Closed / Lapsed |