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US3920567A Expired / Lapsed US ⏱️ 0.0 years remaining

Novel oxazoline-alkyl acid phosphate adducts useful as ashless antiwear additives

Assignee: ExxonMobil Technology and Engineering Co
•
Filing: 1974-12-27
•
Granted: 1975-11-18
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Expires: 1994-12-27
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Abstract

Abstract Ashless antiwear additives for lubricating oils are prepared by reacting a monoester or diester alkyl acid phosphate having 2 to 6 carbon atoms in its alkyl group with a hydroxyalkyl substituted oxazoline having an alkyl or alkene radical of 8 to 22 carbon atoms attached to the ring carbon atom between the nitrogen and oxygen atoms of the oxazoline ring and at least one hydroxyalkyl group having 1 to 4 carbon atoms attached to one of the other two ring carbon atoms. The additives show improved antiwear properties as compared to conventional ash producing antiwear additives.

Inventors

  • 👤 Alfred H Miller

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-25 11:58
CPC Classifications
C; C10; C10M; C10M1/00; C10M1/08; C10M2205/00; C10M2205/02; C10M2205/026; C10M2207/00; C10M2207/28; C10M2207/282; C10M2207/32; C10M2207/34; C10M2209/00; C10M2209/02; C10M2209/08; C10M2209/084; C10M2209/086; C10M2209/10; C10M2209/103; C10M2209/104; C10M2209/11; C10M2209/111; C10M2211/00; C10M2211/02; C10M2215/00; C10M2215/02; C10M2215/06; C10M2215/064; C10M2215/065; C10M2215/22; C10M2215/221; C10M2215/225; C10M2215/226; C10M2215/24; C10M2215/30; C10M2223/00; C10M2223/02; C10M2223/04; C10M2223/042; C10M2229/00; C10M2229/02; C10M2229/04; C10M2229/05; C10N; C10N2030/00; C10N2030/08; C10N2040/00; C10N2040/02; C10N2040/08; C10N2040/12; C10N2040/13

Claims Analysis

Total Claims: 13
Claim 1
Independent Claim 23 words
A COMPOSITION COMPRISING A LUBRICATING OIL AND A QUATERNARY SALT FORMED BY REACTING (A) AN ALKYL ACID PHOSPATE CHARACETERIZED BY THE GENERAL FORMULA:
Claim 2
Dependent Claim 23 words
A COMPOSITION COMPRISING A LUBRICATING OIL AND A QUATERNARY SALT FORMED BY REACTING (A) AN ALKYL ACID PHOSPATE CHARACETERIZED BY THE GENERAL FORMULA:
Claim 3
Dependent Claim 14 words
The composition of claim 1 wherein the oxazoline contains at least two hydroxyalkyl groups.
Claim 4
Dependent Claim 18 words
The composition of claim 1 wherein the oxazoline is a bis hydroxyalkyl substituted oxazoline having two hydroxyalkyl groups.
Claim 5
Dependent Claim 18 words
The composition of claim 3 wherein said two hydroxyalkyl groups are attached to the same ring carbon atom.
Claim 6
Dependent Claim 13 words
The composition of claim 4 wherein said two hydroxyalkyl groups are hydroxymethyl groups.
Claim 7
Dependent Claim 10 words
The composition of claim 5 wherein the oxazoline is 2-heptadecyl-4,4-di-hydroxymethyloxazoline.
Claim 8
Dependent Claim 13 words
The composition of claim 3 wherein the alkyl acid phosphate is di-n-butyl-acid phosphate.
Claim 9
Dependent Claim 13 words
The composition of claim 1 wherein the alkyl acid phosphate is di-n-butyl-acid phosphate.
Claim 10
Dependent Claim 10 words
The composition of claim 8 wherein the oxazoline is 2-heptadecyl-4-methyl-4-hydroxymethyloxazoline.
Claim 11
Dependent Claim 22 words
The composition of claim 1 containing 0.001 to 10 weight percent of said quaternary salt, based on the weight of lubricating oil.
Claim 12
Dependent Claim 34 words
A composition comprising a lubricating oil and 0.001 to 10 weight percent of a quaternary salt, based on the weight of lubricating oil, said quaternary salt being formed by reacting di-n-butyl-acid phosphate with 2-heptadecyl-4,4-di-hydroyxmethyloxazoline.
Claim 13
Dependent Claim 34 words
A composition comprising a lubricating oil and 0.001 to 10 weight percent of a quaternary salt, based on the weight of lubricating oil, said quaternary salt being formed by reacting di-n-butyl-acid phosphate with 2-heptadecyl-4,4-di-hydroyxmethyloxazoline.

References Cited (Backward Citations)

US3819647A Cited
US3844957A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1978-11-17 1979-05-19 1979-11-18 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1982-11-17 1983-05-19 1983-11-18 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1986-11-17 1987-05-19 1987-11-18 $7700.00 Window Closed / Lapsed

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