← Back to Patent Explorer
US3919346A Expired / Lapsed US ⏱️ 0.0 years remaining

Heat-curable pulverulent coating agent consisting of a mixture of copolymers containing anhydrides and curing accelerators

Assignee: Hoechst AG
•
Filing: 1974-05-30
•
Granted: 1975-11-11
•
Expires: 1994-05-30
📄 Original PDF 🌐 Google Patents 🔄 Sync Now

Abstract

Abstract The invention relates to heat-curable pulverulent coating agents, frequently also called powder lacquers, which are suitable for applying a coherent coating which possesses excellent properties after heat-curing.

Inventors

  • 👤 Themistoklis Katsimbas

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-26 01:16
CPC Classifications
C; C08; C08G; C08G59/00; C08G59/18; C08G59/40; C08G59/42; C08G59/20; C08G59/32; C08G59/3209; Y; Y10; Y10S; Y10S525/00; Y10S525/934

Claims Analysis

Total Claims: 12
Claim 1
Independent Claim 181 words
PULVERULENT COATING AGENT OF A MIXTURE OF A. A COPOLYMER OF RELATIVELY LOW MOLECULAR WEIGHT, WHICH CONTAINS GLYCIDYL GROUPS AND IS A COPOLYMER OF SEVERAL ETHYLENICALLY UNSATURATED COMPOUNDS, B. AT LEAST ONE DICARBOXYLIC ACID ANHYDRIDE IN AN AMOUNT CORRESPONDING TO 0.4 - 1.0 ANHYDRIDE GROUPS PER EPOXY GROUP (GLYCIDYL GROUP) OF THE COPOLYMER AND C. A CURING ACCELERATOR IN THE FORM OF AN ORGANIC BASE, D. A FLOW CONTROL AGENT IN AN AMOUNT OF AT LEAST 0.05 PER CENT BY WEIGHT OF THE MIXTURES, WHICH AGENT IS A POLYMER OF MOLECULAR WEIGHT, (MN) OF AT LEAST 1,000 AND HAS A GLASS TRANSITION TEMPERATURE WHICH IS AT LEAST 50*C LOWER THAN THE GLASS TRANSITION TEMPERATURE OF THE COPOLYMER (A), CHARACTERISED IN THAT THE COMPONENT (A) CONSISTS OF 84 TO 94 PER CENT BY WEIGHT OF COPOLYMERS CONTAINING EPOXIDE GROUPS AND HYDROXYL GROUPS, WHICH COPOLYMERS HAVE DURRAN SOFTENING POINTS OF ABOUT 90*-120*C AND ARE SOLUBLE IN ORGANIC SOLVENTS AND WHICH CONSIST ESSENTIALLY OF: A. 6-24 PER CENT BY WEIGHT OF ETHYLENICALLY UNSATURATED A EPOXIDE MONOMERS WITH 6-12 CARBON ATOMS, OF THE GENERAL FORMULA
Claim 2
Dependent Claim 181 words
PULVERULENT COATING AGENT OF A MIXTURE OF A. A COPOLYMER OF RELATIVELY LOW MOLECULAR WEIGHT, WHICH CONTAINS GLYCIDYL GROUPS AND IS A COPOLYMER OF SEVERAL ETHYLENICALLY UNSATURATED COMPOUNDS, B. AT LEAST ONE DICARBOXYLIC ACID ANHYDRIDE IN AN AMOUNT CORRESPONDING TO 0.4 - 1.0 ANHYDRIDE GROUPS PER EPOXY GROUP (GLYCIDYL GROUP) OF THE COPOLYMER AND C. A CURING ACCELERATOR IN THE FORM OF AN ORGANIC BASE, D. A FLOW CONTROL AGENT IN AN AMOUNT OF AT LEAST 0.05 PER CENT BY WEIGHT OF THE MIXTURES, WHICH AGENT IS A POLYMER OF MOLECULAR WEIGHT, (MN) OF AT LEAST 1,000 AND HAS A GLASS TRANSITION TEMPERATURE WHICH IS AT LEAST 50*C LOWER THAN THE GLASS TRANSITION TEMPERATURE OF THE COPOLYMER (A), CHARACTERISED IN THAT THE COMPONENT (A) CONSISTS OF 84 TO 94 PER CENT BY WEIGHT OF COPOLYMERS CONTAINING EPOXIDE GROUPS AND HYDROXYL GROUPS, WHICH COPOLYMERS HAVE DURRAN SOFTENING POINTS OF ABOUT 90*-120*C AND ARE SOLUBLE IN ORGANIC SOLVENTS AND WHICH CONSIST ESSENTIALLY OF: A. 6-24 PER CENT BY WEIGHT OF ETHYLENICALLY UNSATURATED A EPOXIDE MONOMERS WITH 6-12 CARBON ATOMS, OF THE GENERAL FORMULA
Claim 3
Dependent Claim 63 words
Pulverulent coating agent according to claim 1, characterised in that the component (A) consists of a copolymer produced from a. 12 to 16 per cent by weight of glycidyl methacrylate, b. 14 to 18 per cent by weight of hydroxyethyl methacrylate, c. 25 to 38 per cent by weight of ethyl acrylate and d. 30 to 42 per cent by weight of styrene.
Claim 4
Dependent Claim 73 words
Pulverulent coating agent according to claim 1, characterised in that the component (A) consists of a copolymer produced from: a. 12 to 16 per cent by weight of glycidyl methacrylate, b. 12 to 16 per cent by weight of hydroxyethyl methacrylate, c. 18 to 22 per cent by weight of n-butyl acrylate and 7 to 11 per cent by weight of methyl methacrylate, d. 38 to 42 per cent by weight of styrene.
Claim 5
Dependent Claim 62 words
Pulverulent coating agent according to patent claim 1, characterised in that the component (A) consists of a copolymer made of a. 12 to 16 per cent of glycidyl methacrylate, b. 12 to 16 per cent by weight of hydroxyethyl methacrylate, c. 32 to 36 per cent by weight of n-butyl methacrylate and d. 28 to 36 per cent by weight of styrene.
Claim 6
Dependent Claim 73 words
Pulverulent coating agent according to claim 1, characterised in that the component (A) consists of a copolymer produced from: a. 12 to 16 per cent by weight of glycidyl methacrylate, b. 12 to 16 per cent by weight of hydroxyethyl methacrylate, c. 34 to 38 per cent by weight of ethyl acrylate and 7 to 11 per cent by weight of methyl methacrylate, d. 28 to 32 per cent by weight of styrene.
Claim 7
Dependent Claim 73 words
Pulverulent coating agent according to claim 1, characterised in that the component (A) consists of a copolymer produced from: a. 12 to 16 per cent by weight of glycidyl methacrylate, b. 12 to 16 per cent by weight of hydroxyethyl methacrylate, c. 32 to 40 per cent by weight of n-butyl methacrylate and 7 to 11 per cent by weight of methyl methacrylate, d. 28 to 32 per cent by weight of styrene.
Claim 8
Dependent Claim 52 words
A pulverulant coating agent according to claim 1 wherein the copolymer component (A) contains as ethylenically unsaturated epoxide monomer (a) a compound selected from the group consisting of glycidyl acrylate, glycidyl methacrylate, allyl glycidyl ether, methallyl glycidyl ether, glycidyl crotonate, vinyl glycidyl ether, allyl glycidyl maleate, allyl glycidyl phthalate and butadiene monoxide.
Claim 9
Dependent Claim 37 words
A pulverulent coating agent mixture according to claim 1 wherein the copolymer component (A) contains as hydroxyalkyl ester component (b) a compound selected from the group consisting of hydroxyethyl acrylate, hydroxyethyl metacrylate, hydroxypropyl acrylate and hydroxybutyl acrylate.
Claim 10
Dependent Claim 48 words
A pulverulent coating agent according to claim 1 wherein the copolymer component (A) contains as component (c) a C1 to C8 -aliphatically saturated monoalcohol ester of acrylic or methacrylic acid selected from the group consisting of methacrylate, ethylacrylate, butylacrylate, 2-ethylhexyl acrylate, 2-ethylhexyl methacrylate, isobutyl acrylate, and butyl methacrylate.
Claim 11
Dependent Claim 44 words
A method for coating a substrate which comprises applying to the substrate a film of the pulverulent coating agent of claim 1 by the electrostatic powder spray process, and then stoving the filmed substrate at 150* to 180*C for about 15 to 30 minutes.
Claim 12
Dependent Claim 73 words
Pulverulent coating agent according to claim 1, characterised in that the component (A) consists of a copolymer made of: a. 12 to 16 per cent by weight to glycidyl methacrylate, b. 12 to 16 per cent by weight of hydroxyethyl methacrylate, c. 18 to 22 per cent by weight of n-butyl acrylate and 14 to 20 per cent by weight of methyl methacrylate, d. 28 to 32 per cent by weight of styrene.

References Cited (Backward Citations)

US3541055A Cited
US3730930A Cited
US3752870A Cited
US3758635A Cited
US3758632A Cited
US3781379A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1978-11-10 1979-05-12 1979-11-11 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1982-11-10 1983-05-12 1983-11-11 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1986-11-10 1987-05-12 1987-11-11 $7700.00 Window Closed / Lapsed

Assigned Categories & Tags

No categories assigned to this patent yet.

Assign Category Tag