← Back to Patent Explorer
US3917562A Expired / Lapsed US ⏱️ 0.0 years remaining

Combination process for the conversion of heavy distillates to LPG

Assignee: Universal Oil Products Co
•
Filing: 1974-07-16
•
Granted: 1975-11-04
•
Expires: 1994-07-16
📄 Original PDF 🌐 Google Patents 🔄 Sync Now

Abstract

Abstract Maximum conversion of heavy distillates to LPG is achieved through a combination process involving two stage hydrocracking.

Inventors

  • 👤 Lee Hilfman

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-03 05:11
CPC Classifications
C; C10; C10G; C10G65/00; C10G65/02; C10G65/10; B; B01; B01J; B01J29/00; B01J29/04; B01J29/06; B01J29/18; B01J29/20; C10G47/00; C10G47/02; C10G47/10; C10G47/12; C10G47/14; C10G2400/00; C10G2400/26; C10G2400/28; Y; Y10; Y10S; Y10S208/00; Y10S208/02

Claims Analysis

Total Claims: 9
Claim 1
Independent Claim 165 words
A PROCESS FOR THE CONVERSION OF HEAVY DISTILLATE HYDROCARBONS BOILING ABOVE 600*F. TO PRODUCE LPG, WHICH PROCESS COMPRISES THE STEPS OF: A. REACTING SAID HEAVY DISTILLATE IN A FIRST REACTION ZONE CONTAINING A CATALYTIC COMPOSITE COMPRISING A POROUS CARRIER MATERIAL, A GROUP V1-B METAL COMPONENT AND A GROUP V111 METAL COMPONENT AT HYDROCRAKING CONDITIONS SELECTED TO CONVERT THE HEAVY DISTILLATE INTO LOWER BOILING HYDROCARBONS, B. REACTING AT LEAST A PORTION OF SAID LOWER BOILING HYDROCARBONS IN A SECOND REACTION ZONE CONTAINING A CATALYTIC COMPOSITE COMPRISING A GROUP VIII METAL COMPONENT COMBINED WITH AN ALUMINA CARRIER MATERIAL CONTAINING A UNIFORM DISTRIBUTION OF FINELY DIVIDED MORDENITE PARTICLES WHICH CATALYTIC COMPOSITE IS PREPARED BY COMMINGLING SAID MORDENITE WITH AN ALUMINUM HALIDE SOL, GELLING THE RESULTANT MIXTURE THEN CALCINING THE GELLED MIXTURE WHEREIN SAID ALUMINA CARRIER MATERIA CONTAINS FROM ABOUT 20 TO ABOUT 30 WEIGHT ERCENT MORDENITE, AT HYDROCRACKING CONDITIONS SELECTED TO PRODUCE LPG, AND, C. RECOVERING SAID LPG FROM THE RESULTING FIRST AND SECOND ZONE REACTION ZONE EFFUENTS.
Claim 2
Dependent Claim 165 words
A PROCESS FOR THE CONVERSION OF HEAVY DISTILLATE HYDROCARBONS BOILING ABOVE 600*F. TO PRODUCE LPG, WHICH PROCESS COMPRISES THE STEPS OF: A. REACTING SAID HEAVY DISTILLATE IN A FIRST REACTION ZONE CONTAINING A CATALYTIC COMPOSITE COMPRISING A POROUS CARRIER MATERIAL, A GROUP V1-B METAL COMPONENT AND A GROUP V111 METAL COMPONENT AT HYDROCRAKING CONDITIONS SELECTED TO CONVERT THE HEAVY DISTILLATE INTO LOWER BOILING HYDROCARBONS, B. REACTING AT LEAST A PORTION OF SAID LOWER BOILING HYDROCARBONS IN A SECOND REACTION ZONE CONTAINING A CATALYTIC COMPOSITE COMPRISING A GROUP VIII METAL COMPONENT COMBINED WITH AN ALUMINA CARRIER MATERIAL CONTAINING A UNIFORM DISTRIBUTION OF FINELY DIVIDED MORDENITE PARTICLES WHICH CATALYTIC COMPOSITE IS PREPARED BY COMMINGLING SAID MORDENITE WITH AN ALUMINUM HALIDE SOL, GELLING THE RESULTANT MIXTURE THEN CALCINING THE GELLED MIXTURE WHEREIN SAID ALUMINA CARRIER MATERIA CONTAINS FROM ABOUT 20 TO ABOUT 30 WEIGHT ERCENT MORDENITE, AT HYDROCRACKING CONDITIONS SELECTED TO PRODUCE LPG, AND, C. RECOVERING SAID LPG FROM THE RESULTING FIRST AND SECOND ZONE REACTION ZONE EFFUENTS.
Claim 3
Dependent Claim 18 words
The process of claim 1 further characterized in that said heavy distillate is diesel oil or gas oil.
Claim 4
Dependent Claim 29 words
The process of claim 1 further charactereized in that said catalytic composite of said first reaction zone comprises an aluminosilicate carrier material, a nickel component and a molybdenum component.
Claim 5
Dependent Claim 53 words
The process of claim 1 further characterized in that said hydrocracking conditions include a pressure from about 300 to about 2000 psig., a temperature from about 600*F. to about 850*F., a LHSV of about 0.5 to about 10 hr. 1 and a hydrogen circulation rate of about 5000 SCFB to about 15,000 SCFB.
Claim 6
Dependent Claim 23 words
The process of claim 1 further characterized in that said catalytic composite of said second reaction zone comprises platinum or a platinum compound.
Claim 7
Dependent Claim 23 words
The process of claim 1 further characterized in that said catalytic composite of said second reaction zone comprises palladium or a palladium compound.
Claim 8
Dependent Claim 26 words
The process of claim 1 further characterized in that said catalytic composite of said second reaction zone contains about 0.05 to about 1.5 weight percent halogen.
Claim 9
Dependent Claim 26 words
The process of claim 1 further characterized in that said catalytic composite of said second reaction zone contains about 0.1 to about 1.5 weight percent sulfur.

References Cited (Backward Citations)

US3516925A Cited
US3775298A Cited
US3709814A Cited
US3833499A Cited
US3697415A Cited
US3718575A Cited
US3847796A Cited
US3808122A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1978-11-03 1979-05-05 1979-11-04 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1982-11-03 1983-05-05 1983-11-04 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1986-11-03 1987-05-05 1987-11-04 $7700.00 Window Closed / Lapsed

Assigned Categories & Tags

No categories assigned to this patent yet.

Assign Category Tag