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US3917518A Expired / Lapsed US ⏱️ 0.0 years remaining

Hypochlorite production

Assignee: ELECTRODE Corp A CORP OF
•
Filing: 1973-04-19
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Granted: 1975-11-04
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Expires: 1993-04-19
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Abstract

Abstract A process is described that is particularly applicable to the continuous production of hypochlorite solution over long periods of time by electrolysis of aqueous chloride solutions with an anode having a coating that is a mixture of oxides of tin, antimony, at least one platinum group metal, and a valve metal selected from the group titanium and tantalum, all in certain proportions.

Inventors

  • 👤 Charles R Franks
  • 👤 Barry A Schenker
  • 👤 James M Kolb

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-27 21:16
CPC Classifications
C; C25; C25B; C25B1/00; C25B1/01; C25B1/24; C25B1/26

Claims Analysis

Total Claims: 6
Claim 1
Independent Claim 121 words
IN A PROCESS FOR THE PRODUCTION OF HYPOCHLORITEBY THE ELECTROLYSIS OF AN AQUEOUS ALKALI METAL CHLORIDE SOLUTION, THE IMPROVEMENT THAT COMPRISES PASSINGAN ELECTROLYZING CURRENT THROUGH SAID SOLUTION BETWEEN A CATHODE AND AN OPPOSED ANODE, WHICH ANODE COMPRISES A CONDUCTIVE BASE BEARING ON AT LEAST APORTION OF THE SURFACE THEREOF A COATING CONSISTING ESSENTIALLY OF FROM 30 TO 90 PERCENT BY WEIGHT STANNIC OXIDE, FROM 1.0 TO 10 PERCENT ANTIMONY OXILE, CALCULATED AS SB2O3, FROM 1.0 TO 50 PERCENT OF AT LEAST ONE PLATINUM GROUP METAL OXIDE AND FROM 0.5 TO 30 PERCENT OF A VALVE METAL OXIDE SELECTED FROM TE GROUP CONSISTING OF TITANIUM AND TATALUM OXIDES, WITH THE PROVISO THAT THE MOLE RATIO OF SNO2:SB2O3 IS BETWEEN 95:5 AND 85:15.
Claim 2
Dependent Claim 121 words
IN A PROCESS FOR THE PRODUCTION OF HYPOCHLORITEBY THE ELECTROLYSIS OF AN AQUEOUS ALKALI METAL CHLORIDE SOLUTION, THE IMPROVEMENT THAT COMPRISES PASSINGAN ELECTROLYZING CURRENT THROUGH SAID SOLUTION BETWEEN A CATHODE AND AN OPPOSED ANODE, WHICH ANODE COMPRISES A CONDUCTIVE BASE BEARING ON AT LEAST APORTION OF THE SURFACE THEREOF A COATING CONSISTING ESSENTIALLY OF FROM 30 TO 90 PERCENT BY WEIGHT STANNIC OXIDE, FROM 1.0 TO 10 PERCENT ANTIMONY OXILE, CALCULATED AS SB2O3, FROM 1.0 TO 50 PERCENT OF AT LEAST ONE PLATINUM GROUP METAL OXIDE AND FROM 0.5 TO 30 PERCENT OF A VALVE METAL OXIDE SELECTED FROM TE GROUP CONSISTING OF TITANIUM AND TATALUM OXIDES, WITH THE PROVISO THAT THE MOLE RATIO OF SNO2:SB2O3 IS BETWEEN 95:5 AND 85:15.
Claim 3
Dependent Claim 143 words
A process for the production of a solution containing from 0.5 to 10 grams per liter of hypochlorite, which process comprises passing an electrolyzing current through an aqueous solution of alkali metal chloride, at a pH of greater than 7 and a temperature between 5* and 50* C, between a cathode and an opposed anode, which anode comprises an electrically conductive supporting substrate bearing on at least a portion of the surface thereof a coating consisting essentially of from 30 to 90 percent stannic oxide, from 1.0 to 10 percent antimony oxide, calculated as Sb2O3, from 1.0 to 50 percent of at least one platinum group metal oxide and from 0.5 to 30 percent of a valve metal oxide selected from the group consisting of titanium and tantalum oxides, with the proviso that the mole ratio of SnO2:Sb2O3 is between 95:5 and 85:15.
Claim 4
Dependent Claim 143 words
A process for the production of a solution containing from 0.5 to 10 grams per liter of hypochlorite, which process comprises passing an electrolyzing current through an aqueous solution of alkali metal chloride, at a pH of greater than 7 and a temperature between 5* and 50* C, between a cathode and an opposed anode, which anode comprises an electrically conductive supporting substrate bearing on at least a portion of the surface thereof a coating consisting essentially of from 30 to 90 percent stannic oxide, from 1.0 to 10 percent antimony oxide, calculated as Sb2O3, from 1.0 to 50 percent of at least one platinum group metal oxide and from 0.5 to 30 percent of a valve metal oxide selected from the group consisting of titanium and tantalum oxides, with the proviso that the mole ratio of SnO2:Sb2O3 is between 95:5 and 85:15.
Claim 5
Dependent Claim 22 words
A process as in claim 2 wherein the electrolyzing current is within the range of 0.5 to 1.0 ampere per square inch.
Claim 6
Dependent Claim 20 words
A process as in claim 2 wherein the alkali metal chloride concentratiOn is between 28 and 35 grams per liter.

References Cited (Backward Citations)

US1397239A Cited
US3732157A Cited
US3627669A Cited
US3711397A Cited
US3684543A Cited
US3779889A Cited
US3776834A Cited
US3793164A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1978-11-03 1979-05-05 1979-11-04 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1982-11-03 1983-05-05 1983-11-04 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1986-11-03 1987-05-05 1987-11-04 $7700.00 Window Closed / Lapsed

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