US3917518A
Expired / Lapsed
US
⏱️ 0.0 years remaining
Hypochlorite production
Assignee: ELECTRODE Corp A CORP OF
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Filing: 1973-04-19
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Granted: 1975-11-04
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Expires: 1993-04-19
Abstract
Abstract A process is described that is particularly applicable to the continuous production of hypochlorite solution over long periods of time by electrolysis of aqueous chloride solutions with an anode having a coating that is a mixture of oxides of tin, antimony, at least one platinum group metal, and a valve metal selected from the group titanium and tantalum, all in certain proportions.
Inventors
- 👤 Charles R Franks
- 👤 Barry A Schenker
- 👤 James M Kolb
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-10-27 21:16
CPC Classifications
C; C25; C25B; C25B1/00; C25B1/01; C25B1/24; C25B1/26
Claims Analysis
Total Claims: 6
Claim 1
Independent Claim
121 words
IN A PROCESS FOR THE PRODUCTION OF HYPOCHLORITEBY THE ELECTROLYSIS OF AN AQUEOUS ALKALI METAL CHLORIDE SOLUTION, THE IMPROVEMENT THAT COMPRISES PASSINGAN ELECTROLYZING CURRENT THROUGH SAID SOLUTION BETWEEN A CATHODE AND AN OPPOSED ANODE, WHICH ANODE COMPRISES A CONDUCTIVE BASE BEARING ON AT LEAST APORTION OF THE SURFACE THEREOF A COATING CONSISTING ESSENTIALLY OF FROM 30 TO 90 PERCENT BY WEIGHT STANNIC OXIDE, FROM 1.0 TO 10 PERCENT ANTIMONY OXILE, CALCULATED AS SB2O3, FROM 1.0 TO 50 PERCENT OF AT LEAST ONE PLATINUM GROUP METAL OXIDE AND FROM 0.5 TO 30 PERCENT OF A VALVE METAL OXIDE SELECTED FROM TE GROUP CONSISTING OF TITANIUM AND TATALUM OXIDES, WITH THE PROVISO THAT THE MOLE RATIO OF SNO2:SB2O3 IS BETWEEN 95:5 AND 85:15.
Claim 2
Dependent Claim
121 words
IN A PROCESS FOR THE PRODUCTION OF HYPOCHLORITEBY THE ELECTROLYSIS OF AN AQUEOUS ALKALI METAL CHLORIDE SOLUTION, THE IMPROVEMENT THAT COMPRISES PASSINGAN ELECTROLYZING CURRENT THROUGH SAID SOLUTION BETWEEN A CATHODE AND AN OPPOSED ANODE, WHICH ANODE COMPRISES A CONDUCTIVE BASE BEARING ON AT LEAST APORTION OF THE SURFACE THEREOF A COATING CONSISTING ESSENTIALLY OF FROM 30 TO 90 PERCENT BY WEIGHT STANNIC OXIDE, FROM 1.0 TO 10 PERCENT ANTIMONY OXILE, CALCULATED AS SB2O3, FROM 1.0 TO 50 PERCENT OF AT LEAST ONE PLATINUM GROUP METAL OXIDE AND FROM 0.5 TO 30 PERCENT OF A VALVE METAL OXIDE SELECTED FROM TE GROUP CONSISTING OF TITANIUM AND TATALUM OXIDES, WITH THE PROVISO THAT THE MOLE RATIO OF SNO2:SB2O3 IS BETWEEN 95:5 AND 85:15.
Claim 3
Dependent Claim
143 words
A process for the production of a solution containing from 0.5 to 10 grams per liter of hypochlorite, which process comprises passing an electrolyzing current through an aqueous solution of alkali metal chloride, at a pH of greater than 7 and a temperature between 5* and 50* C, between a cathode and an opposed anode, which anode comprises an electrically conductive supporting substrate bearing on at least a portion of the surface thereof a coating consisting essentially of from 30 to 90 percent stannic oxide, from 1.0 to 10 percent antimony oxide, calculated as Sb2O3, from 1.0 to 50 percent of at least one platinum group metal oxide and from 0.5 to 30 percent of a valve metal oxide selected from the group consisting of titanium and tantalum oxides, with the proviso that the mole ratio of SnO2:Sb2O3 is between 95:5 and 85:15.
Claim 4
Dependent Claim
143 words
A process for the production of a solution containing from 0.5 to 10 grams per liter of hypochlorite, which process comprises passing an electrolyzing current through an aqueous solution of alkali metal chloride, at a pH of greater than 7 and a temperature between 5* and 50* C, between a cathode and an opposed anode, which anode comprises an electrically conductive supporting substrate bearing on at least a portion of the surface thereof a coating consisting essentially of from 30 to 90 percent stannic oxide, from 1.0 to 10 percent antimony oxide, calculated as Sb2O3, from 1.0 to 50 percent of at least one platinum group metal oxide and from 0.5 to 30 percent of a valve metal oxide selected from the group consisting of titanium and tantalum oxides, with the proviso that the mole ratio of SnO2:Sb2O3 is between 95:5 and 85:15.
Claim 5
Dependent Claim
22 words
A process as in claim 2 wherein the electrolyzing current is within the range of 0.5 to 1.0 ampere per square inch.
Claim 6
Dependent Claim
20 words
A process as in claim 2 wherein the alkali metal chloride concentratiOn is between 28 and 35 grams per liter.
References Cited (Backward Citations)
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USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1978-11-03 | 1979-05-05 | 1979-11-04 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1982-11-03 | 1983-05-05 | 1983-11-04 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1986-11-03 | 1987-05-05 | 1987-11-04 | $7700.00 | Window Closed / Lapsed |