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US3916997A Expired / Lapsed US ⏱️ 0.0 years remaining

Oil recovery with high conductivity micellar systems

Assignee: Marathon Oil Co
•
Filing: 1973-09-13
•
Granted: 1975-11-04
•
Expires: 1993-09-13
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Abstract

Abstract Improved oil recovery can be obtained by flooding with oilexternal micellar systems having an electrical conductivity above about 5 X 10 5 ohm 1 centimeter 1. Such conductivities can be obtained varying slug constituents, e.g., surfactant, cosurfactants, cyclohexanone, isopropyl alcohol, and the concentrations of the constituents.

Inventors

  • 👤 Larry J Douglas
  • 👤 Charles B Wenger

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-28 06:53
CPC Classifications
C; C09; C09K; C09K8/00; C09K8/58; C09K8/584

Claims Analysis

Total Claims: 14
Claim 1
Independent Claim 40 words
IN A PROCESS FOR THE SECONDARY-TYPE RECOVERY OF PETROLEUM BY INJECTION OF MICELLAR SYSTEMS INTO SUBSTRERANEAN PETROLEUM-BEARING RESERVOIRS, THE IMPROVEMENT COMPRISING UTILIZING AS SAID MICELLAR SYSTEM SOIL-EXTERNAL COMPOSITIONS HAVING ELECTRICAL CONDUCTIVITIES OF AT EAST ABOUT 5 X 10-4 OHM-1 CENTIMETER-1
Claim 2
Dependent Claim 40 words
IN A PROCESS FOR THE SECONDARY-TYPE RECOVERY OF PETROLEUM BY INJECTION OF MICELLAR SYSTEMS INTO SUBSTRERANEAN PETROLEUM-BEARING RESERVOIRS, THE IMPROVEMENT COMPRISING UTILIZING AS SAID MICELLAR SYSTEM SOIL-EXTERNAL COMPOSITIONS HAVING ELECTRICAL CONDUCTIVITIES OF AT EAST ABOUT 5 X 10-4 OHM-1 CENTIMETER-1
Claim 3
Dependent Claim 96 words
In a process for the recovery of petroleum comprising injecting micellar systems into subterranean oil-bearing formations, the improvement comprising in combination formulating said micellar systems so that they comprise: a. from about 3 to about 20 weight percent of surfactant, b. from about 5 to about 60 percent by weight water containing electrolyte, c. from about 10 to about 60 percent by weight hydrocarbon, and d. cosurfactant in a quantity sufficient to provide a micellar system having an electrical conductivity above about 5 X 10 5 ohm 1 centimeter 1, wherein said micellar system is oil-external.
Claim 4
Dependent Claim 96 words
In a process for the recovery of petroleum comprising injecting micellar systems into subterranean oil-bearing formations, the improvement comprising in combination formulating said micellar systems so that they comprise: a. from about 3 to about 20 weight percent of surfactant, b. from about 5 to about 60 percent by weight water containing electrolyte, c. from about 10 to about 60 percent by weight hydrocarbon, and d. cosurfactant in a quantity sufficient to provide a micellar system having an electrical conductivity above about 5 X 10 5 ohm 1 centimeter 1, wherein said micellar system is oil-external.
Claim 5
Dependent Claim 22 words
A process according to claim 1 wherein said micellar system has a surface tension of less than about 27 dynes per centimeter.
Claim 6
Dependent Claim 24 words
A process according to claim 3 wherein said micellar system is formulated to be completely miscible with oil and substantially immiscible with water-containing electrolytes.
Claim 7
Dependent Claim 24 words
A process according to claim 4 wherein said micellar system is formulated to be completely miscible with oil and substantially immiscible with water-containing electrolytes.
Claim 8
Dependent Claim 25 words
A process according to claim 2 wherein said cosurfactant is selected from the group consisting of isopropyl alcohol, amyl alcohol, hexyl alcohol, cyclohexanone, and acetone.
Claim 9
Dependent Claim 25 words
A process according to claim 3 wherein said cosurfactant is selected from the group consisting of isopropyl alcohol, amyl alcohol, hexyl alcohol, cyclohexanone, and acetone.
Claim 10
Dependent Claim 25 words
A process according to claim 4 wherein said cosurfactant is selected from the group consisting of isopropyl alcohol, amyl alcohol, hexyl alcohol, cyclohexanone, and acetone.
Claim 11
Dependent Claim 25 words
A process according to claim 5 wherein said cosurfactant is selected from the group consisting of isopropyl alcohol, amyl alcohol, hexyl alcohol, cyclohexanone, and acetone.
Claim 12
Dependent Claim 41 words
A process according to claim 2 wherein said electrolytes comprise from about 5 to about 60 percent by weight based on the weight of water of a salt selected from the group consisting of NaCl, Na2SO4 KCl, K2SO4, KOH, and CaCl2.
Claim 13
Dependent Claim 59 words
In a process for secondary-type recovery of petroleum by injecting of micellar systems into subterranean petroleum-bearing reservoirs, the improvement comprising preparing said micellar systems by mixing together a surfactant, water, and cosurfactant, the amount of said cosurfactant being just sufficient to obtain a predetermined electrical conductivity which is greater than about 5 X 10 5 ohm 1 centimeters 1.
Claim 14
Dependent Claim 59 words
In a process for secondary-type recovery of petroleum by injecting of micellar systems into subterranean petroleum-bearing reservoirs, the improvement comprising preparing said micellar systems by mixing together a surfactant, water, and cosurfactant, the amount of said cosurfactant being just sufficient to obtain a predetermined electrical conductivity which is greater than about 5 X 10 5 ohm 1 centimeters 1.

References Cited (Backward Citations)

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USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1978-11-03 1979-05-05 1979-11-04 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1982-11-03 1983-05-05 1983-11-04 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1986-11-03 1987-05-05 1987-11-04 $7700.00 Window Closed / Lapsed

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