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US3915849A Expired / Lapsed US ⏱️ 0.0 years remaining

Method of removing organometallic compounds from liquid hydrocarbons

Assignee: ExxonMobil Technology and Engineering Co
•
Filing: 1973-10-10
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Granted: 1975-10-28
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Expires: 1993-10-10
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Abstract

Abstract Organometallic compounds are separated from liquid hydrocarbons containing the same by contacting the liquid hydrocarbon with an activated charcoal having hydrous ferric chloride impregnated thereon. The contacting may be accomplished at any combination of temperature and pressure at which the hydrocarbon will remain liquid and at which all components used in the process will remain stable. The contacting may be accomplished in essentially any suitable fashion; however, contacting in a fixed bed of the activated charcoal is, generally, most convenient and effective. Impregnation of the activated charcoal is accomplished by contacting a suitable activated charcoal with an aqueous solution of hydrous ferric chloride and thereafter at least partially drying the resulting mixture such that the water remaining is internally adsorbed in the activated charcoal pores. Generally, the presence of water in the impregnated activated carbon adsorbent will improve separation performance. This method of separation is particularly suited to the separation of organo lead compounds from gasoline.

Inventors

  • 👤 Abraham A Zimmerman

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-09 03:53
CPC Classifications
C; C10; C10G; C10G53/00; C10G53/02; C10G53/08; C10G25/00; C10G25/003; C10G29/00; C10G29/02; C10G29/06; C10G29/12

Claims Analysis

Total Claims: 9
Claim 1
Independent Claim 91 words
A METHOD FOR SEPARATING AN ORGANO LEAD COMPOUND FROM LIQUID HYDROCARBON COMPRISING THE STEPS OF: A. CONTACTING A LIQUID HYCDROCATBON HAVING AN ORGANO LEAD COMPOUND DISSOLVED THEREIN WITH AN ACTIVATED CARBON IMPREGNATED WITH A HYDROUS FERRIC CHROLIDE, SAID ACTIVATED CARBON IMPREGNATED WITH A HYDROUS CHLORIDE COMPRISING BETWEEN ABOUT 5 AND ABOUT 20 WT. % FECI3 ON A WATER-FREE BASIS, BETWEEN ABOUT 2 AND ABOUT 30 WT.% WATER AND BETWEEN ABOUT 50 AND ABOUT 93 WT. % ACTIVATED CARBON, AND B. RECOVERING A LIQUID HYDROCARBON HAVING A REDUCED DISSOLNED LEAD CONTENT THEREIN.
Claim 2
Independent Claim 91 words
A METHOD FOR SEPARATING AN ORGANO LEAD COMPOUND FROM LIQUID HYDROCARBON COMPRISING THE STEPS OF: A. CONTACTING A LIQUID HYCDROCATBON HAVING AN ORGANO LEAD COMPOUND DISSOLVED THEREIN WITH AN ACTIVATED CARBON IMPREGNATED WITH A HYDROUS FERRIC CHROLIDE, SAID ACTIVATED CARBON IMPREGNATED WITH A HYDROUS CHLORIDE COMPRISING BETWEEN ABOUT 5 AND ABOUT 20 WT. % FECI3 ON A WATER-FREE BASIS, BETWEEN ABOUT 2 AND ABOUT 30 WT.% WATER AND BETWEEN ABOUT 50 AND ABOUT 93 WT. % ACTIVATED CARBON, AND B. RECOVERING A LIQUID HYDROCARBON HAVING A REDUCED DISSOLNED LEAD CONTENT THEREIN.
Claim 3
Dependent Claim 19 words
The method of claim 1 wherein said activated carbon is impregnated with an aqueous solution of hydrous ferric chloride.
Claim 4
Dependent Claim 28 words
The method of claim 1 wherein the activated carbon is substantially amorphous and has an oxygen content within the range of about 3 to about 25 wt. %.
Claim 5
Dependent Claim 51 words
The method of claim 1 wherein the activated carbon impregnated with an aqueous solution of ferric chloride comprises between about 8 and about 15 wt. % FeCl3, on a water-free basis, between about 5 and about 20 wt. % water and between about 65 and about 87 wt. % activated carbon.
Claim 6
Dependent Claim 64 words
The method of claim 4 wherein said activated carbon contains less than about 5.0 wt. % graphitic type carbon; has an oxygen content within the range of about 10 to about 20 wt. %; has a total pore volume within the range of about 0.8 to about 1.2 ml/g; and exhibits a surface area within the range of about 500 to about 1000 m2/g.
Claim 7
Dependent Claim 19 words
The method of claim 1 wherein the contacting is accomplished at a temperature between about 30* and about 120*F.
Claim 8
Dependent Claim 22 words
The method of claim 6 wherein the contacting is continued for a period of time between about 1 and about 5 minutes.
Claim 9
Dependent Claim 16 words
The method of claim 7 wherein the liquid hydrocarbon contains less than about 0.5 g Pb/gallon.

References Cited (Backward Citations)

US1769794A Cited
US1814410A Cited
US1988114A Cited
US2392846A Cited
US2884369A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1978-10-27 1979-04-28 1979-10-28 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1982-10-27 1983-04-28 1983-10-28 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1986-10-27 1987-04-28 1987-10-28 $7700.00 Window Closed / Lapsed

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