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US3915759A Expired / Lapsed US ⏱️ 0.0 years remaining

Black oxide coating for stainless steels

Assignee: Coral Chemical Co
•
Filing: 1974-01-08
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Granted: 1975-10-28
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Expires: 1994-01-08
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Abstract

Abstract A method of blackening ferritic and/or martensitic stainless steels which comprises treating said steels by (a) immersing said steel in a fused alkali metal hydroxide-salt bath, which as conventionally produced may initially contain from 3 to 8% water of hydration, for a period of 1-30 minutes, at a temperature of 540*-720*F., and (b) continually adding water during the heat treatment in step (a); said water can be introduced in the form of steam to replenish the original water of hydration of the fused bath and the amount of water added ranges from an effective amount to about 15% by weight of the fused salt mixture. This addition of water in the ranges 1-15% and 3-8% replenishes and reinvigorates the molten salt bath so that the bath likewise has a satisfactory water content based on the molten salt mixture. A preferred fused salt mixture is the eutectic mixture of sodium and potassium hydroxide, and an additive agent such as an alkali metal molybdate may be added to the fused salt mix.

Inventors

  • 👤 Thomas J Smollett
  • 👤 Bozidar Stipanovic

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-31 14:30
CPC Classifications
C; C23; C23C; C23C22/00; C23C22/70; C23C22/72; B; B60; B60S; B60S1/00; B60S1/02; B60S1/04; B60S1/32; B60S1/38; B60S1/3801

Claims Analysis

Total Claims: 13
Claim 1
Independent Claim 77 words
A METHOD OF BLACKENING FERRITIC AND MARTENSTIC STAINLESS STEELS WHICH COMPRISES IMMERSING SAID STEELS FOR A PERIOD OF 1-30 MINUTES IN A FUSED ALKALI METAL HYDROSIDE SALT BATH, WHEREIN THE ALKALI METAL IS SELECTED FROM THE GROUP CONSISTING OF SODIUM AND POTASSIUM, WHICH BATH CONTAINS AN EFFECTIVE AMOUNT OF WATER MAINTAINED BY SUBSEQUENT ADDITION TO THE BATH AT ABOUT 1-15% BY WEIGHT OF SAID BATH, AND WHEREIN SAID BATH IS MAINTAINED AT A TEMPERATURE OF ABOUT 510*-720*F.
Claim 2
Independent Claim 77 words
A METHOD OF BLACKENING FERRITIC AND MARTENSTIC STAINLESS STEELS WHICH COMPRISES IMMERSING SAID STEELS FOR A PERIOD OF 1-30 MINUTES IN A FUSED ALKALI METAL HYDROSIDE SALT BATH, WHEREIN THE ALKALI METAL IS SELECTED FROM THE GROUP CONSISTING OF SODIUM AND POTASSIUM, WHICH BATH CONTAINS AN EFFECTIVE AMOUNT OF WATER MAINTAINED BY SUBSEQUENT ADDITION TO THE BATH AT ABOUT 1-15% BY WEIGHT OF SAID BATH, AND WHEREIN SAID BATH IS MAINTAINED AT A TEMPERATURE OF ABOUT 510*-720*F.
Claim 3
Dependent Claim 30 words
The method of claim 1, wherein water is continuously added to the fused salt bath in order to maintain a concentration of 1-15% by weight of water in said bath.
Claim 4
Dependent Claim 30 words
The method of claim 1, wherein water is intermittently added to the fused salt bath in order to maintain a concentration of 1-15% by weight of water in said bath.
Claim 5
Dependent Claim 19 words
The process of claim 2, wherein water is introduced into the fused salt bath in the form of steam.
Claim 6
Dependent Claim 19 words
The process of claim 2, wherein water is introduced into the fused salt in the form of dry steam.
Claim 7
Dependent Claim 21 words
The method of claim 1, wherein the water content is maintained at about 2-12% by weight of the fused salt mixture.
Claim 8
Dependent Claim 21 words
The method of claim 1, wherein the water content is maintained at about 3-8% by weight of the fused salt mixture.
Claim 9
Dependent Claim 26 words
The method of claim 1, wherein alkali metal hydroxide is selected from at least one member of the group consisting of sodium hydroxide and potassium hydroxide.
Claim 10
Dependent Claim 19 words
The method of claim 1, wherein the fused salt bath is an eutectic mixture of sodium and potassium hydroxides.
Claim 11
Dependent Claim 27 words
The method of claim 1, wherein the stainless steel is selected from at least one member of the group consisting of the AISI 400 series stainless steels.
Claim 12
Dependent Claim 13 words
The method of claim 1, wherein the temperature is maintained at 540*-650* F.
Claim 13
Dependent Claim 45 words
The method of claim 1, wherein an oxidizing agent is added in the amount of 5-10% by weight of the fused salt mixture, and said oxidizing agent is selected from at least one member of the group consisting of alkali metal molybdates. chromates and permanganates.

References Cited (Backward Citations)

US2537830A Cited
US3645802A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1978-10-27 1979-04-28 1979-10-28 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1982-10-27 1983-04-28 1983-10-28 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1986-10-27 1987-04-28 1987-10-28 $7700.00 Window Closed / Lapsed

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