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US3910997A Expired / Lapsed US ⏱️ 0.0 years remaining

Process for cleaning slurry coolers

Assignee: Atlantic Richfield Co
•
Filing: 1971-07-28
•
Granted: 1975-10-07
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Expires: 1991-07-28
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Abstract

Abstract Plating deposits are removed from the surface of tubes of heat exchangers used to control exothermic reactions and cool hot slurries in which the quantity of reaction product exceeds the solubility limit at surface temperature by periodically substituting a hot fluid for the cooling liquid.

Inventors

  • 👤 Anders E Andersen
  • 👤 Alan R Hirsig
  • 👤 Walter A Mameniskis
  • 👤 Frank W Melpolder

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-08 12:25
CPC Classifications
F; F28; F28G; F28G9/00; C; C07; C07C; C07C51/00; C07C51/16; C07C51/21; C07C51/255; C07C51/265

Claims Analysis

Total Claims: 6
Claim 1
Independent Claim 226 words
THE PROCESS FOR OPERATING A HEAT EXCHANGER WHEREIN A REACTION SYSTEM COMPRISING A SLURRY IS COOLED BY PASSING SAID SLURRY THROUGH ONE SIDE OF SAID HEAT EXCHANGE AND PASSING A COOLER LIQUID THROUGH THE OTHER SIDE OF SAID HEAT EXCHANGER. THE IMPROVEMENT WHICH CONSIST OF: REGULATING THE COMPOSITION OF SAID SLURRY BY CONDUCTING THE OXIDATION OF METAXYLENE BY AIR TO ISOPHTHALIC ACID IN AN AQUEOUS ACETIC ACID SOLVENT CONTAINING A SOLUTION OF COBALT AS CATALYST, SAID SLURRY TENDING TO DEPOSIT PLATING DEPOSITS OF SLURRIED MATERIAL ONTO THE SURFACE OF THE PROCESS SIDE OF THE EXCHANGER, SAID PLATING COMPRISING ORGANIC COMPOUNDS AND ACIDS, REGULATING THE TEMPERATURE OF THE REACTION SYSTEM IN THE HEAT EXCHANGER TO MAINTAIN A REACTION TEMPERATURE OF FROM ABOUT 200*F TO 275*F. BY CIRCULATING COOLING WATER IN SAID HEAT EXCHANGER, AND OPERATING THE HEAT EXCHANGER IN AN IMPROVED MANNER BY PERIODICALLY SUBSTITUTING LOW PRESSURE STEAM FOR SAID COOLING WATER TO REMOVE PLATING DEPOSITS OF SLURRIED MATERIAL FROM THE SURFACE OF THE PROCESS SIDE OF THE EXCHANGER, THE TEMPERATURE OF THE LOW PRESSURE STEAM BEING LESS THAN THE MELTING POINT OF ISOPHTHALIC ACID BUT SUFFICIENTLY HOT TO ALTER THE ADHESION OF SUCH DEPOSITS TO PERMIT SUCH DEPOSITS TO BECOME DISPERSED AND WITHDRAWN AS A COMPONENT OF WITHDRAWN SLURRY, SAID LOW PRESSURE STEAM HEATING THE HEAT EXCHANGER AND CIRCULATING SLURRY TO A TEMPERATURE OF ABOUT 200*F.
Claim 2
Dependent Claim 226 words
THE PROCESS FOR OPERATING A HEAT EXCHANGER WHEREIN A REACTION SYSTEM COMPRISING A SLURRY IS COOLED BY PASSING SAID SLURRY THROUGH ONE SIDE OF SAID HEAT EXCHANGE AND PASSING A COOLER LIQUID THROUGH THE OTHER SIDE OF SAID HEAT EXCHANGER. THE IMPROVEMENT WHICH CONSIST OF: REGULATING THE COMPOSITION OF SAID SLURRY BY CONDUCTING THE OXIDATION OF METAXYLENE BY AIR TO ISOPHTHALIC ACID IN AN AQUEOUS ACETIC ACID SOLVENT CONTAINING A SOLUTION OF COBALT AS CATALYST, SAID SLURRY TENDING TO DEPOSIT PLATING DEPOSITS OF SLURRIED MATERIAL ONTO THE SURFACE OF THE PROCESS SIDE OF THE EXCHANGER, SAID PLATING COMPRISING ORGANIC COMPOUNDS AND ACIDS, REGULATING THE TEMPERATURE OF THE REACTION SYSTEM IN THE HEAT EXCHANGER TO MAINTAIN A REACTION TEMPERATURE OF FROM ABOUT 200*F TO 275*F. BY CIRCULATING COOLING WATER IN SAID HEAT EXCHANGER, AND OPERATING THE HEAT EXCHANGER IN AN IMPROVED MANNER BY PERIODICALLY SUBSTITUTING LOW PRESSURE STEAM FOR SAID COOLING WATER TO REMOVE PLATING DEPOSITS OF SLURRIED MATERIAL FROM THE SURFACE OF THE PROCESS SIDE OF THE EXCHANGER, THE TEMPERATURE OF THE LOW PRESSURE STEAM BEING LESS THAN THE MELTING POINT OF ISOPHTHALIC ACID BUT SUFFICIENTLY HOT TO ALTER THE ADHESION OF SUCH DEPOSITS TO PERMIT SUCH DEPOSITS TO BECOME DISPERSED AND WITHDRAWN AS A COMPONENT OF WITHDRAWN SLURRY, SAID LOW PRESSURE STEAM HEATING THE HEAT EXCHANGER AND CIRCULATING SLURRY TO A TEMPERATURE OF ABOUT 200*F.
Claim 3
Dependent Claim 15 words
The process of claim 1 wherein said heat exchanger is a shell and tube type.
Claim 4
Dependent Claim 33 words
The process of claim 1 wherein said heat exchanger is a double pipe type wherein the process liquid is passed through the inside and the cooling fluid is passed through the annular space.
Claim 5
Dependent Claim 119 words
An improved process of controlling the temperature of a circulating slurry of reaction system in the exothermic oxidation reaction of metaxylene to isophthalic acid in the presence of acetic acid as solvent and a soluble catalyst comprising: cooling the reaction product in a heat exchanger so as to maintain a reaction temperature of from about 200*F. to 275*F. by circulating cooling water in said heat exchanger; and periodically substituting low pressure steam for said cooling water in said heat exchanger to heat the heat exchanger and circulating slurry to a temperature oF about 200*F., thereby dispersing into said circulating slurry of reaction system the organic deposits previously formed in said heat exchanger, said deposits comprising organic compounds and acids.
Claim 6
Dependent Claim 119 words
An improved process of controlling the temperature of a circulating slurry of reaction system in the exothermic oxidation reaction of metaxylene to isophthalic acid in the presence of acetic acid as solvent and a soluble catalyst comprising: cooling the reaction product in a heat exchanger so as to maintain a reaction temperature of from about 200*F. to 275*F. by circulating cooling water in said heat exchanger; and periodically substituting low pressure steam for said cooling water in said heat exchanger to heat the heat exchanger and circulating slurry to a temperature oF about 200*F., thereby dispersing into said circulating slurry of reaction system the organic deposits previously formed in said heat exchanger, said deposits comprising organic compounds and acids.

References Cited (Backward Citations)

US3004397A Cited
US3305320A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1978-10-06 1979-04-07 1979-10-07 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1982-10-06 1983-04-07 1983-10-07 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1986-10-06 1987-04-07 1987-10-07 $7700.00 Window Closed / Lapsed

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