Halo derivatives of vanadium organophosphates

Claim 2

A COMPOSITION OF MATTER REPRESENTED BY THE FORMULA:

Claim 3

A composition of matter represented by the formula:

Claim 4

A composition of matter represented by the formula:

Claim 5

The composition of claim 2 wherein said halo is chloro.

Claim 6

The composition of claim 2 wherein R1 is methyl, ethyl, propyl, butyl or mixtures thereof and R2 is Beta -chloroethyl, Beta -chloropropyl, Beta -chlorobutyl, Beta -bromoethyl, Beta -bromopropyl, Beta -bromobutyl or mixtures thereof.

Claim 7

The composition of claim 2 wherein R1 is ethyl and R2 is chloroethyl.

Claim 8

The composition of claim 2 wherein R1 is ethyl and R2 is bromoethyl.

Claim 9

The composition of claim 2 wherein the composition of matter is a polymeric form represented by the formula:

Claim 10

A process for producing a halo derivative of a vanadium organophosphate composition which comprises reacting in an aqueous solution a vanadyl salt wherein the vanadium is in its tetravalent form with a salt of an organophosphoric and, said salt having the formula: M(OP(O)w(R1O)x(OR2)y)2 wherein M is beryllium, magnesium, calcium, zinc, strontium, cadmium, barium or mixtures thereof, R1 is hydrogen, an alkyl or cycloalkyl having 1 to 16 carbon atoms or an aryl having up to 16 carbon atoms, R2 is a haloalkyl, pseudohaloalkyl, halocycloalkyl or pseudohalocycloalkyl, having 1 to 16 carbon atoms or a haloaryl or pseudohaloaryl having up to 16 carbon atoms, said halo being fluoro, chloro, iodo or bromo and said pseudohalo being cyano, cyanato or hydroxyl, w has a value of 0 or 1, x has a value of 0 or 1, y has a value of 1 or 2 and the sum of x and y is 2, at a temperature in the range of 0* to 200*C and recovering the resulting product from the aqueous solution.

Claim 11

A process for producing a halo derivative of a vanadium organophosphate composition which comprises reacting in an aqueous solution a vanadyl salt wherein the vanadium is in its tetravalent form with a salt of an organophosphoric and, said salt having the formula: M(OP(O)w(R1O)x(OR2)y)2 wherein M is beryllium, magnesium, calcium, zinc, strontium, cadmium, barium or mixtures thereof, R1 is hydrogen, an alkyl or cycloalkyl having 1 to 16 carbon atoms or an aryl having up to 16 carbon atoms, R2 is a haloalkyl, pseudohaloalkyl, halocycloalkyl or pseudohalocycloalkyl, having 1 to 16 carbon atoms or a haloaryl or pseudohaloaryl having up to 16 carbon atoms, said halo being fluoro, chloro, iodo or bromo and said pseudohalo being cyano, cyanato or hydroxyl, w has a value of 0 or 1, x has a value of 0 or 1, y has a value of 1 or 2 and the sum of x and y is 2, at a temperature in the range of 0* to 200*C and recovering the resulting product from the aqueous solution.

Claim 12

The process of claim 8 wherein said vanadyl salt is vanadyl sulfate, chloride, bromide, iodide, oxalate, acetate or mixtures thereof.

Claim 13

The process of claim 8 wherein said halo is chloro.

Claim 14

The process of claim 8 wherein R1 is methyl, ethyl, propyl, butyl or mixtures thereof and R2 is Beta -chloroethyl, Beta -chloropropyl, Beta -chlorobutyl, Beta -bromoethyl, Beta -chloropropyl, Beta -bromobutyl or mixtures thereof.

Claim 15

A process for producing a halo derivative of a vanadium organophosphate which comprises reacting in an aqueous solution vanadyl sulfate with a salt of an organophosphoric acid, said salt having the formula:

Claim 16

A process for producing a halo derivative of a vanadium organophosphate which comprises reacting in an aqueous solution vanadyl sulfate with a salt of an organophosphoric acid, said salt having the formula:

Claim 17

The process of claim 12 wherein M is magnesium.