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US3909485A Expired / Lapsed US ⏱️ 0.0 years remaining

Flame-resistant glass-fiber reinforced polytetramethylene terephthalate resin composition

Assignee: Mitsubishi Chemical Corp
•
Filing: 1974-07-10
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Granted: 1975-09-30
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Expires: 1994-07-10
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Abstract

Abstract A flame-resistant glass-fiber reinforced resin composition comprising glass-fiber filled polytetramethylene terephthalate, a flame retardant, and antimony trioxide, characterized in that said flame retardant consists of a compound represented by the general formula (I), wherein X represents a chlorine or bromine atom and R represents a residue for connecting the left and right ring structures to form a tetrahydrofuran, cyclopentane, cyclooctane, endomethylenecylohexane, or endomethylenehydroindan ring and a halogenated bisphenol-based epoxy resin having a degree of halogenation of 10% by weight or more and represented by the general formula (II), WHEREIN Y represents a chlorine or bromine atom, each of i, j, k, and l represents a number of from 1 to 4, and (n + m) represents a mean degree of polymerization in the range of from 0 to 10; the proportions of the compounds of the formulas (I) and (II) being 3 to 30 parts by weight and 0.3 to 25 parts by weight, respectively, per 100 parts by weight of said polytetramethylene terephthalate and the weight ratio of said flame retardant to said antimony trioxide being 0.25 - 6.00 to 1. The present composition is excellent in mechanical properties, thermal properties, moldability and flame resistance.

Inventors

  • 👤 Masafumi Hongo
  • 👤 Ryoji Handa
  • 👤 Kazumasa Kamada

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-26 21:15
CPC Classifications
C; C08; C08K; C08K3/00; C08K3/18; C08K3/20; C08K3/22; C08K3/2279; C08K5/00; C08K5/02; C08L; C08L67/00; C08L67/02; Y; Y10; Y10S; Y10S260/00; Y10S260/24

Claims Analysis

Total Claims: 9
Claim 1
Independent Claim 33 words
A FLAME-RESESTANT, GLASS-FIBER-REINFORCED RESIN COMPOSITION COMPRISING GLASS-FIBER-FILLED POLYTETRAMETHYLENE TEREPHTHALATE, A FLAME RETARDANT, AND ANTIMONY TRIOXIDE CHARACTERIZED IN THAT SAID FLAME RETARDANT CONSISTS OF AT LEAST ONE COMPOUND REPRESENTED BY THE GENERAL FORMULA (I):
Claim 2
Dependent Claim 33 words
A FLAME-RESESTANT, GLASS-FIBER-REINFORCED RESIN COMPOSITION COMPRISING GLASS-FIBER-FILLED POLYTETRAMETHYLENE TEREPHTHALATE, A FLAME RETARDANT, AND ANTIMONY TRIOXIDE CHARACTERIZED IN THAT SAID FLAME RETARDANT CONSISTS OF AT LEAST ONE COMPOUND REPRESENTED BY THE GENERAL FORMULA (I):
Claim 3
Dependent Claim 48 words
A flame-resistant, glass-fiber-reinforced resin composition according to claim 1, wherein the flame retardant consists of a compound represented by the general formula (I) and a halogenated bisphenol-based epoxy resin having a degree of halogenation of 10 percent by weight or more and represented by the general formula (II).
Claim 4
Dependent Claim 20 words
A composition according to claim 1, wherein the glass-fiber content of the composition is 5 to 40 percent by weight.
Claim 5
Dependent Claim 20 words
A composition according to claim 1, wherein in the general formula (II), m 0 and i j k l 2.
Claim 6
Dependent Claim 32 words
A composition according to claim 3, wherein the polytetramethylene terephthalate has an intrinsic viscosity ( eta ) of 0.6 to 1.5 dl/g as measured in tetrachloroethane-phenol (50 : 50) mixture at 25*C.
Claim 7
Dependent Claim 20 words
A composition according to claim 1, wherein the compound of the formula (I) is a compound represented by the formula:
Claim 8
Dependent Claim 33 words
A composition according to claim 4, wherein n is a number of 1.5 to 10, and the weight ratio of the flame retardants to antimony trioxide is from 0.25 - 5.0 to 1.
Claim 9
Dependent Claim 34 words
A composition according to claim 4, wherein n is 0 or a number of less than 1.5, and the weight ratio of the flame retardants to antimony trioxide is 0.25 - 5.0 to 1.

References Cited (Backward Citations)

US3535253A Cited
US3524901A Cited
US3814725A Cited
US3645962A Cited
US3751396A Cited
US3671487A Cited
US3843615A Cited
US3855277A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1978-09-29 1979-03-31 1979-09-30 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1982-09-29 1983-03-31 1983-09-30 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1986-09-29 1987-03-31 1987-09-30 $7700.00 Window Closed / Lapsed

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