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US3909477A Expired / Lapsed US ⏱️ 0.0 years remaining

Warp-sizing compositions and yarns sized therewith

Assignee: Dow Chemical Co
•
Filing: 1973-06-27
•
Granted: 1975-09-30
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Expires: 1993-06-27
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Abstract

Abstract Aqueous warp sizing compositions and the sized yarns obtained by applying the new sizing composition to textile yarn, removing excess composition from the yarn, drying the resulting wet-sized yarn and separating the individual yarns (ends) from one another before or after drying. The novel aqueous sizing composition is a blend of a lubricant, a surfactant, a redispersible latex composition and various optional ingredients. The redispersible latex component comprises a blend of (a) a six-membered carbocyclic compound having two carboxyl substituents and which is soluble in aqueous alkaline media such as the disodium salt of 1,2,3,6-tetrahydrophthalic acid and (b) an aqueous colloidal dispersion of a film-forming carboxyl-containing polymer such as a copolymer of styrene, butadiene and acrylic acid.

Inventors

  • 👤 Norman L Madison
  • 👤 Victor E Meyer
  • 👤 Gerald P Beaumont
  • 👤 Alfred R Nelson

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-25 13:59
CPC Classifications
D; D06; D06M; D06M15/00; D06M15/19; D06M15/21; D06M15/263; D06M15/693

Claims Analysis

Total Claims: 13
Claim 1
Independent Claim 113 words
A TEXTILE YARN SIZING COMPOSITION COMPRISING (A) AN AQUEOUS COLLODIAL DISPERSION CONTAINING (1) A FILM-FORMING COPOLYMER OF FROM ABOUT 1 PERCENT TO ABOUT 10 PERCENT OF AN A,BETHYLENICALLY UNSATURATED CARBOXYLIC ACID AND THE BALANCE OF AN ESSENTIALLY WATER-INSOLUBLE, ETHYLENICALLY UNSATURATED MONOMER COMPOSITION AND (2) A SIX-MEMBERED CARBOCYCLIC COMPOUND HAVING TWO VICINAL CARBOXY GROUPS WHICH IS SOLUBLE IN AQUEOUS ALKALINE MEDIA IN AN AMOUNT SUFFICIENT TO PROVIDE REDISPERSIBILITY OF THE COPOLYMER RESIDUE OBTAINED BY DRYING THE AQUEOUS COLLOIDAL DISPERSION AT A PH OF FROM ABOUT 7 TO ABOUT 14 AND (B) A LUBRICANT, SAID SIZING COMPOSITION ALSO CONTAINING FOR ABOUT 0.5 PERCENT TO ABOUT 7 PERCENT, BASED ON THE COPOLYMER WEIGHT, OF A SURFACTANT.
Claim 2
Dependent Claim 113 words
A TEXTILE YARN SIZING COMPOSITION COMPRISING (A) AN AQUEOUS COLLODIAL DISPERSION CONTAINING (1) A FILM-FORMING COPOLYMER OF FROM ABOUT 1 PERCENT TO ABOUT 10 PERCENT OF AN A,BETHYLENICALLY UNSATURATED CARBOXYLIC ACID AND THE BALANCE OF AN ESSENTIALLY WATER-INSOLUBLE, ETHYLENICALLY UNSATURATED MONOMER COMPOSITION AND (2) A SIX-MEMBERED CARBOCYCLIC COMPOUND HAVING TWO VICINAL CARBOXY GROUPS WHICH IS SOLUBLE IN AQUEOUS ALKALINE MEDIA IN AN AMOUNT SUFFICIENT TO PROVIDE REDISPERSIBILITY OF THE COPOLYMER RESIDUE OBTAINED BY DRYING THE AQUEOUS COLLOIDAL DISPERSION AT A PH OF FROM ABOUT 7 TO ABOUT 14 AND (B) A LUBRICANT, SAID SIZING COMPOSITION ALSO CONTAINING FOR ABOUT 0.5 PERCENT TO ABOUT 7 PERCENT, BASED ON THE COPOLYMER WEIGHT, OF A SURFACTANT.
Claim 3
Dependent Claim 11 words
The sizing composition of claim 1 which also includes a thickener.
Claim 4
Dependent Claim 28 words
The sizing composition of claim 1 in which the amount of carboxyclic compound is from about 2 parts to about 8 parts for each 100 parts of copolymer.
Claim 5
Dependent Claim 28 words
The sizing composition of claim 1 in which the Alpha , Beta -ethylenically unsaturated carboxylic acid comprises from about 3 percent to about 5 percent of the copolymer.
Claim 6
Dependent Claim 15 words
The sizing composition of claim 1 in which the carboxyclic compound is a phthalic acid.
Claim 7
Dependent Claim 16 words
The sizing composition of claim 1 in which the copolymer contains a copolymerized aliphatic conjugated diene.
Claim 8
Dependent Claim 14 words
The sizing composition of claim 6 in which the aliphatic conjugated diene is butadiene.
Claim 9
Dependent Claim 17 words
The sizing composition of claim 6 in which the copolymer also contains a copolymerized alkenyl aromatic compound.
Claim 10
Dependent Claim 14 words
The sizing composition of claim 8 in which the alkenyl aromatic compound is styrene.
Claim 11
Dependent Claim 15 words
The sizing composition of claim 6 in which the carboxyclic compound is a tetrahydrophthalic acid.
Claim 12
Dependent Claim 17 words
An article of manufacture comprising the dried sizing compound of claim 1 deposited on a textile yarn.
Claim 13
Dependent Claim 13 words
The article of claim 11 in which the textile yarn contains synthetic fiber.

References Cited (Backward Citations)

US2768090A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1978-09-29 1979-03-31 1979-09-30 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1982-09-29 1983-03-31 1983-09-30 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1986-09-29 1987-03-31 1987-09-30 $7700.00 Window Closed / Lapsed

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