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US3908001A Expired / Lapsed US ⏱️ 0.0 years remaining

Manufacture of chlorine hydrate

Assignee: Energy Development Associates Inc
•
Filing: 1971-11-18
•
Granted: 1975-09-23
•
Expires: 1991-11-18
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Abstract

Abstract Chlorine hydrate is made by vaporizing liquid water to gaseous form, mixing it with gaseous chlorine and contacting the mixture with a low temperature heat transfer means which converts it to solid chlorine hydrate. The liquid water to be converted to gaseous form is most preferably that present in an aqueous metal chloride electrolyte employed in an electric battery of the metal electrode-metal chloride electrolyte-chlorine electrode type, the chlorine is also obtained from the battery, during charging thereof, and the chlorine hydrate produced is reconverted to chlorine and returned to the battery when it is being discharged. An apparatus for producing chlorine hydrate may be simply constructed, containing means for adding water (preferably in an aqueous halide solution) and chlorine to an apparatus reaction zone, means for vaporizing water and mixing it with the chlorine and cooling or refrigerating means for cooling the mixed chlorine and water vapors to form chlorine hydrate. The apparatus and method are adapted for the continuous feeding of sources of chlorine and water so as to continuously produce the desired chlorine hydrate.

Inventors

  • 👤 Philip C Symons
  • 👤 Harry K Bjorkman

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-06 16:17
CPC Classifications
C; C01; C01B; C01B7/00; C01B7/01; C01B7/015; H; H01; H01M; H01M8/00; H01M8/06; Y; Y02; Y02E; Y02E60/00; Y02E60/30; Y02E60/50; Y02P; Y02P70/00; Y02P70/50

Claims Analysis

Total Claims: 7
Claim 1
Independent Claim 99 words
A METHOD FOR FORMING CHLORINE HYDRATE WHICH COMPRISES VAPORIZING AQUEOUS ZINC CHLORIDE SOLUTION HAVING A CONCENTRATION GREATER THAN 10 PERCENT ZINC CHLORIDE WITH 0.1 TO 4 VOLUMES OF CHLORINE DISSOLVED AND/OR DISPERSED THEREIN TO FORM A GASEOUS FORM OF WATER AND CHLORINE AND CONTACTING SAID MIXTURE OF GASES WITH A HEAT TRANSFER MEANS AT A TEMPERATURE BETWEEN ABOUT -50* TO ABOUT +9*C TO CONVERT THE GAS MIXTURE TO CHLORINE HYDRATE IN SOLID FORM THE MOLAR RATIO OF WATER AND CHLORINE IN GASEOUS FORM CONTACTING THE HEAT TRANSFER MEANS BEING FROM ABOUT 0.01 TO ABOUT 8:1 AND FURTHER PROVIDING THAT
Claim 2
Independent Claim 99 words
A METHOD FOR FORMING CHLORINE HYDRATE WHICH COMPRISES VAPORIZING AQUEOUS ZINC CHLORIDE SOLUTION HAVING A CONCENTRATION GREATER THAN 10 PERCENT ZINC CHLORIDE WITH 0.1 TO 4 VOLUMES OF CHLORINE DISSOLVED AND/OR DISPERSED THEREIN TO FORM A GASEOUS FORM OF WATER AND CHLORINE AND CONTACTING SAID MIXTURE OF GASES WITH A HEAT TRANSFER MEANS AT A TEMPERATURE BETWEEN ABOUT -50* TO ABOUT +9*C TO CONVERT THE GAS MIXTURE TO CHLORINE HYDRATE IN SOLID FORM THE MOLAR RATIO OF WATER AND CHLORINE IN GASEOUS FORM CONTACTING THE HEAT TRANSFER MEANS BEING FROM ABOUT 0.01 TO ABOUT 8:1 AND FURTHER PROVIDING THAT
Claim 3
Dependent Claim 87 words
A method according to claim 1, wherein gaseous chlorine, released from aqueous zinc chloride, is continuously fed into a hydrate-forming zone, water vapor is continuously formed by vaporization of the liquid water, chlorine hydrate is continuously formed, the feed of chlorine and the vaporization of water are regulated to maintain a molar ratio of about 1:1 and the temperature of the heat transfer means, said heat transfer means and the feed of chlorine and vaporization of water are increased or decreased together to maintain said molar ratio.
Claim 4
Dependent Claim 92 words
A method according to claim 1, wherein both the gaseous chlorine and the liquid water utilizied are obtained from an aqueous metal chloride solution in which the gaseous chlorine is at least partially dissolved and/or dispersed, vaporization of the liquid water to gaseous form is effected by heating it, the proportions of water and chlorine gas contacting the heat transfer means are maintained at a molar ratio of about 0.01:1 to 12:1, and the heat transfer means is a refrigerating means having a refrigerant which has a temperature from -30* to +9*C.
Claim 5
Dependent Claim 96 words
A method as defined in claim 1, wherein gaseous chlorine, released from aqueous zinc chloride, is continuously fed into a hydrate-forming zone, water, in liquid form, is continuously fed into saiD zone, water vapor or gas is continuously formed by vaporization of the liquid water, chlorine hydrate is continuously formed, the feed of chlorine and the vaporization of water are regulated to maintain a molar ratio of about 1:1, and the heat removed by the refrigerating means and the feed of chlorine and vaporization of water being increased or decreased together to maintain said molar ratio.
Claim 6
Dependent Claim 24 words
The method of claim 1, wherein the concentration of zinc chloride ranges from above 10 percent by weight to about 35 percent by weight.
Claim 7
Dependent Claim 62 words
The method of claim 1, wherein the gaseous chlorine and water are obtained from an aqueous zinc chloride solution of a concentration of greater than 10 percent zinc chloride, with 0.1 to 4 volumes of chlorine dissolved and/or dispersed therein and the molar ratio of water and chlorine in gaseous form contacting the heat transfer means is from about 0.01 to 8:1.

References Cited (Backward Citations)

US2035990A Cited
US2570612A Cited
US2656011A Cited
US2785055A Cited
US3044862A Cited
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US3713888A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1978-09-22 1979-03-24 1979-09-23 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1982-09-22 1983-03-24 1983-09-23 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1986-09-22 1987-03-24 1987-09-23 $7700.00 Window Closed / Lapsed

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