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US3907882A Expired / Lapsed US ⏱️ 0.0 years remaining

Method for the oxycarbonylation of ethylene and propylene

Assignee: Roehm GmbH Darmstadt
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Filing: 1974-03-29
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Granted: 1975-09-23
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Expires: 1994-03-29
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Abstract

Abstract An improved method for the oxycarbonylation of ethylene and propylene to form Alpha , Beta -unsaturated carboxylic acids, which method employs a catalyst consisting essentially of a rhenium compound and, as a co-catalyst, at least one member selected from the group consisting of compounds of metals of the second and third main groups of the Periodic System, compounds of metals and the fourth, fifth, and sixth sub-groups of the Periodic System, and compounds of manganese, iron, and copper.

Inventors

  • 👤 Wolfgang Gaenzler
  • 👤 Klaus Kabs
  • 👤 Guenter Schroeder

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-05 19:07
CPC Classifications
C; C07; C07C; C07C51/00; C07C51/10; C07C51/145; B; B01; B01J; B01J23/00; B01J23/16; B01J23/32; B01J23/36; B01J23/70; B01J23/76; B01J23/84; B01J23/889; B01J23/8896; C07C51/14

Claims Analysis

Total Claims: 7
Claim 1
Independent Claim 35 words
A method as in claim 1 wherein said co-catalyst is a compound of a metal selected from the group consisting of magnesium, calcium, aluminum, gallium, titanium, hafnium, vanadium, tantalum, chromium, tungsten, manganese, copper, and iron.
Claim 2
Dependent Claim 16 words
A method as in claim 1 wherein said co-catalyst is a compound of a multivalent metal.
Claim 3
Dependent Claim 13 words
A method as in claim 1 wherein said co-catalyst is an aluminum compound.
Claim 4
Dependent Claim 20 words
A method as in claim 1 wherein said catalyst consists essentially of a rhenium (V) salt and an aluminum compound.
Claim 5
Dependent Claim 14 words
A method as in claim 1 wHerein an alkali metal carboxylate is additionally present.
Claim 6
Dependent Claim 17 words
A method as in claim 6 wherein said alkali carboxylate is a carboxylate of sodium or lithium.
Claim 7
Dependent Claim 13 words
A method as in claim 1 wherein ethylene is converted to acrylic acid.

References Cited (Backward Citations)

US2739169A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1978-09-22 1979-03-24 1979-09-23 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1982-09-22 1983-03-24 1983-09-23 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1986-09-22 1987-03-24 1987-09-23 $7700.00 Window Closed / Lapsed

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