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US3907668A Expired / Lapsed US ⏱️ 0.0 years remaining

Hydrodesulfurization of petroleum distillates

Assignee: Chevron USA Inc
•
Filing: 1974-03-25
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Granted: 1975-09-23
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Expires: 1994-03-25
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Abstract

Abstract Sulfur-containing petroleum distillates are desulfurized with hydrogen and with a catalyst composite containing a Group VI-B hydrogenating component, at least one iron group hydrogenating component and alumina. The catalyst is prepared by calcining alumina having a bayerite content of 0-50 wt. percent, at a temperature of 800*-1600*F, impregnating the calcined alumina with the hydrogenating components and calcining the impregnated alumina at 800*-1600*F. The composite catalyst is characterized as having a pore volume of at least 0.5cc/g, a surface area of at least 150 m2/g and an average pore radius of 45 to 75 Angstrom units. At least 65 percent of the pore volume of the composite catalyst is in pores having a radius in the range of 50 - 300 Angstrom units.

Inventors

  • 👤 Robert D Christman
  • 👤 Geoffrey R Wilson

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-04 13:32
CPC Classifications
B; B01; B01J; B01J23/00; B01J23/70; B01J23/76; B01J23/84; B01J23/85; B01J23/88; B01J35/00; B01J35/60; B01J37/00; B01J37/20; C; C10; C10G; C10G45/00; C10G45/02; C10G45/04; C10G45/06; C10G45/08; B01J35/61; B01J35/615; B01J35/63; B01J35/635; B01J35/64; B01J35/643; B01J35/647

Claims Analysis

Total Claims: 5
Claim 1
Independent Claim 187 words
A PROCESS FOR CATALYTICALLY HYYDRODE-SULFURIZING A SULFUR CONTAINING ASPHALTENE-FREE PETROLEUM DISTILLATE WHICH COMPRISES CONTACTING SAID DISTILLATE WITH HYDROGEN AT HYDROSULFURIZATION CONDITIONS AND WITH A CATALYST CONSISTING ESSENTIALLY OF A HYDROGENATING COMPONENT SELECTED FROM THE GROUP VI-B METALS AND AT LEAST ONE HYDROGENATING COMPONENT SELECTED FROM THE IRON GROUP METALS COMPOSITED WITH AN ALUMINA BASE, AT LEAST 65 PERCENT OF THE PORE VOLUME OF SAID COMPOSITE CATALYST BEING IN PORES HAVING A RADIUS IN THE RANGE OF 50 TO 300 A UNITS, THE AVERAGE PORE RADIUS OF SAID COMPOSITE CATALYST BEING IN THE RANGE OF 45 TO 75A UNITS, THE SURFACE AREA OF SAID COMPOSITE CATALYST BENG AT LEAST 150 SQUARE METERS PER GRAM, THE PORE VOLUME OF SAID COMPOSITE CATALYST BEING AT LEAST 0.5 CC PER GRAM SAID COMPOSITE CATALYST HAVING BEEN PREPARED BY CALCINING AN ALUMINA SUPPORT HAVING A BAYERITE CONTENT IN THE RANGE OF 0 TO 50 WEIGHT PERCENT AT A TEMPERATURE IN THE RANGE OF 800* TO 1600*F., IMPREGNATING SAID CALCINED ALUMINA SUPPORT WITH SAID HYDROGENATING COMPONENTS, AND THEREAFTER CALCINING SAID IMPREGNATED ALUMINA SUPPORT AT A TEMPERATURE IN THE RANGE OF 800* TO 1600*F.
Claim 2
Dependent Claim 187 words
A PROCESS FOR CATALYTICALLY HYYDRODE-SULFURIZING A SULFUR CONTAINING ASPHALTENE-FREE PETROLEUM DISTILLATE WHICH COMPRISES CONTACTING SAID DISTILLATE WITH HYDROGEN AT HYDROSULFURIZATION CONDITIONS AND WITH A CATALYST CONSISTING ESSENTIALLY OF A HYDROGENATING COMPONENT SELECTED FROM THE GROUP VI-B METALS AND AT LEAST ONE HYDROGENATING COMPONENT SELECTED FROM THE IRON GROUP METALS COMPOSITED WITH AN ALUMINA BASE, AT LEAST 65 PERCENT OF THE PORE VOLUME OF SAID COMPOSITE CATALYST BEING IN PORES HAVING A RADIUS IN THE RANGE OF 50 TO 300 A UNITS, THE AVERAGE PORE RADIUS OF SAID COMPOSITE CATALYST BEING IN THE RANGE OF 45 TO 75A UNITS, THE SURFACE AREA OF SAID COMPOSITE CATALYST BENG AT LEAST 150 SQUARE METERS PER GRAM, THE PORE VOLUME OF SAID COMPOSITE CATALYST BEING AT LEAST 0.5 CC PER GRAM SAID COMPOSITE CATALYST HAVING BEEN PREPARED BY CALCINING AN ALUMINA SUPPORT HAVING A BAYERITE CONTENT IN THE RANGE OF 0 TO 50 WEIGHT PERCENT AT A TEMPERATURE IN THE RANGE OF 800* TO 1600*F., IMPREGNATING SAID CALCINED ALUMINA SUPPORT WITH SAID HYDROGENATING COMPONENTS, AND THEREAFTER CALCINING SAID IMPREGNATED ALUMINA SUPPORT AT A TEMPERATURE IN THE RANGE OF 800* TO 1600*F.
Claim 3
Dependent Claim 36 words
The process of claim 1 wherein said composite catalyst comprises from 0.1 to 5 weight percent of at least one material of the iron group metals, from 5.0 to 15 weight percent of molybdenum, and alumina.
Claim 4
Dependent Claim 33 words
The process of claim 1 wherein said composite catalyst comprises from 0.1 to 5 weight percent cobalt, from 0.1 to 5 weight percent nickel, from 5.0 to 15 weight percent molybdenum, and alumina.
Claim 5
Dependent Claim 64 words
The process of claim 1 wherein the hydrodesulfurization process is conducted at a temperature in the range of 550* to 800* F., at a liquid weight hourly space velocity of 0.25 to 10, at a pressure in the range of 200 to 5000 psig, and at a hydrogen rate in the range of 700 to 3000 standard cubic feet per barrel of distillate feed.

References Cited (Backward Citations)

US3340180A Cited
US3383301A Cited
US3594312A Cited
US3714032A Cited
US3814683A Cited
US3814684A Cited
US3814682A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1978-09-22 1979-03-24 1979-09-23 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1982-09-22 1983-03-24 1983-09-23 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1986-09-22 1987-03-24 1987-09-23 $7700.00 Window Closed / Lapsed

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