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US3907662A Expired / Lapsed US ⏱️ 0.0 years remaining

Process of preparing desulfurized light oil and fuel gas from heavy oil

Assignee: Mitsui Engineering and Shipbuilding Co Ltd
•
Filing: 1974-02-14
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Granted: 1975-09-23
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Expires: 1994-02-14
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Abstract

Abstract The process of this invention comprises following steps; (1) heavy oil is converted in a low temperature coking reactor operator at 470*- 550*C and including a fluidized bed containing particles of an alkali metal carbonate compound into particles of carbonaceous residue containing desulfurized decomposition gas, desulfurized light oil, particles of the alkali metal carbonate compound and volatile components; (2) at the same time a portion of the sulfur contained in the heavy oil is fixed to form an alkali metal sulfide by the action of the alkali metal carbonate compound whereby to recover the desulfurized decomposition gas and the desulfurized light oil from the raw temperature coking reactor; (3) the particles of carbonaceous substance residue containing the alkali metal carbonate compound is transferred from the low temperature coking reactor into a high temperature coking reactor including a fluidized bed; (4) the carbonaceous substance residue is treated at an elevated temperature in the bed operating at 550* - 700*C for forming coke particles containing the alkali metal carbonate compound and desulfurized light substance; (5) the desulfurized light substance is admitted into the low temperature coking reactor whereby to recover the desulfurized gas and the desulfurized light oil; (6) the coke particles are transferred into an alkali metal sulfide regeneration reactor from the high temperature coking reactor; (7) the coke particles are contacted in a high temperature bed operating at 600*-800*C with high temperature fuel gas transferred from a heating and gasifying reactor thereby converting the alkali metal sulfide compound which has fixed the sulfur in the heavy oil contained in the coke particles into the alkali metal carbonate compound thus releasing the fixed sulfur as hydrogen sulfide; (8) the hydrogen sulfide containing fuel gas is recovered from the alkali metal sulfide regeneration reactor; (9) the coke particles are transferred into a heating and gasifying reactor provided with a fluidized bed; (10) most of the coke in the coke particles is converted into heated fuel gas in the fluidized bed operating at 700*-1,000*C; (11) the fuel gas is transferred into the alkali metal sulfide regeneration reactor thus recovering the fuel gas as hydrogen sulfide containing fuel gas; and (12) the alkali metal carbonate containing particles from which most of the coke has been removed are circulated through the high temperature coking reactor.

Inventors

  • 👤 Takeshi Kubota
  • 👤 Mikio Ueda

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-29 19:55
CPC Classifications
C; C10; C10G; C10G9/00; C10G9/28; C10G9/32

Claims Analysis

Total Claims: 5
Claim 1
Independent Claim 405 words
IN A PROCESS OF PREPARING DESULFURIZED LIGHT OIL AND FUEL GAS FROM HEAVY OIL BY USING AN ALKALI METAL CARBONATE COMPOUND, THE IMPROVEMENT COMPRISING THE STEPS OF CONVERTING RAW MATERIAL HEAVY OIL IN A LOW TEMPERATURE COKING REACTOR OPERATING AT A TEMPERATURE OF FROM 470* TO 550*C AND INCLUDING A FLUIDIZED BED CONTAINING PARTICLES OF AN ALKALI METAL CARBONATE COMPOUND INTO PARTICLES OF CARBONACEOUS RESIDUE CONTAINING DESULFURIZED DECOMPOSITION GAS, DESULFURIZED LIGHT OIL, PARTICLES OF SAID ALKALI METAL CARBONATE COMPOUND AND AN APPRECIABLE QUANTITY OF VOLATILE COMPONENTS, SIMULTANEOUSLY FIXING A PORTION OF THE SULFUR CONTAINED IN SAID RAW MATERIAL HEAVY OIL TO FORM AN ALKALI METAL SULFIDE BY THE ACTION OF SAID ALKALI METAL CARBONATE COMPOUND TO RECOVER SAID DESULFURIZED DECOMPOSITION GAS AND SAID DESULFURIZED LIGHT OIL FROM SAID LOW TEMPERATURE COKING REACTOR, TRANSFERRING SAID PARTICLES OF CARBONACEOUS SUBSTANCE RESIDUE CONTAINING SAID ALKALI METAL CARBONATE COMPOUND FROM SAID LOW TEMPERATURE COKING REACTOR INTO HIGH TEMPERATURE COKING REACTOR INCLUDING A HIGH TEMPERATURE FLUIDIZED BED, TREATING AT AN ELEVATED TEMPERATURE SAID CARBONACEOUS SUBSTANCE RESIDUE IN SAID HIGH TEMPERATURE FLUIDIZED BED OPERAING AT A TEMPERATURE OF FROM 550* TO 700* C. FORMING COKE PARTICLES CONTAINING SAID ALKALI METAL CARBONATE COMPOUND AND DESULFURIZED LIGHT SUBSTANCE, ADMITTING SAID DESULFURIZED LIGHT SUBSTANCE INTO SAID LOW TEMPERATURE COKING REACTOR TO RECOVER DESULFURIZED GAS AND DESULFURIZED LIGHT OIL, TRANSFERRING SAID COKE PARTICLES INTO AN ALKALI METAL SULFIDE REGENERATION REACTOR FROM SAID HIGH TEMPERATURE COKING REACTOR, CONTACTING SAID COKE PARTICLES IN A HIGH REGENERATION BED OPERATING AT A TEMPERATURE OF FROM 600* TO 800*C WITH HIGH TEMPERATURE FUEL GAS TRANSFERRED FROM A HEATING AND GRATIFYING REACTOR THEREBY CONVERTING SAID ALKALI METAL SULFIDE COMPOUND WHICH HAS FIXED THE SULFUR IN THE RAW MATERIAL HEAVY OIL CONTAINED IN SAID COKE PARTICLES INTO THE ALKALI METAL CARBONATE COMPOUND THUS RELEASING THE FIXED SULFUR AS HYDROGEN SULFIDE, RECOVERING HYDROGEN SULFIDE CONTAINING FUEL GAS FROM SAID AKLALI METAL SULFIDE REGENARATION REACTOR, TRANSFERRING SAID COKE PARTICLES INTO A HEATING AND GRASIFYING REACTOR PROVIDED WITH A GRASIFYING FLUIDIZED BED, CONVERTING MOST OF THE COKE IN THE COKE PARTICLLES INTO HEATED FUEL GAS IN SAID GRASIFYING FLUID IZED BED OPERATING AT A TEMPERATURE OF FROM 700* TO 1,000*C, TRANSFERRING SAID FUEL GAS INTO SID ALKALI METAL SULFIE REGENERATION REACTOR THHUS RECOVERING SID FUEL GAS AS HYDROGEN SULFIDE CONTAINING FUEL GAS, AND RECIRCULATING THE ALKALI METAL CRBONATE CONTAINING PARTICLES FROM WHICH MOST OF THE COKE HAS BEEN REMOVED THROUGH SI HIGH TEMPERATURE COKING REACTOR.
Claim 2
Dependent Claim 405 words
IN A PROCESS OF PREPARING DESULFURIZED LIGHT OIL AND FUEL GAS FROM HEAVY OIL BY USING AN ALKALI METAL CARBONATE COMPOUND, THE IMPROVEMENT COMPRISING THE STEPS OF CONVERTING RAW MATERIAL HEAVY OIL IN A LOW TEMPERATURE COKING REACTOR OPERATING AT A TEMPERATURE OF FROM 470* TO 550*C AND INCLUDING A FLUIDIZED BED CONTAINING PARTICLES OF AN ALKALI METAL CARBONATE COMPOUND INTO PARTICLES OF CARBONACEOUS RESIDUE CONTAINING DESULFURIZED DECOMPOSITION GAS, DESULFURIZED LIGHT OIL, PARTICLES OF SAID ALKALI METAL CARBONATE COMPOUND AND AN APPRECIABLE QUANTITY OF VOLATILE COMPONENTS, SIMULTANEOUSLY FIXING A PORTION OF THE SULFUR CONTAINED IN SAID RAW MATERIAL HEAVY OIL TO FORM AN ALKALI METAL SULFIDE BY THE ACTION OF SAID ALKALI METAL CARBONATE COMPOUND TO RECOVER SAID DESULFURIZED DECOMPOSITION GAS AND SAID DESULFURIZED LIGHT OIL FROM SAID LOW TEMPERATURE COKING REACTOR, TRANSFERRING SAID PARTICLES OF CARBONACEOUS SUBSTANCE RESIDUE CONTAINING SAID ALKALI METAL CARBONATE COMPOUND FROM SAID LOW TEMPERATURE COKING REACTOR INTO HIGH TEMPERATURE COKING REACTOR INCLUDING A HIGH TEMPERATURE FLUIDIZED BED, TREATING AT AN ELEVATED TEMPERATURE SAID CARBONACEOUS SUBSTANCE RESIDUE IN SAID HIGH TEMPERATURE FLUIDIZED BED OPERAING AT A TEMPERATURE OF FROM 550* TO 700* C. FORMING COKE PARTICLES CONTAINING SAID ALKALI METAL CARBONATE COMPOUND AND DESULFURIZED LIGHT SUBSTANCE, ADMITTING SAID DESULFURIZED LIGHT SUBSTANCE INTO SAID LOW TEMPERATURE COKING REACTOR TO RECOVER DESULFURIZED GAS AND DESULFURIZED LIGHT OIL, TRANSFERRING SAID COKE PARTICLES INTO AN ALKALI METAL SULFIDE REGENERATION REACTOR FROM SAID HIGH TEMPERATURE COKING REACTOR, CONTACTING SAID COKE PARTICLES IN A HIGH REGENERATION BED OPERATING AT A TEMPERATURE OF FROM 600* TO 800*C WITH HIGH TEMPERATURE FUEL GAS TRANSFERRED FROM A HEATING AND GRATIFYING REACTOR THEREBY CONVERTING SAID ALKALI METAL SULFIDE COMPOUND WHICH HAS FIXED THE SULFUR IN THE RAW MATERIAL HEAVY OIL CONTAINED IN SAID COKE PARTICLES INTO THE ALKALI METAL CARBONATE COMPOUND THUS RELEASING THE FIXED SULFUR AS HYDROGEN SULFIDE, RECOVERING HYDROGEN SULFIDE CONTAINING FUEL GAS FROM SAID AKLALI METAL SULFIDE REGENARATION REACTOR, TRANSFERRING SAID COKE PARTICLES INTO A HEATING AND GRASIFYING REACTOR PROVIDED WITH A GRASIFYING FLUIDIZED BED, CONVERTING MOST OF THE COKE IN THE COKE PARTICLLES INTO HEATED FUEL GAS IN SAID GRASIFYING FLUID IZED BED OPERATING AT A TEMPERATURE OF FROM 700* TO 1,000*C, TRANSFERRING SAID FUEL GAS INTO SID ALKALI METAL SULFIE REGENERATION REACTOR THHUS RECOVERING SID FUEL GAS AS HYDROGEN SULFIDE CONTAINING FUEL GAS, AND RECIRCULATING THE ALKALI METAL CRBONATE CONTAINING PARTICLES FROM WHICH MOST OF THE COKE HAS BEEN REMOVED THROUGH SI HIGH TEMPERATURE COKING REACTOR.
Claim 3
Dependent Claim 116 words
The process according to claim 1, said process comprising the steps of transferring small particles to the upper layer of respective reactors and large particles to the classifying section of the reactors by utilizing the classifying function of the fluidized bed, transferring by gravity large particles collected at the classifying section in the upper reactor into the lower reactor and transferring small particles collected in the upper layer of the lower reactor into the upper reactor by the vapour phase formed between the low temperature coking reactor and the high temperature coking reactor and between the alkali metal sulfide regeneration reactor and the heating and gasifying reactor thereby supplying necessary quantities of the particles and heat.
Claim 4
Dependent Claim 62 words
The process according to claim 1 wherein a portion of the raw material heavy oil is supplied into the low temperature coking reactor through a nozzle on the head thereof, and a portion of the raw material heavy oil is supplied through a nozzle on the side wall of said reactor thus improving the dispersion of the heavy oil through the particles.
Claim 5
Dependent Claim 43 words
The process according to claim 1 wherein in the upper portion of the low temperature coking reactor are provided a steam admission region, a decomposition gas oil spray region, and a deceleration chamber thus effecting cooling and washing of the desulfurized decomposition products.

References Cited (Backward Citations)

US2862871A Cited
US2953517A Cited
US2853434A Cited
US3661543A Cited
US3803023A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1978-09-22 1979-03-24 1979-09-23 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1982-09-22 1983-03-24 1983-09-23 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1986-09-22 1987-03-24 1987-09-23 $7700.00 Window Closed / Lapsed

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