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US3904709A Expired / Lapsed US ⏱️ 0.0 years remaining

Process for producing thermoplastic resins

Assignee: Sumitomo Chemical Co Ltd
•
Filing: 1973-01-15
•
Granted: 1975-09-09
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Expires: 1993-01-15
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Abstract

Abstract A process for producing a graft co- or terpolymeric thermoplastic resin consisting of an ethylene-propylene rubber and an aromatic vinyl compound or of an ethylene-propylene rubber, an aromatic vinyl compound and a vinyl cyanide compound, characterized by subjecting these materials to solution polymerization in a mixed solvent comprising an aromatic hydrocarbon solvent capable of dissolving the ethylene-propylene rubber and a polar solvent capable of dissolving poly-(aromatic vinyl compound) in the case of the graft-copolymer or aromatic vinyl compound-vinyl cyanide compound copolymer in the case of the graft-terpolymer. The graft-copolymer or graft-terpolymer obtained by the present process is excellent in weather resistance and impact resistance. The impact resistance of the present graft co- or ter-polymer is not affected by processing conditions.

Inventors

  • 👤 Masayoshi Morimoto
  • 👤 Tetsutaro Sanjiki
  • 👤 Hideki Horiike
  • 👤 Motonobu Furuta

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-08 11:47
CPC Classifications
C; C08; C08F; C08F255/00; C08F255/02

Claims Analysis

Total Claims: 9
Claim 1
Independent Claim 263 words
IN A PROCESS FOR PRODUCING A GRAFT COPOLYMER WHICH COMTHERMOPLASTIC RESIN CONSISTING OF AN ETHYLENE-PROPYLENE RUBBER AND AN AROMATIC VINYL COMPOUND OR OF AN ETHYLENE-PROPYLENE RUBBER AN AROMATIC VINYL COMPOUND AND A VINYL CYANIDE COMPOUND BY USING A RADICAL CATALYST THE IMPROVEMENT WHICH COMPRISES SUBJECTING THESE MATERIALS TO SOLUTION POLYMERIZATION AT A TEMPERATURE OF 30* TO 120*C FOR 5 TO 40 HOURS IN A MIXED SOLVENT CCONSISTING OF 95 TO 5% BY WEIGHT OF AT LEAST ONE AROMATIC HYDROCARBON SOLVENT CAPABLE OF DISSOLVING THE ETHYLENE PROPYLENE RUBBER AND 5 TO 95% BY WEIGHT OF AT LAST ONE POLAR SOLVENT CAPABLE OF DISSOLVING POLY (AROMATIC VINYL COMPOUND) IN THE CASE OF THE GRAFTCOPOLYMER OR AROMATIC VINYL COMPOUND-VINYL CYANIDE COMPOUND COPOLYMER IN THE ASE OF THE GRAFT-TERPOLYMER THE AROMATIC HYDRCARBON SOLVENT BEING SELECTED FROM THE GROUP CONSISTING OF BENZENE TOLUENE DIMETHYLBENZENE XYLENE ETHYLBENZENE DIETHYLBENEZENE AND TRIETHYLBENZENE THE POLAR SOLVENT BEING SELECTED FROM THE GROUP CONSISTING OF KETONES ESTERS ETHERS CHLORINE-SUBSTITUTED ALIPHATIC HYDROCARBONS NITROGEN CONTAINING HYDROCARBONS AND SULFUR-CONTAINING HYDROCARBONS THE ETHYLENE-PROPYLENE RUBBER COMPRISING ETHYLENE AND PRPYLENE IN A MOLAR RATIO OF FROM 5.1 TO 1,3 AND BEING SELECTED FROM THE GROUP CONSISTING OF TWO-COMPONENT POLYMER COMPRISING ETHYLENE AND PROPYLENE AND ETHYLENE-PROPYLENE-DIENE TERPOLYMER CONTAINING AS THE THIRD COMPONENT A DIENE SELECTED FROM THE GROUP CONSISTING OF DICYCLOPENTADIENE ETHYLIDENENORBORNENE 1,4-HEXIDIENE, 1-5-HEXADIENE, 2-METHYL-1, 5-HEXADIENE, 1,4CYCLOHEPTADIENE, 1,5-CYCLOOCTADIENE AND MIXTURES THEREOF AND HAVING AN IODINE VALUE OF 4 TO 50, THE AROMATIC VINYL COMPONENT BEING SELECTED FROM THE GROUP CONSISTING OF STYRENE, A-METHYLSTYRENE, A-CHLOROSTYRENE AND DIEMTHYLSTYRENE, AND THE VINYL CYANIDE COMPOUND BEING SELECTED FROM THE GROUP CONSISTING OF ACRYLONITRILE AND METHACRYLONITRILE.
Claim 2
Dependent Claim 263 words
IN A PROCESS FOR PRODUCING A GRAFT COPOLYMER WHICH COMTHERMOPLASTIC RESIN CONSISTING OF AN ETHYLENE-PROPYLENE RUBBER AND AN AROMATIC VINYL COMPOUND OR OF AN ETHYLENE-PROPYLENE RUBBER AN AROMATIC VINYL COMPOUND AND A VINYL CYANIDE COMPOUND BY USING A RADICAL CATALYST THE IMPROVEMENT WHICH COMPRISES SUBJECTING THESE MATERIALS TO SOLUTION POLYMERIZATION AT A TEMPERATURE OF 30* TO 120*C FOR 5 TO 40 HOURS IN A MIXED SOLVENT CCONSISTING OF 95 TO 5% BY WEIGHT OF AT LEAST ONE AROMATIC HYDROCARBON SOLVENT CAPABLE OF DISSOLVING THE ETHYLENE PROPYLENE RUBBER AND 5 TO 95% BY WEIGHT OF AT LAST ONE POLAR SOLVENT CAPABLE OF DISSOLVING POLY (AROMATIC VINYL COMPOUND) IN THE CASE OF THE GRAFTCOPOLYMER OR AROMATIC VINYL COMPOUND-VINYL CYANIDE COMPOUND COPOLYMER IN THE ASE OF THE GRAFT-TERPOLYMER THE AROMATIC HYDRCARBON SOLVENT BEING SELECTED FROM THE GROUP CONSISTING OF BENZENE TOLUENE DIMETHYLBENZENE XYLENE ETHYLBENZENE DIETHYLBENEZENE AND TRIETHYLBENZENE THE POLAR SOLVENT BEING SELECTED FROM THE GROUP CONSISTING OF KETONES ESTERS ETHERS CHLORINE-SUBSTITUTED ALIPHATIC HYDROCARBONS NITROGEN CONTAINING HYDROCARBONS AND SULFUR-CONTAINING HYDROCARBONS THE ETHYLENE-PROPYLENE RUBBER COMPRISING ETHYLENE AND PRPYLENE IN A MOLAR RATIO OF FROM 5.1 TO 1,3 AND BEING SELECTED FROM THE GROUP CONSISTING OF TWO-COMPONENT POLYMER COMPRISING ETHYLENE AND PROPYLENE AND ETHYLENE-PROPYLENE-DIENE TERPOLYMER CONTAINING AS THE THIRD COMPONENT A DIENE SELECTED FROM THE GROUP CONSISTING OF DICYCLOPENTADIENE ETHYLIDENENORBORNENE 1,4-HEXIDIENE, 1-5-HEXADIENE, 2-METHYL-1, 5-HEXADIENE, 1,4CYCLOHEPTADIENE, 1,5-CYCLOOCTADIENE AND MIXTURES THEREOF AND HAVING AN IODINE VALUE OF 4 TO 50, THE AROMATIC VINYL COMPONENT BEING SELECTED FROM THE GROUP CONSISTING OF STYRENE, A-METHYLSTYRENE, A-CHLOROSTYRENE AND DIEMTHYLSTYRENE, AND THE VINYL CYANIDE COMPOUND BEING SELECTED FROM THE GROUP CONSISTING OF ACRYLONITRILE AND METHACRYLONITRILE.
Claim 3
Dependent Claim 39 words
A process according to claim 1, wherein the solution polymerization is effected in the presence of a radical polymerization catalyst in an amount of 0.1 - 10 % by weight based on the total weight of the vinyl monomers.
Claim 4
Dependent Claim 13 words
A process according to claim 1, wherein the catalyst is added in portions.
Claim 5
Dependent Claim 63 words
A process according to claim 1, wherein the polar solvent is at least one member selected from the group consisting of acetone, methyl ethyl ketone, methyl n-propyl ketone, diethyl ketone, 2-hexanone, 3-hexanone, acetophenone, propiophenone, methyl formate, ethyl formate, methyl acetate, ethyl acetate, n-propyl acetate, n-butyl acetate, n-amyl acetate, methyl propionate, methyl n-butyrate, tetrahydrofuran, dioxane, dichloroethane, chloroform, pyridine, aniline, acetonitrile, dimethylformamide and dimethyl sulfoxide.
Claim 6
Dependent Claim 36 words
A process according to claim 1, wherein the catalyst is selected from the group consisting of benzoyl peroxide, lauroyl peroxide, di-t-butyl peroxide, acetyl peroxide, t-butyl peroxybenzoic acid, dicumyl peroxide, peroxybenzoic acid, peroxyacetic acid, tert-butylperoxypivalate and azobisisobutyronitrile.
Claim 7
Dependent Claim 24 words
A process according to claim 1, wherein the weight ratio of the vinyl aromatic compound to the vinyl cyanide compound is 2:1 to 5:1.
Claim 8
Dependent Claim 23 words
A process according to claim 1, wherein styrene and acrylonitrile are graft-copolymerized in a weight ratio of 70:30 to 75:25 on the rubber.
Claim 9
Dependent Claim 47 words
A process according to claim 1, wherein 95 to 80% by weight of the aromatic vinyl or a mixture of the aromatic vinyl and the vinyl cyanide is graft-copolymerized on 5 to 20% by weight of the rubber based upon the weight of combined monomer and rubber.

References Cited (Backward Citations)

US3538191A Cited
US3538190A Cited
US3538193A Cited
US3538192A Cited
US3642950A Cited
US3683050A Cited
US3671608A Cited
US3657395A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1978-09-08 1979-03-10 1979-09-09 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1982-09-08 1983-03-10 1983-09-09 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1986-09-08 1987-03-10 1987-09-09 $7700.00 Window Closed / Lapsed

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