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US3904559A Expired / Lapsed US ⏱️ 0.0 years remaining

Foundry aggregate binders

Assignee: Occidental Chemical Corp
•
Filing: 1973-11-19
•
Granted: 1975-09-09
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Expires: 1993-11-19
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Abstract

Abstract A binder for foundry aggregates comprises a phenolic compound, an organic polyisocyanate, and a substantially non-aqueous, organic solvent soluble resin prepared by reacting (a) a condensation product of a phenol and an aldehyde or ketone containing condensate units having reactive phenolic hydroxyl groups, and (b) a substance reactive with the phenolic hydroxyl groups such as a mono oxirane ring compound, an alkylene halohydrin or an alkylene carbonate. Said phenolic compounds can be represented by the formula: WHEREIN X is oxygen or sulfur, y is an alkylidene radical, an arylene radical, an aryl bis alkylene radical, -S-, -S-S-, or n is 0 or 1, and R1 and R2 are hydrogen, alkyl of 1 to 6 carbon atoms or halogen. The binders are useful in preparing foundry aggregate compositions which can be cured at room temperature. Shaped foundry products such as cores made using organic isocyanate, phenolic compound, resin binders are rendered easy releasing from metallic and thermosetting resin patterns by the incorporation of tall oil, fatty acid ester, or poly(ethylene glycol) esters of fatty acids into the binder composition.

Inventors

  • 👤 Ralph J Furness
  • 👤 Frank W Less

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-06 10:06
CPC Classifications
C; C08; C08G; C08G18/00; C08G18/06; C08G18/28; C08G18/30; C08G18/38; C08G18/3855; C08G18/3863; C08G18/40; C08G18/54; C08G18/546; C08G18/65

Claims Analysis

Total Claims: 30
Claim 1
Independent Claim 24 words
A FOUNDRY AGGREGATE COMPOSITION COMPRISING (1) A FOUNDRY AGGREGATE: (2) AN ORGANIC POLYISOCYANATE: (3) A SUBSTANTIALLY NONAQUEOUS, ORGANIC SOLVENT SOLUBLE COMPONENT HAVING THE FORMULA:
Claim 2
Dependent Claim 24 words
A FOUNDRY AGGREGATE COMPOSITION COMPRISING (1) A FOUNDRY AGGREGATE: (2) AN ORGANIC POLYISOCYANATE: (3) A SUBSTANTIALLY NONAQUEOUS, ORGANIC SOLVENT SOLUBLE COMPONENT HAVING THE FORMULA:
Claim 3
Dependent Claim 18 words
The composition of claim 1 wherein components (2), (3) and (4) are in solution in an inert solvent.
Claim 4
Dependent Claim 31 words
A composition comprising the composition of claim 1 and a compound selected from the group consisting of poly(ethylene glycol) esters of fatty acids, and lower (C1-C8) alcohol esters of fatty acids.
Claim 5
Dependent Claim 36 words
The compositions of claim 2 wherein the solvent solution of components (2), (3) and (4) is present to the extent of about 0.8 to about 10% by weight based on the weight of said foundry aggregate.
Claim 6
Dependent Claim 20 words
A foundry aggregate composition comprising (1) a foundry aggregate, (2) a substantially non-aqueous organic solvent soluble component of the formula:
Claim 7
Dependent Claim 20 words
A foundry aggregate composition comprising (1) a foundry aggregate, (2) a substantially non-aqueous organic solvent soluble component of the formula:
Claim 8
Dependent Claim 32 words
The composition of claim 1 wherein said polyisocyanate is present in a proportion to provide from about 0.9 to 1.1 reactive isocyanato groups per reactive hydrogen present in components (3) and (4).
Claim 9
Dependent Claim 12 words
The composition of claim 1 wherein R1, R2 and R3 are hydrogen.
Claim 10
Dependent Claim 13 words
The composition of claim 1 wherein the organic polyisocyanate is a polyaryl polyisocyanate.
Claim 11
Dependent Claim 14 words
The composition of claim 8 wherein said polyaryl polyisocyanate has a functionality of 2.6.
Claim 12
Dependent Claim 11 words
The composition of claim 7 wherein the solvent comprises ethyl benzene.
Claim 13
Dependent Claim 21 words
A composition which comprises the composition of claim 4 cured with a volatilized tertiary amine containing up to 20 carbon atoms.
Claim 14
Dependent Claim 31 words
The composition of claim 4 comprising (1) an organic polyisocyanate, (2) an inert solvent, and (3) a component selected from the group consisting of lower (C1-C8) alcohol esters of fatty acids.
Claim 15
Dependent Claim 12 words
The composition of claim 5 wherein the phenolic compound is a bisphenol.
Claim 16
Dependent Claim 32 words
The composition of claim 5 wherein said composition additionally comprises a component selected from the group consisting of poly(ethylene glycol) esters of fatty acids, and lower (C1-C8) alcohol esters of fatty acids.
Claim 17
Dependent Claim 16 words
The composition of claim 13 wherein the solvent comprises ethyl benzene and ethylene glycol monoethylether acetate.
Claim 18
Dependent Claim 53 words
The composition of claim 1, and a component selected from the group consisting of lower (C1-C8) alcohol esters Of fatty acids, and poly(ethylene glycol) esters of fatty acids wherein said solution is present in the proportions of about 0.8 to about 10 percent by weight based upon the weight of said foundry aggregate.
Claim 19
Dependent Claim 21 words
A composition which comprises the composition of claim 16 cured with a volatilized tertiary amine containing up to 20 carbon atoms.
Claim 20
Dependent Claim 40 words
A process for bonding discrete inert, solid particles which comprises (1) coating said particles with a solution of a binder in an organic solvent comprising: A. an organic polyisocyanate, B. a substantially non-aqueous organic solvent soluble component having the formula:
Claim 21
Dependent Claim 40 words
A process for bonding discrete inert, solid particles which comprises (1) coating said particles with a solution of a binder in an organic solvent comprising: A. an organic polyisocyanate, B. a substantially non-aqueous organic solvent soluble component having the formula:
Claim 22
Dependent Claim 66 words
The process of claim 18 wherein said solution of a binder binder additionally comprises an easy release component selected from the group consisting of lower (C1-C8) alcohol esters of fatty acids, and poly(ethylene glycol) esters of fatty acids wherein said solution of a binder is present in the proportions of about 0.8 to about 10 percent by weight based on the weight of said foundry aggregate.
Claim 23
Dependent Claim 23 words
The process of claim 19 wherein the composition is cured by passing therethrough a volatilized tertiary amine containing up to 20 carbon atoms.
Claim 24
Dependent Claim 12 words
The process of claim 18 wherein the phenolic compound is a bisphenol.
Claim 25
Dependent Claim 23 words
The process of claim 20 wherein the phenolic compound is para,para''-isopropylidene diphenol and the composition is cured by passing a tertiary amine therethrough.
Claim 26
Dependent Claim 28 words
The process of claim 22 wherein the organic polyisocyanate is a polyaryl polyisocyanate and the solvent is a mixture comprising ethyl benzene and ethylene glycol monoethyl ether acetate.
Claim 27
Dependent Claim 11 words
The process of claim 22 wherein the tertiary amine is triethylamine.
Claim 28
Dependent Claim 14 words
The process of claim 23 wherein said polyaryl polyisocyanate has a functionality of 2.6
Claim 29
Dependent Claim 38 words
A binder composition for foundry aggregates comprising the the composition of claim 1 wherein the proportion of said (3) organic solvent soluble component to said (4) phenolic compound in said binder is from 30 percent to 100 percent.
Claim 30
Dependent Claim 67 words
A binder composition for foundry aggregates comprising the composition of claim 1 wherein the proportion of said (2) organic solvent soluble component to said (3) phenolic compound in said binder is from 30 percent to 100 percent, and wherein said (1) organic polyisocyanate is present in a proportion to provide from about 0.9 to 1.1 reactive isocyanate groups per reactive hydrogen present in components (2) and (3).

References Cited (Backward Citations)

US2284637A Cited
US3409579A Cited
US3538040A Cited
US3428110A Cited
US3706680A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1978-09-08 1979-03-10 1979-09-09 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1982-09-08 1983-03-10 1983-09-09 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1986-09-08 1987-03-10 1987-09-09 $7700.00 Window Closed / Lapsed

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