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US3904418A Expired / Lapsed US ⏱️ 0.0 years remaining

Hardenable vehicles for silver halide emulsions

Assignee: Eastman Kodak Co
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Filing: 1974-08-15
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Granted: 1975-09-09
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Expires: 1994-08-15
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Abstract

Abstract Disclosed herein is a photographic element adapted for silverdye bleach processes comprising a support having coated thereon at least one photographic silver halide emulsion and at least one binding agent comprising an interpolymer comprising A. from about 1 to 50% by weight of a polymerized monomer containing at least one active methylene group and having the formula wherein n is 0 or 1, R is hydrogen or methyl, R1 is substituted or unsubstituted arylenethylene having the structure wherein Ar is arylene, R2 is hydrogen, alkyl, aryl, or cycloalkyl, R3 is alkoxy or amino when n is equal to 0, and R3 is alkyl, alkoxy, amino, cycloalkyl, or aryl when n is equal to 1; and B. from 50 to about 99% by weight of at least one additional polymerized ethylenically unsaturated monomer.

Inventors

  • 👤 Rowland George Mowrey
  • 👤 Ignazio Salvatore Ponticello

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-25 23:07
CPC Classifications
G; G03; G03C; G03C1/00; G03C1/005; G03C1/04; C; C08; C08F; C08F12/00; C08F12/02; C08F12/04; C08F12/14; C08F12/22; C08F16/00; C08F16/36; C08F20/00; C08F20/02; C08F20/10; C08F20/26

Claims Analysis

Total Claims: 38
Claim 1
Independent Claim 50 words
A PHOTOGRAPHIC ELEMENT COMPRISING A SUPPORT HAVING COATED THEREON AT LEAST ONE PHOTOGRAPHIC SILVER HALIDE EMULSION AND AT LEAST ONE BINDING AGENT COMPRISING AN ADDITION INTERPOLYMER COMPRISING A. FROM ABOUT 1 TO 50% BY WEIGHT OF A POLYMERIZED MONOMER CONTAINING AT LEAST ONE ACTIVE METHYLENE GROUP AND HAVING THE FORMULA
Claim 2
Dependent Claim 50 words
A PHOTOGRAPHIC ELEMENT COMPRISING A SUPPORT HAVING COATED THEREON AT LEAST ONE PHOTOGRAPHIC SILVER HALIDE EMULSION AND AT LEAST ONE BINDING AGENT COMPRISING AN ADDITION INTERPOLYMER COMPRISING A. FROM ABOUT 1 TO 50% BY WEIGHT OF A POLYMERIZED MONOMER CONTAINING AT LEAST ONE ACTIVE METHYLENE GROUP AND HAVING THE FORMULA
Claim 3
Dependent Claim 19 words
The element of claim 1 wherein the polymer has an inherent viscosity in the rAnge of 0.1 to 2.0.
Claim 4
Dependent Claim 46 words
The element of claim 1 wherein at least one of the additional polymerized ethylenically unsaturated monomers is selected from the group consisting of acrylamide, N-butyl acrylate, 2-hydroxyethyl methacrylate, N-isopropyl acrylamide, methacrylic acid, vinylimidazole, and N,N-dimethyl-N-2-hydroxypropylamine methacrylimide, sodium 2-acrylamide-2-methylpropane-1-sulfonate, sodium p-styrene sulfonate, 3-methyl-1-vinylimidazolium methosulfate and 1,2-dimethyl-5-vinylpyridinium methosulfate.
Claim 5
Dependent Claim 18 words
The element of claim 3 wherein at least one of the additional polymerized ethylenically unsaturated monomers is acrylamide.
Claim 6
Dependent Claim 12 words
The element of claim 1 wherein the polymerized monomer of the formula
Claim 7
Dependent Claim 50 words
A photographic element comprising a support having coated thereon at least one photographic silver halide emulsion and at least one binding agent comprising an addition interpolymer comprising A. from about 1 to about 50% by weight of a polymerized monomer containing at least one active methylene group having the formula
Claim 8
Dependent Claim 50 words
A photographic element comprising a support having coated thereon at least one photographic silver halide emulsion and at least one binding agent comprising an addition interpolymer comprising A. from about 1 to about 50% by weight of a polymerized monomer containing at least one active methylene group having the formula
Claim 9
Dependent Claim 37 words
A photographic silver halide emulsion containing a binding agent comprising an addition interpolymer comprising A. from about 1 to 50% by weight of a polymerized monomer containing at least one active methylene group and having the formula
Claim 10
Dependent Claim 37 words
A photographic silver halide emulsion containing a binding agent comprising an addition interpolymer comprising A. from about 1 to 50% by weight of a polymerized monomer containing at least one active methylene group and having the formula
Claim 11
Dependent Claim 19 words
The emulsion of claim 7 wherein the interpolymer has an inherent viscosity in the range of 0.10 to 2.0.
Claim 12
Dependent Claim 45 words
The emulsion of claim 7 wherein at least one of the additional polymerized ethylenically unsaturated monomers is selected from the group consisting of acrylamide, N-butyl acrylate, 2-hydroxyethyl methacrylate, N-isopropylacrylamide, methacrylic acid, vinylimidazole, and N,N-dimethyl-N-2-hydroxypropylamine methacrylimide, sodium 2-acrylamide-2-methylpropane-1-sulfonate, sodium p-styrene sulfonate, 3-methyl-1-vinyl-imidazolium methosulfate and 1,2-dimethyl-5-vinylpyridinium methosulfate.
Claim 13
Dependent Claim 18 words
The emulsion of claim 9 wherein at least one of the additional polymerized ethylenically unsaturated monomers is acrylamide.
Claim 14
Dependent Claim 12 words
The emulsion of claim 7 wherein the polymerized monomer of the formula
Claim 15
Dependent Claim 37 words
A photographic silver halide emulsion containing a binding agent comprising an addition interpolymer comprising A. from about 1to about 50% by weight of a polymerized monomer containing at least one active methylene group and having the formula
Claim 16
Dependent Claim 37 words
A photographic silver halide emulsion containing a binding agent comprising an addition interpolymer comprising A. from about 1to about 50% by weight of a polymerized monomer containing at least one active methylene group and having the formula
Claim 17
Dependent Claim 48 words
A photographic element comprising a support having deposited thereon at least one photographic silver halide emulsion containing at binding agent comprising an addition interpolymer comprising A. from about 1 to 50% by weight of a polymerized monomer containing at least one active methylene group and having the formula
Claim 18
Dependent Claim 48 words
A photographic element comprising a support having deposited thereon at least one photographic silver halide emulsion containing at binding agent comprising an addition interpolymer comprising A. from about 1 to 50% by weight of a polymerized monomer containing at least one active methylene group and having the formula
Claim 19
Dependent Claim 19 words
The element of claim 13 wherein the interpolymer has an inherent viscosity in the range of 0.10 to 2.0.
Claim 20
Dependent Claim 44 words
The element of claim 13 wherein at least one of the additional polymerized ethylenically unsaturated monomers is selected from the group consisting of acrylamide, N-butyl acrylate, 2-hydroxyethyl methacrylate, N-isopropylamide, methacrylic acid, vinylimidazole, N,N-dimethyl-N-2-hydroxypropylamine methacrylimide, sodium 2-acrylamido-2-methylpropane-2-sulfonate, sodium p-styrene sulfonate, 3-methyl-1-vinylimidazolium methosulfate and 1,2-dimethyl-5-vinylpyridinium methosulfate.
Claim 21
Dependent Claim 18 words
The element of claim 15 wherein at least one of the additional polymerized ethylenically unsaturated monomers is acrylamide.
Claim 22
Dependent Claim 12 words
The element of claim 13 wherein the polymerized monomer of the formula
Claim 23
Dependent Claim 48 words
A photographic element comprising a support having deposited thereon at least one photographic silver halide emulsion containing a binding agent comprising an addition interpolymer comprising A. from about 1 to about 50% by weight of a polymerized monomer containing at least one active methylene group having the formula
Claim 24
Dependent Claim 48 words
A photographic element comprising a support having deposited thereon at least one photographic silver halide emulsion containing a binding agent comprising an addition interpolymer comprising A. from about 1 to about 50% by weight of a polymerized monomer containing at least one active methylene group having the formula
Claim 25
Dependent Claim 63 words
A photographic element adapted for silver-dye-bleach processes comprising a support having coated thereon at least one photographic silver halide emulsion, aT least one bleachable dye, at least one hardener, and at least one binding agent comprising an addition interpolymer comprising A. from about 1 to 50% by weight of a polymerized monomer containing at least one active methylene group and having the formula
Claim 26
Dependent Claim 63 words
A photographic element adapted for silver-dye-bleach processes comprising a support having coated thereon at least one photographic silver halide emulsion, aT least one bleachable dye, at least one hardener, and at least one binding agent comprising an addition interpolymer comprising A. from about 1 to 50% by weight of a polymerized monomer containing at least one active methylene group and having the formula
Claim 27
Dependent Claim 19 words
The element of claim 19 wherein the interpolymer has an inherent viscosity in the range of 0.10 to 2.0.
Claim 28
Dependent Claim 45 words
The element of claim 19 wherein at least one of the additional polymerized ethylenically unsaturated monomers is selected from the group consisting of acrylamide, N-butyl acrylate, 2-hydroxyethyl methacrylate, N-isopropylacrylamide, methacrylic acid, vinylimidazole, N,N-dimethyl-N-2-hydroxy propylamine methacrylimide, sodium 2-acrylamido-2-methylpropane-2-sulfonate, sodium p-styrene sulfonate, 3-methyl-1-vinylimidazolium methosulfate and 1,2-dimethyl-5-vinylpyridinium methosulfate.
Claim 29
Dependent Claim 12 words
The element of claim 19 wherein the polymerized monomer of the formula
Claim 30
Dependent Claim 21 words
The element of claim 19 wherein the hardener is selected from the group consisting of bis-vinyl sulfone methyl ether and formaldehyde.
Claim 31
Dependent Claim 13 words
The element of claim 19 wherein the bleachable dye is an azo dye.
Claim 32
Dependent Claim 64 words
A photographic element adapted for silver-dye-bleach processes comprising a support having coated thereon at least one photographic silver halide emulsion, at least one azo dye, at least one hardener, and at least one binding agent comprising an addition interpolymer comprising A. from about 1 to about 50% by weight of a polymerized monomer containing at least one active methylene group and having the formula
Claim 33
Dependent Claim 64 words
A photographic element adapted for silver-dye-bleach processes comprising a support having coated thereon at least one photographic silver halide emulsion, at least one azo dye, at least one hardener, and at least one binding agent comprising an addition interpolymer comprising A. from about 1 to about 50% by weight of a polymerized monomer containing at least one active methylene group and having the formula
Claim 34
Dependent Claim 41 words
A photographic silver halide emulsion containing a bleachable dye and a binding agent comprising an addition interpolymer comprising A. from about 1 to 50% by weight of a polymerized monomer containing at least one active methylene group and having the formula
Claim 35
Dependent Claim 41 words
A photographic silver halide emulsion containing a bleachable dye and a binding agent comprising an addition interpolymer comprising A. from about 1 to 50% by weight of a polymerized monomer containing at least one active methylene group and having the formula
Claim 36
Dependent Claim 83 words
In an image-transfer film unit comprising A. a photosensitive element comprising a support having thereon at least one layer containing a silver halide emulsion, B. an image-receiving layer, and C. means containing an alkaline processing composition adapted to discharge its contents within said film unit, the improvement wherein at least one of the alkali permeable layers contains a polymer comprising A. from about 1 to 50% by weight of a polymerized monomer containing at least one activity methylene group and having the formula
Claim 37
Dependent Claim 83 words
In an image-transfer film unit comprising A. a photosensitive element comprising a support having thereon at least one layer containing a silver halide emulsion, B. an image-receiving layer, and C. means containing an alkaline processing composition adapted to discharge its contents within said film unit, the improvement wherein at least one of the alkali permeable layers contains a polymer comprising A. from about 1 to 50% by weight of a polymerized monomer containing at least one activity methylene group and having the formula
Claim 38
Dependent Claim 22 words
An image transfer film unit according to claim 27 wherein said silver halide emulsion has associated therewith an image dye providing material.

References Cited (Backward Citations)

US3459790A Cited
US3488708A Cited
US3554987A Cited
US3700456A Cited
US3775129A Cited
US3713834A Cited
US3861918A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1978-09-08 1979-03-10 1979-09-09 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1982-09-08 1983-03-10 1983-09-09 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1986-09-08 1987-03-10 1987-09-09 $7700.00 Window Closed / Lapsed

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