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US3903046A Expired / Lapsed US ⏱️ 0.0 years remaining

Process for the production of shapeable polymers containing N-silyl groups

Assignee: Novartis Corp
•
Filing: 1973-12-11
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Granted: 1975-09-02
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Expires: 1993-12-11
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Abstract

Abstract The invention relates to a process for the production of shapeable polymers containing N-silyl groups, of the polyamide, polyamide-imide and polyimide type, which polymers can be used for the production of shaped structures such as fibres, films, coatings, adhesives and the like. The polymers obtained by the process of this invention are distinguished by an inherent viscosity of from 0.1 to 4.0 dl/g and by their improved solubility in organic solvents which facilitates the processing of said polymers.

Inventors

  • 👤 Gerd Greber
  • 👤 Urs Gruber
  • 👤 Martin Kuhn
  • 👤 Dieter Lohmann
  • 👤 Sandor Gati

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-28 18:18
CPC Classifications
C; C08; C08G; C08G69/00; C08G69/48; C08G73/00; C08G73/06; C08G73/10; C08G73/1057; C08G73/106

Claims Analysis

Total Claims: 8
Claim 1
Independent Claim 52 words
PROCESS FOR MAKING A POLYAMIDE OR POLYAMIDE-ACID POLYMER WHICH CONTAINS N-SILYL GROUPS, IS SOUBLE IN ORGANIC SOLVENTS, HAS AN INHERENT VISCOSITY AT A CONCENTRATION OF 0.5 PERCENT BY WEIGHT IN N,N-DIMETHYLFORMAMIDE, N,N-DIMETHYLACETAMIDE OR N-METHYL-PYRROLIDONE, MEASURED AT 25*C, OF 0.1 TO 4.0 DL/G, SAID POLYMER HAVING A RECURRING STRUCTURAL UNIT OF FORMULA I
Claim 2
Dependent Claim 52 words
PROCESS FOR MAKING A POLYAMIDE OR POLYAMIDE-ACID POLYMER WHICH CONTAINS N-SILYL GROUPS, IS SOUBLE IN ORGANIC SOLVENTS, HAS AN INHERENT VISCOSITY AT A CONCENTRATION OF 0.5 PERCENT BY WEIGHT IN N,N-DIMETHYLFORMAMIDE, N,N-DIMETHYLACETAMIDE OR N-METHYL-PYRROLIDONE, MEASURED AT 25*C, OF 0.1 TO 4.0 DL/G, SAID POLYMER HAVING A RECURRING STRUCTURAL UNIT OF FORMULA I
Claim 3
Dependent Claim 19 words
Process according to claim 1, characterised in that bis-trimethylsilylacetamide or N-methyl-N-trimethylsilylacetamide is used as silylating agent of formula XV.
Claim 4
Dependent Claim 50 words
Process according to claim 1, characterised in that a polyamide-acid having the recurring structural unit of formula II is used in which R denotes the benzene ring of the benzophenone ring system, n1 and n2 denote the number 2, and E denotes a benzene ring, a 4,4''-diphenylsulphone or 4,4''-diphenylene radical.
Claim 5
Dependent Claim 45 words
Process according to claim 1, characterised in that a polyamide-acid having the recurring structural unit of formula II is used in which R denotes the benzene ring or the benzophenone ring system, n1 and n2 denote the number 2, and E denotes a 4,4''-diphenylyl-ether radical.
Claim 6
Dependent Claim 48 words
Process according to claim 1, characterised in that a polyamide-acid having the recurring structural unit of formula II is used in which R denotes the benzene ring, n1 denotes the number 2, n2 denotes the number 1, and E denotes a benzene ring, a 4,4''-diphenylylsulphone or 4,4''-diphenylylene radical.
Claim 7
Dependent Claim 43 words
Process according to claim 1, characterised in that a polyamide-acid having the recurring structural unit of formula II is used in which R denotes the benzene ring, n1 denotes the number 2, n2 denotes the number 1, and E denotes a 4,4''-diphenylyl-ether radical.
Claim 8
Dependent Claim 39 words
Process according to claim 1, characterised in that a polyamide having the recurring structural unit of formula II is used in which R and E each denote the benzene ring and n1 and n2 each denote the number 1.

References Cited (Backward Citations)

US3303157A Cited
US3440204A Cited
US3392144A Cited
US3663728A Cited
US3553282A Cited
US3673155A Cited
US3598785A Cited
US3779990A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1978-09-01 1979-03-03 1979-09-02 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1982-09-01 1983-03-03 1983-09-02 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1986-09-01 1987-03-03 1987-09-02 $7700.00 Window Closed / Lapsed

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