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US3900679A Expired / Lapsed US ⏱️ 0.0 years remaining

Glass fiber reinforced elastomers

Assignee: Owens Corning
•
Filing: 1973-07-23
•
Granted: 1975-08-19
•
Expires: 1993-07-23
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Abstract

Abstract The improvement in the bonding relationship between glass fibers and elastomeric materials in the manufacture of glass fiberreinforced elastomeric products wherein individual glass fibers are impregnated with a composition containing a terpolymer formed by the interpolymerization of butadiene, styrene and a monomeric material which can be an amino silane containing ethylenic unsaturation or an amide formed by the reaction of an amino silane with polymerizable mono- and dicarboxylic acids.

Inventors

  • 👤 Alfred Marzocchi

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-27 20:43
CPC Classifications
C; C08; C08J; C08J5/00; C08J5/04; C08J5/06; C08J5/08; C03; C03C; C03C25/00; C03C25/10; C03C25/24; C03C25/26; C03C25/27; C03C25/40; C08F; C08F212/00; C08F212/02; C08F212/04; C08F212/06; C08F212/08; C08F230/00; C08F230/04; C08F230/08; C08F230/085; C08F236/00; C08F236/02; C08F236/04; C08F236/06; C08F236/10; C08J2321/00; Y; Y10; Y10S; Y10S57/00; Y10S57/902; Y10T; Y10T428/00; Y10T428/29; Y10T428/2913; Y10T428/2915; Y10T428/2933; Y10T428/2938; Y10T428/294; Y10T428/296; Y10T428/2962; Y10T428/2964; Y10T442/00; Y10T442/20; Y10T442/2926; Y10T442/2992

Claims Analysis

Total Claims: 18
Claim 1
Independent Claim 26 words
GLASS FIBERS HAVING A THIN COATING THEREON, SAID COATING COMPRISING A TERPOLYMER FORMED BY THE INTERPOLYMERIZATION OF BUTADIENE, STYRENE AND AN AMINO SILANE HAVING THE FORMULA
Claim 2
Dependent Claim 26 words
GLASS FIBERS HAVING A THIN COATING THEREON, SAID COATING COMPRISING A TERPOLYMER FORMED BY THE INTERPOLYMERIZATION OF BUTADIENE, STYRENE AND AN AMINO SILANE HAVING THE FORMULA
Claim 3
Dependent Claim 21 words
Glass fibers as defined in claim 1 wherein said amino silane forms between 1 and 10% by weight of said terpolymer.
Claim 4
Dependent Claim 33 words
Glass fibers as defined in claim 1 wherein the coating includes an elastomer compatible material selected from the group consisting of an elastomer and a blend of an elastomer and a resorcinol-aldehyde resin.
Claim 5
Dependent Claim 14 words
Glass fibers as defined in claim 1 wherein the coating includes an anchoring agent.
Claim 6
Dependent Claim 14 words
Glass fibers as defined in claim 1 wherein the amino silane is gamma-aminopropylvinyldimethoxy silane.
Claim 7
Dependent Claim 27 words
A glass fiber bundle having an impregnant therein, said impregnant comprising a terpolymer formed by the interpolymerization of butadiene, styrene and an amino silane having the formula:
Claim 8
Dependent Claim 27 words
A glass fiber bundle having an impregnant therein, said impregnant comprising a terpolymer formed by the interpolymerization of butadiene, styrene and an amino silane having the formula:
Claim 9
Dependent Claim 35 words
A glass fiber bundle as defined in claim 6 wherein said impregnant includes an elastomer compatible material selected from the group consisting of an elastomer and a blend of an elastomer with a resorcinol-aldehyde resin.
Claim 10
Dependent Claim 22 words
A glass fiber bundle as defined in claim 6 wherein said impregnant constitutes between 5-25% by weight of the glass fiber system.
Claim 11
Dependent Claim 23 words
A glass fiber bundle as defined in claim 6 wherein the individual glass fibers comprising the bundle have a thin size coating thereon.
Claim 12
Dependent Claim 16 words
A glass fiber bundle as defined in claim 6 wherein the amino silane is gamma-aminopropylvinyldimethoxy silane.
Claim 13
Dependent Claim 56 words
In a glass fiber reinforced elastomeric product wherein an elastomeric material constitutes a continuous phase in which the glass fibers are distributed, the improvement in the bonding relationship between the glass fibers and the elastomeric material comprising a coating of a terpolymer formed by the interpolymerization of butadiene, styrene and a silicon compound having the formula
Claim 14
Dependent Claim 56 words
In a glass fiber reinforced elastomeric product wherein an elastomeric material constitutes a continuous phase in which the glass fibers are distributed, the improvement in the bonding relationship between the glass fibers and the elastomeric material comprising a coating of a terpolymer formed by the interpolymerization of butadiene, styrene and a silicon compound having the formula
Claim 15
Dependent Claim 28 words
An elastomeric product as defined in claim 11 wherein the glass fibers are in the form of a bundle and the coating constitutes an impregnant in the bundle.
Claim 16
Dependent Claim 24 words
An elastomeric product as defined in claim 12 wherein the glass fibers forming the bundle have a thin size coating on the surfaces thereof.
Claim 17
Dependent Claim 26 words
An elastomeric product as defined in claim 12 wherein the bundle is formed of strands of glass fibers plied and twisted together to form a cord.
Claim 18
Dependent Claim 15 words
An elastomeric product as defined in claim 11 wherein the silicon compound is gamma-aminopropylvinyldimethoxy silane.

References Cited (Backward Citations)

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US3249461A Cited
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USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1978-08-18 1979-02-17 1979-08-19 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1982-08-18 1983-02-17 1983-08-19 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1986-08-18 1987-02-17 1987-08-19 $7700.00 Window Closed / Lapsed

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