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US3900377A Expired / Lapsed US ⏱️ 0.0 years remaining

Reduction of toxicity of aqueous solutions

Assignee: Individual
•
Filing: 1973-01-08
•
Granted: 1975-08-19
•
Expires: 1993-01-08
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Abstract

Abstract The toxicity of waste solutions, particularly cyanide wastes, is reduced using electro-oxidation. A cell structure suitable for accomplishing the result and including an extensive liquid flow path between closely-spaced electrodes is provided.

Inventors

  • 👤 Kurt Enns
  • 👤 John J Byerley
  • 👤 Clare J Beingessner

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-08 22:03
CPC Classifications
C; C25; C25B; C25B11/00; C25B11/02; C25B11/036; C02; C02F; C02F1/00; C02F1/46; C02F1/461; C02F1/46104; C02F1/46109; C02F1/46114; C02F1/467; C02F1/4672; C25B9/00; C25B9/70; C25B9/73; C25B9/75; C02F2001/46128; C02F2001/46133; C02F2001/46152; C02F2001/46157; C02F2101/00; C02F2101/10; C02F2101/16; C02F2101/18; C02F2201/00; C02F2201/46; C02F2201/461; C02F2201/46105; C02F2201/4611; C02F2201/4612; C02F2201/46145

Claims Analysis

Total Claims: 12
Claim 1
Independent Claim 308 words
A METHOD OF DECREASING THE CONCENRATION OF ANODICALYOXIDIZABLE SPECIES SELECTED FROM FREE AND/OR COMPLEXED CYANIDE IONS, CYANATE IONS AND THIOCYANATE IONS IN AN AQUEOUS SOLUTION THEREOF WHICH COMPRISES: PASSING SAID AQUEOUS SOLUTION ALONG A PLURALITY OF FLUIDLYINTERCONNECTED SUCCESSIVE CONFINED PATHS EACH CONSTITUTED BY AT LEAST ONE PAIR OF ELECTRODES HAVING FACES OF OPPOSITE POLARITY SPACED APART A DISTANCE OF ABOUT 1/16 INCH TO 1 INCH, SAID PASSAGE OF SAID AQUEOUS SOLUTION ALONG SAID PLURALITY OF FLUIDLY-INTERCONNECTED SUCCESSIVE CONFINED PATHS PROVIDING A LAYER OF LIQUOR IMMEDIATELY ADJACENT EACH OF SAID ELECTRODE FACES AND A BULK MASS OF LIQUOR BETWEEN SAID LAYERS, APPLYING D.C. POWER BETWEEN SAID ELECTRODES TO PROVIDE A CURRENT DENSITY OF LESS THAN 200 AMPS PER SQ.FT. TO SAID ELECTRODES, WHEREBY AN ELECTROACTIVE ANODE AND AN ELECTROACTIVE CATHODE ARE PROVIDED, MAINTAINING SAID AQUEOUS SOLUTION AT A FLOW RATE ALONG SAID CONFINED PATHS AND OVER SAID ELECTRODES LESS THAN 5FT/SEC, OXIDIZING SAID ANODICALLY-OXIDIZABLE SPECIES AT SAID ELECTROACTIVEANODE TO PRODUCE MATERIALS INCLUDING GASEOUS MATERIAL, INTERMIXING THE LAYER OF LIQUOR IMMEDIATELY ADJACENT SAID ELECTROACTIVE ANODE WITH SAID BULK MASS OF SAID AQUEOUS SOLUTION TO MINIMIZE PH POLARIZATION AND ANODICALLY-OXIDIZABLE SPECIES CONCENTRATION POLARIZATION BETWEEN SAID BULK MASS AND SAID LIQUOR LAYER IMMEDIATELY ADJACENT SAID ELECTROACTIVE ANODE, SCRUBBING BUBBLES OF GASEOUS MATERIAL FROM BOTH SAID ELECTROACTIVE ANODE AND SAID ELECTROACTIVE CATHODE DURING SAID PASSAGE OF SAID AQUEOUS SOLUTION ALONG SAID PLURALITY OF FLUIDLY-INTERCONNECTED SUCCESSIVE CONFINED PATHS TO FORM A MIXTURE OF SAID GASEOUS MATERIAL AND SAID AQUEOUS SOLTUION AND TO MINIMIZE THE ACCUMULATION OF GASEOUS MATERIAL ON SAID ELECTROACTIVE ANODE AND ELECTROACTIVE CATHODE, CONVEYING SAID MIXTURE OF GASEOUS MATERIAL AND AQUEOUS SOLUTION SUCCESSIVELY ALONG SAID CONFINED PATHS, AND RESTRICTING THE PASSAGE OF SAID MIXURE ALONG SAID CONFINED PATHS BELOW A TOTAL PATH LENGTH ABOVE WHICH THE PROPORTION OF GAS IN THE MIXTURE AT THE EXTREMITY OF SAID PATHS EXCEEDS ABOUT 20 PERCENT.
Claim 2
Independent Claim 308 words
A METHOD OF DECREASING THE CONCENRATION OF ANODICALYOXIDIZABLE SPECIES SELECTED FROM FREE AND/OR COMPLEXED CYANIDE IONS, CYANATE IONS AND THIOCYANATE IONS IN AN AQUEOUS SOLUTION THEREOF WHICH COMPRISES: PASSING SAID AQUEOUS SOLUTION ALONG A PLURALITY OF FLUIDLYINTERCONNECTED SUCCESSIVE CONFINED PATHS EACH CONSTITUTED BY AT LEAST ONE PAIR OF ELECTRODES HAVING FACES OF OPPOSITE POLARITY SPACED APART A DISTANCE OF ABOUT 1/16 INCH TO 1 INCH, SAID PASSAGE OF SAID AQUEOUS SOLUTION ALONG SAID PLURALITY OF FLUIDLY-INTERCONNECTED SUCCESSIVE CONFINED PATHS PROVIDING A LAYER OF LIQUOR IMMEDIATELY ADJACENT EACH OF SAID ELECTRODE FACES AND A BULK MASS OF LIQUOR BETWEEN SAID LAYERS, APPLYING D.C. POWER BETWEEN SAID ELECTRODES TO PROVIDE A CURRENT DENSITY OF LESS THAN 200 AMPS PER SQ.FT. TO SAID ELECTRODES, WHEREBY AN ELECTROACTIVE ANODE AND AN ELECTROACTIVE CATHODE ARE PROVIDED, MAINTAINING SAID AQUEOUS SOLUTION AT A FLOW RATE ALONG SAID CONFINED PATHS AND OVER SAID ELECTRODES LESS THAN 5FT/SEC, OXIDIZING SAID ANODICALLY-OXIDIZABLE SPECIES AT SAID ELECTROACTIVEANODE TO PRODUCE MATERIALS INCLUDING GASEOUS MATERIAL, INTERMIXING THE LAYER OF LIQUOR IMMEDIATELY ADJACENT SAID ELECTROACTIVE ANODE WITH SAID BULK MASS OF SAID AQUEOUS SOLUTION TO MINIMIZE PH POLARIZATION AND ANODICALLY-OXIDIZABLE SPECIES CONCENTRATION POLARIZATION BETWEEN SAID BULK MASS AND SAID LIQUOR LAYER IMMEDIATELY ADJACENT SAID ELECTROACTIVE ANODE, SCRUBBING BUBBLES OF GASEOUS MATERIAL FROM BOTH SAID ELECTROACTIVE ANODE AND SAID ELECTROACTIVE CATHODE DURING SAID PASSAGE OF SAID AQUEOUS SOLUTION ALONG SAID PLURALITY OF FLUIDLY-INTERCONNECTED SUCCESSIVE CONFINED PATHS TO FORM A MIXTURE OF SAID GASEOUS MATERIAL AND SAID AQUEOUS SOLTUION AND TO MINIMIZE THE ACCUMULATION OF GASEOUS MATERIAL ON SAID ELECTROACTIVE ANODE AND ELECTROACTIVE CATHODE, CONVEYING SAID MIXTURE OF GASEOUS MATERIAL AND AQUEOUS SOLUTION SUCCESSIVELY ALONG SAID CONFINED PATHS, AND RESTRICTING THE PASSAGE OF SAID MIXURE ALONG SAID CONFINED PATHS BELOW A TOTAL PATH LENGTH ABOVE WHICH THE PROPORTION OF GAS IN THE MIXTURE AT THE EXTREMITY OF SAID PATHS EXCEEDS ABOUT 20 PERCENT.
Claim 3
Dependent Claim 15 words
The method of claim 1 wherein said current density is from 15 to 40 amps/sq.ft.
Claim 4
Dependent Claim 14 words
The method of claim 1 wherein said flow rate is less than 1.5 ft/sec.
Claim 5
Dependent Claim 46 words
The method of claim 1 wherein said electrodes are graphite and are spaced apart a distanCe of about 1/8 to 3/8 inch, said flow rate is from 0.8 to 1.5 ft/sec. and said current density varies interdependently with said flow rate from 15 to 40 amps/sq.ft.
Claim 6
Dependent Claim 32 words
The method of claim 1 wherein said total path length is below that above which the proportion of gas in the mixture at the extremity of said paths exceeds about 10 percent.
Claim 7
Dependent Claim 32 words
The method of claim 4 wherein said total path length is below that above which the proportion of gas in the mixture at the extremity of said paths exceeds about 10 percent.
Claim 8
Dependent Claim 19 words
The method of claim 1 wherein said aqueous solution of anodically-oxidizable species is an aqueous solution containing sodium cyanide.
Claim 9
Dependent Claim 17 words
The method of claim 7 wherein said aqueous solution is formed in the heat treating of steel.
Claim 10
Dependent Claim 18 words
The method of claim 7 wherein said aqueous solution is formed in the aerated bath nitriding of steel.
Claim 11
Dependent Claim 20 words
The method of claim 7 wherein said aqueous solution contains up to 12,000 ppm of free and/or complexed cyanide ions.
Claim 12
Dependent Claim 21 words
The method of claim 7 wherein said aqueous solution is metal cyanide waste from a hydrometallurgical or a metals finishing operation.

References Cited (Backward Citations)

US478048A Cited
US2520703A Cited
US744171A Cited
US831434A Cited
US1894271A Cited
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US2737298A Cited
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US3756932A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1978-08-18 1979-02-17 1979-08-19 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1982-08-18 1983-02-17 1983-08-19 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1986-08-18 1987-02-17 1987-08-19 $7700.00 Window Closed / Lapsed

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