US3900377A
Expired / Lapsed
US
⏱️ 0.0 years remaining
Reduction of toxicity of aqueous solutions
Assignee: Individual
•
Filing: 1973-01-08
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Granted: 1975-08-19
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Expires: 1993-01-08
Abstract
Abstract The toxicity of waste solutions, particularly cyanide wastes, is reduced using electro-oxidation. A cell structure suitable for accomplishing the result and including an extensive liquid flow path between closely-spaced electrodes is provided.
Inventors
- 👤 Kurt Enns
- 👤 John J Byerley
- 👤 Clare J Beingessner
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-11-08 22:03
CPC Classifications
C; C25; C25B; C25B11/00; C25B11/02; C25B11/036; C02; C02F; C02F1/00; C02F1/46; C02F1/461; C02F1/46104; C02F1/46109; C02F1/46114; C02F1/467; C02F1/4672; C25B9/00; C25B9/70; C25B9/73; C25B9/75; C02F2001/46128; C02F2001/46133; C02F2001/46152; C02F2001/46157; C02F2101/00; C02F2101/10; C02F2101/16; C02F2101/18; C02F2201/00; C02F2201/46; C02F2201/461; C02F2201/46105; C02F2201/4611; C02F2201/4612; C02F2201/46145
Claims Analysis
Total Claims: 12
Claim 1
Independent Claim
308 words
A METHOD OF DECREASING THE CONCENRATION OF ANODICALYOXIDIZABLE SPECIES SELECTED FROM FREE AND/OR COMPLEXED CYANIDE IONS, CYANATE IONS AND THIOCYANATE IONS IN AN AQUEOUS SOLUTION THEREOF WHICH COMPRISES: PASSING SAID AQUEOUS SOLUTION ALONG A PLURALITY OF FLUIDLYINTERCONNECTED SUCCESSIVE CONFINED PATHS EACH CONSTITUTED BY AT LEAST ONE PAIR OF ELECTRODES HAVING FACES OF OPPOSITE POLARITY SPACED APART A DISTANCE OF ABOUT 1/16 INCH TO 1 INCH, SAID PASSAGE OF SAID AQUEOUS SOLUTION ALONG SAID PLURALITY OF FLUIDLY-INTERCONNECTED SUCCESSIVE CONFINED PATHS PROVIDING A LAYER OF LIQUOR IMMEDIATELY ADJACENT EACH OF SAID ELECTRODE FACES AND A BULK MASS OF LIQUOR BETWEEN SAID LAYERS, APPLYING D.C. POWER BETWEEN SAID ELECTRODES TO PROVIDE A CURRENT DENSITY OF LESS THAN 200 AMPS PER SQ.FT. TO SAID ELECTRODES, WHEREBY AN ELECTROACTIVE ANODE AND AN ELECTROACTIVE CATHODE ARE PROVIDED, MAINTAINING SAID AQUEOUS SOLUTION AT A FLOW RATE ALONG SAID CONFINED PATHS AND OVER SAID ELECTRODES LESS THAN 5FT/SEC, OXIDIZING SAID ANODICALLY-OXIDIZABLE SPECIES AT SAID ELECTROACTIVEANODE TO PRODUCE MATERIALS INCLUDING GASEOUS MATERIAL, INTERMIXING THE LAYER OF LIQUOR IMMEDIATELY ADJACENT SAID ELECTROACTIVE ANODE WITH SAID BULK MASS OF SAID AQUEOUS SOLUTION TO MINIMIZE PH POLARIZATION AND ANODICALLY-OXIDIZABLE SPECIES CONCENTRATION POLARIZATION BETWEEN SAID BULK MASS AND SAID LIQUOR LAYER IMMEDIATELY ADJACENT SAID ELECTROACTIVE ANODE, SCRUBBING BUBBLES OF GASEOUS MATERIAL FROM BOTH SAID ELECTROACTIVE ANODE AND SAID ELECTROACTIVE CATHODE DURING SAID PASSAGE OF SAID AQUEOUS SOLUTION ALONG SAID PLURALITY OF FLUIDLY-INTERCONNECTED SUCCESSIVE CONFINED PATHS TO FORM A MIXTURE OF SAID GASEOUS MATERIAL AND SAID AQUEOUS SOLTUION AND TO MINIMIZE THE ACCUMULATION OF GASEOUS MATERIAL ON SAID ELECTROACTIVE ANODE AND ELECTROACTIVE CATHODE, CONVEYING SAID MIXTURE OF GASEOUS MATERIAL AND AQUEOUS SOLUTION SUCCESSIVELY ALONG SAID CONFINED PATHS, AND RESTRICTING THE PASSAGE OF SAID MIXURE ALONG SAID CONFINED PATHS BELOW A TOTAL PATH LENGTH ABOVE WHICH THE PROPORTION OF GAS IN THE MIXTURE AT THE EXTREMITY OF SAID PATHS EXCEEDS ABOUT 20 PERCENT.
Claim 2
Independent Claim
308 words
A METHOD OF DECREASING THE CONCENRATION OF ANODICALYOXIDIZABLE SPECIES SELECTED FROM FREE AND/OR COMPLEXED CYANIDE IONS, CYANATE IONS AND THIOCYANATE IONS IN AN AQUEOUS SOLUTION THEREOF WHICH COMPRISES: PASSING SAID AQUEOUS SOLUTION ALONG A PLURALITY OF FLUIDLYINTERCONNECTED SUCCESSIVE CONFINED PATHS EACH CONSTITUTED BY AT LEAST ONE PAIR OF ELECTRODES HAVING FACES OF OPPOSITE POLARITY SPACED APART A DISTANCE OF ABOUT 1/16 INCH TO 1 INCH, SAID PASSAGE OF SAID AQUEOUS SOLUTION ALONG SAID PLURALITY OF FLUIDLY-INTERCONNECTED SUCCESSIVE CONFINED PATHS PROVIDING A LAYER OF LIQUOR IMMEDIATELY ADJACENT EACH OF SAID ELECTRODE FACES AND A BULK MASS OF LIQUOR BETWEEN SAID LAYERS, APPLYING D.C. POWER BETWEEN SAID ELECTRODES TO PROVIDE A CURRENT DENSITY OF LESS THAN 200 AMPS PER SQ.FT. TO SAID ELECTRODES, WHEREBY AN ELECTROACTIVE ANODE AND AN ELECTROACTIVE CATHODE ARE PROVIDED, MAINTAINING SAID AQUEOUS SOLUTION AT A FLOW RATE ALONG SAID CONFINED PATHS AND OVER SAID ELECTRODES LESS THAN 5FT/SEC, OXIDIZING SAID ANODICALLY-OXIDIZABLE SPECIES AT SAID ELECTROACTIVEANODE TO PRODUCE MATERIALS INCLUDING GASEOUS MATERIAL, INTERMIXING THE LAYER OF LIQUOR IMMEDIATELY ADJACENT SAID ELECTROACTIVE ANODE WITH SAID BULK MASS OF SAID AQUEOUS SOLUTION TO MINIMIZE PH POLARIZATION AND ANODICALLY-OXIDIZABLE SPECIES CONCENTRATION POLARIZATION BETWEEN SAID BULK MASS AND SAID LIQUOR LAYER IMMEDIATELY ADJACENT SAID ELECTROACTIVE ANODE, SCRUBBING BUBBLES OF GASEOUS MATERIAL FROM BOTH SAID ELECTROACTIVE ANODE AND SAID ELECTROACTIVE CATHODE DURING SAID PASSAGE OF SAID AQUEOUS SOLUTION ALONG SAID PLURALITY OF FLUIDLY-INTERCONNECTED SUCCESSIVE CONFINED PATHS TO FORM A MIXTURE OF SAID GASEOUS MATERIAL AND SAID AQUEOUS SOLTUION AND TO MINIMIZE THE ACCUMULATION OF GASEOUS MATERIAL ON SAID ELECTROACTIVE ANODE AND ELECTROACTIVE CATHODE, CONVEYING SAID MIXTURE OF GASEOUS MATERIAL AND AQUEOUS SOLUTION SUCCESSIVELY ALONG SAID CONFINED PATHS, AND RESTRICTING THE PASSAGE OF SAID MIXURE ALONG SAID CONFINED PATHS BELOW A TOTAL PATH LENGTH ABOVE WHICH THE PROPORTION OF GAS IN THE MIXTURE AT THE EXTREMITY OF SAID PATHS EXCEEDS ABOUT 20 PERCENT.
Claim 3
Dependent Claim
15 words
The method of claim 1 wherein said current density is from 15 to 40 amps/sq.ft.
Claim 4
Dependent Claim
14 words
The method of claim 1 wherein said flow rate is less than 1.5 ft/sec.
Claim 5
Dependent Claim
46 words
The method of claim 1 wherein said electrodes are graphite and are spaced apart a distanCe of about 1/8 to 3/8 inch, said flow rate is from 0.8 to 1.5 ft/sec. and said current density varies interdependently with said flow rate from 15 to 40 amps/sq.ft.
Claim 6
Dependent Claim
32 words
The method of claim 1 wherein said total path length is below that above which the proportion of gas in the mixture at the extremity of said paths exceeds about 10 percent.
Claim 7
Dependent Claim
32 words
The method of claim 4 wherein said total path length is below that above which the proportion of gas in the mixture at the extremity of said paths exceeds about 10 percent.
Claim 8
Dependent Claim
19 words
The method of claim 1 wherein said aqueous solution of anodically-oxidizable species is an aqueous solution containing sodium cyanide.
Claim 9
Dependent Claim
17 words
The method of claim 7 wherein said aqueous solution is formed in the heat treating of steel.
Claim 10
Dependent Claim
18 words
The method of claim 7 wherein said aqueous solution is formed in the aerated bath nitriding of steel.
Claim 11
Dependent Claim
20 words
The method of claim 7 wherein said aqueous solution contains up to 12,000 ppm of free and/or complexed cyanide ions.
Claim 12
Dependent Claim
21 words
The method of claim 7 wherein said aqueous solution is metal cyanide waste from a hydrometallurgical or a metals finishing operation.
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USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1978-08-18 | 1979-02-17 | 1979-08-19 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1982-08-18 | 1983-02-17 | 1983-08-19 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1986-08-18 | 1987-02-17 | 1987-08-19 | $7700.00 | Window Closed / Lapsed |