← Back to Patent Explorer
US3900375A Expired / Lapsed US ⏱️ 0.0 years remaining

Electrolytic separation of metals

Assignee: Texas Instruments Inc
•
Filing: 1973-12-13
•
Granted: 1975-08-19
•
Expires: 1993-12-13
📄 Original PDF 🌐 Google Patents 🔄 Sync Now

Abstract

Abstract A process for separating a first metal from a composite metal body in which said first metal is adhered as an external layer over a substrate constituted by a second metal. The body is immersed in an electrolytic solution in which the two metals are subject to differential anodic dissolution at a predetermined anode voltage measured by reference to a standard electrode, with the degree of dissolution of the second metal in the half-cell comprising the second metal and the solution being substantially less than the degree of dissolution of the first metal in the half-cell comprising the first metal and the solution at that voltage. Direct current is supplied to the body from the positive terminal of a direct current power source whose negative terminal is connected to a cathode also immersed in the solution. The voltage of the anode is controlled relative to the standard electrode at a level which maintains the aforesaid differential dissolution and thereby causes selective removal of the first metal from the body.

Inventors

  • 👤 Robert Baboian

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-28 17:26
CPC Classifications
C; C25; C25F; C25F5/00

Claims Analysis

Total Claims: 11
Claim 1
Independent Claim 246 words
A PROCESS FOR SEPARATING A FIRST METAL SELECTED FROM THE GROUP CONSISTING OF GOLD, SILVER AND ALLOYS OF GOLD AND SILVER FROM A COMPOSITE METAL BODY IN WHICH SAID FIRST METAL IS ADHERED AS AN EXTERNAL LAYER OVER A SUBSTRATE CONSITUTED BY A SECOND METAL, THE PROCESS COMPRISING THE STEPS OF: IMMERSING THE BODY IN AN ELECTROLYTIC SOLUTION OF AN ALKALI METAL CYANIDE IN WHICH THE TWO METALS ARE SUBJECT TO DIFFERENTIAL ANODIC DISSOLUTION AT A PREEDETERMIND ANODE VOLTAGE MEASURED BY REFERENCE TO A STANDARD ELECTRODE WITH THE DEGREE OF DISSOLUTION OF THE SECOND METAL IN THE HALF-CELL COMPRISING SAID SECOND METAL AND SAID SOLUTION BEING SUBSTANTIALLY LESS THAN THE DEGREE OF DISSOLUTION OF THE FIRST METAL IN THE HALF-CELL COMPRISING SAID FIRST METAL AND SAID SOLUTION AT SAID VOLTAGE, SUPPLYING DIRECT CURRENT TO SAID BODY FROM THE POSITIVE TERMINAL OF A DIRECT CURRENT POWER SOURCE WHOSE NEGATIVE TERMINAL IS CONNECTED TO A SECOND ELECTRODE IMMERSED IN SAID SOLUTION THEREBY ESTABLISHING AN ELECTROLYTIC CIRUCIT IN WHICH SAID BODY IS THE ANODE AND SAID SECOND ELECTRODE IS THE CATHODE, AND CONTINUOUSLY CONTROLLING THE VOLTAGE OF SAID ANODE RELATIVE TO SAID STANDARD ELECTRODE AT A LEVEL AT WHICH THE DEGREE OF DISSOLUTION OF THE SECOND METAL IN THE HALF-CELL COMPRISING SAID SECOND METAL AND SOLUTION IS SUBSTANTIALLY LESS THAN THE DEGREE OF DISSOLUTION OF THE FIRST METAL IN THE HALF-CELL COMPRISING SAID FIRST METAL AND THE SOLUTION THEREBY CAUSING SELECTIVE REMOVAL OF SAID FIRST METAL FROM SAID BODY.
Claim 2
Dependent Claim 246 words
A PROCESS FOR SEPARATING A FIRST METAL SELECTED FROM THE GROUP CONSISTING OF GOLD, SILVER AND ALLOYS OF GOLD AND SILVER FROM A COMPOSITE METAL BODY IN WHICH SAID FIRST METAL IS ADHERED AS AN EXTERNAL LAYER OVER A SUBSTRATE CONSITUTED BY A SECOND METAL, THE PROCESS COMPRISING THE STEPS OF: IMMERSING THE BODY IN AN ELECTROLYTIC SOLUTION OF AN ALKALI METAL CYANIDE IN WHICH THE TWO METALS ARE SUBJECT TO DIFFERENTIAL ANODIC DISSOLUTION AT A PREEDETERMIND ANODE VOLTAGE MEASURED BY REFERENCE TO A STANDARD ELECTRODE WITH THE DEGREE OF DISSOLUTION OF THE SECOND METAL IN THE HALF-CELL COMPRISING SAID SECOND METAL AND SAID SOLUTION BEING SUBSTANTIALLY LESS THAN THE DEGREE OF DISSOLUTION OF THE FIRST METAL IN THE HALF-CELL COMPRISING SAID FIRST METAL AND SAID SOLUTION AT SAID VOLTAGE, SUPPLYING DIRECT CURRENT TO SAID BODY FROM THE POSITIVE TERMINAL OF A DIRECT CURRENT POWER SOURCE WHOSE NEGATIVE TERMINAL IS CONNECTED TO A SECOND ELECTRODE IMMERSED IN SAID SOLUTION THEREBY ESTABLISHING AN ELECTROLYTIC CIRUCIT IN WHICH SAID BODY IS THE ANODE AND SAID SECOND ELECTRODE IS THE CATHODE, AND CONTINUOUSLY CONTROLLING THE VOLTAGE OF SAID ANODE RELATIVE TO SAID STANDARD ELECTRODE AT A LEVEL AT WHICH THE DEGREE OF DISSOLUTION OF THE SECOND METAL IN THE HALF-CELL COMPRISING SAID SECOND METAL AND SOLUTION IS SUBSTANTIALLY LESS THAN THE DEGREE OF DISSOLUTION OF THE FIRST METAL IN THE HALF-CELL COMPRISING SAID FIRST METAL AND THE SOLUTION THEREBY CAUSING SELECTIVE REMOVAL OF SAID FIRST METAL FROM SAID BODY.
Claim 3
Dependent Claim 41 words
A process as set fourth in claim 1 wherein the voltage of said anode is controlled by controlling the voltage output of said direct current power source in response to the difference in voltage between said anode and said standard electrode.
Claim 4
Dependent Claim 14 words
A process as set forth in claim 1 wherein said second metal is palladium.
Claim 5
Dependent Claim 26 words
A process as set forth in claim 3 wherein said electrolytic solution contains between about 1 and about 10% by weight of an alkali metal cyanide.
Claim 6
Dependent Claim 21 words
A process as set forth in claim 4 wherein said solution contains on the order of 5% by weight sodium cyanide.
Claim 7
Dependent Claim 30 words
A process as set forth in claim 4 wherein the anode potential is maintained at a level between about -0.4 and about +0.1 volts relative to a saturated calomel electrode.
Claim 8
Dependent Claim 17 words
A process as set forth in claim 3 wherein said first metal is deposited at said cathode.
Claim 9
Dependent Claim 193 words
A process for separating a first metal selected from the group consisting of silver and gold and alloys of silver and gold from a composite metal body in which said first metal is adhered as an external layer over a palladium substrate, the process comprising the steps of: immersing the body in a solution containing between about 1 and about 10% by weight alkali metal cyanide; supplying direct current to said body from the positive terminal of a direct current power source whose negative terminal is connected to a second electrode immersed in said solution, thereby establishing an electrolytic circuit in which said body is the anode and said second electrode is the cathode; continuously agitating said solution; and continuously controlling the voltage of said anode relative to a standard electrode at a level at which the degree of dissolution of the palladium in the half-cell comprising palladium and said solution is substantially less thaN the degree of dissolution of the first metal in the half-cell comprising said first metal and said solution thereby causing selective removal of said first metal from said body and deposition of said first metal onto said cathode.
Claim 10
Dependent Claim 193 words
A process for separating a first metal selected from the group consisting of silver and gold and alloys of silver and gold from a composite metal body in which said first metal is adhered as an external layer over a palladium substrate, the process comprising the steps of: immersing the body in a solution containing between about 1 and about 10% by weight alkali metal cyanide; supplying direct current to said body from the positive terminal of a direct current power source whose negative terminal is connected to a second electrode immersed in said solution, thereby establishing an electrolytic circuit in which said body is the anode and said second electrode is the cathode; continuously agitating said solution; and continuously controlling the voltage of said anode relative to a standard electrode at a level at which the degree of dissolution of the palladium in the half-cell comprising palladium and said solution is substantially less thaN the degree of dissolution of the first metal in the half-cell comprising said first metal and said solution thereby causing selective removal of said first metal from said body and deposition of said first metal onto said cathode.
Claim 11
Dependent Claim 32 words
A process as set forth in claim 8 wherein the voltage of said anode is maintained at a level between about -0.4 and about +0.1 volts relative to a saturated calomel electrode.

References Cited (Backward Citations)

US3826724A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1978-08-18 1979-02-17 1979-08-19 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1982-08-18 1983-02-17 1983-08-19 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1986-08-18 1987-02-17 1987-08-19 $7700.00 Window Closed / Lapsed

Assigned Categories & Tags

No categories assigned to this patent yet.

Assign Category Tag