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US3899445A Expired / Lapsed US ⏱️ 0.0 years remaining

Catalyst for oxidation of ethylene to ethylene oxide

Assignee: Toray Industries Inc
•
Filing: 1973-01-08
•
Granted: 1975-08-12
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Expires: 1993-01-08
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Abstract

Abstract A silver catalyst composition containing, as a moderator, at least one metal selected from the group consisting of praseodymium, neodymium, terbium and dysprosium gives high selectivity in the oxidation of ethylene by molecular oxygen to ethylene oxide.

Inventors

  • 👤 Tsunesuke Kajimoto
  • 👤 Shigeru Wakamatsu

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-28 18:22
CPC Classifications
C; C07; C07D; C07D301/00; C07D301/02; C07D301/03; C07D301/04; C07D301/08; C07D301/10; B; B01; B01J; B01J23/00; B01J23/38; B01J23/54; B01J23/66

Claims Analysis

Total Claims: 18
Claim 1
Independent Claim 187 words
A CATALYST COMPOSITION FOR THE OXIDATION OF ETHYLENE TO ETHYLENE OXIDE WHICH COMPRISES SILVER CATALYST AND, AS A MODERATOR, AT LEAST ONE RARE EARTH METAL SELECTED FROM THE GROUP CONSISTING OF PRASEODYMIUM, NEODYMIUM, TERBIUM AND DYSPROSIUM WHICH IS PREPARED BY COATING A CARRIER WITH A SLURRIED SOLUTION WHICH CONTAINS REDUCED SILVER IN THE FORM OF SILVER POWDER AND A SALT OF AT LEAST ONE RARE EARTH METAL SELECTED FROM THE GROUP CONSISTING OF PRASODYMIUM, NEODYMIUM, TERBIUM AND DYSPROSIUM AND DRYING THE COATED CARRIER, WHEREIN SAID REDUCED SILVER IS PREPARED AS SILVER POWDER BY THE CHEMICAL REACTION OF SILVER OXIDE IN AN AQUEOUS SOLUTION, AND WHEREIN THE REDUCED SILVER AND THE SALT OF THE RARE EARTH METAL ARE PREVIOUSLY COMBINED BY IMMERSING THE REDUCED SILVER INTO AN AQUEOUS SOLUTION OF A SOLUBLE SALT OF SAID RARE EARTHMETAL, ADDING THERETO AN AQUEOUS SOLUTION OF ALKAL OR ALKALINE EARTH HYDROXIDE THEREBY CONVERTING SAID SOLUBLE SALT OF SAID RARE EARTH METAL INTO THE INSOLUBLE HYDROXIDE AND PRECIPITATING SAID INSOLUBLE HYDROXIDE ON THE REDUCED SILVER, FILTERING OFF THE COMBINED REDUCED SILVER AND PRECIPITATED RARE EARTH METAL HYDROXIDE, AND WASHIING THEM WITH WATER.
Claim 2
Dependent Claim 187 words
A CATALYST COMPOSITION FOR THE OXIDATION OF ETHYLENE TO ETHYLENE OXIDE WHICH COMPRISES SILVER CATALYST AND, AS A MODERATOR, AT LEAST ONE RARE EARTH METAL SELECTED FROM THE GROUP CONSISTING OF PRASEODYMIUM, NEODYMIUM, TERBIUM AND DYSPROSIUM WHICH IS PREPARED BY COATING A CARRIER WITH A SLURRIED SOLUTION WHICH CONTAINS REDUCED SILVER IN THE FORM OF SILVER POWDER AND A SALT OF AT LEAST ONE RARE EARTH METAL SELECTED FROM THE GROUP CONSISTING OF PRASODYMIUM, NEODYMIUM, TERBIUM AND DYSPROSIUM AND DRYING THE COATED CARRIER, WHEREIN SAID REDUCED SILVER IS PREPARED AS SILVER POWDER BY THE CHEMICAL REACTION OF SILVER OXIDE IN AN AQUEOUS SOLUTION, AND WHEREIN THE REDUCED SILVER AND THE SALT OF THE RARE EARTH METAL ARE PREVIOUSLY COMBINED BY IMMERSING THE REDUCED SILVER INTO AN AQUEOUS SOLUTION OF A SOLUBLE SALT OF SAID RARE EARTHMETAL, ADDING THERETO AN AQUEOUS SOLUTION OF ALKAL OR ALKALINE EARTH HYDROXIDE THEREBY CONVERTING SAID SOLUBLE SALT OF SAID RARE EARTH METAL INTO THE INSOLUBLE HYDROXIDE AND PRECIPITATING SAID INSOLUBLE HYDROXIDE ON THE REDUCED SILVER, FILTERING OFF THE COMBINED REDUCED SILVER AND PRECIPITATED RARE EARTH METAL HYDROXIDE, AND WASHIING THEM WITH WATER.
Claim 3
Dependent Claim 28 words
A catalyst composition as claimed in claim 1 wherein the amount of the moderator is from 0.001 to about 5.0 atomic % on the basis of silver atoms.
Claim 4
Dependent Claim 27 words
A catalyst composition as claimed in claim 1 wherein the amount of the moderator is from 0.01 to 1.0 atomic % on the basis of silver atoms.
Claim 5
Dependent Claim 25 words
A catalyst composition as claimed in claim 1, wherein the reduced silver is prepared by the reduction of silver oxide with formalin in alkaline solution.
Claim 6
Dependent Claim 19 words
A catalyst composition as claimed in claim 1, wherein the soluble salt of the rare earth metal is chloride.
Claim 7
Dependent Claim 19 words
A catalyst composition as claimed in claim 1, wherein the soluble salt of the rare earth metal is nitrate.
Claim 8
Dependent Claim 19 words
A catalyst composition, as claimed in claim 1, wherein the soluble salt of the rare earth metal is lactate.
Claim 9
Dependent Claim 16 words
A catalyst composition, as claimed in claim 1, wherein the alkali metal hydroxide is sodium hydroxide.
Claim 10
Dependent Claim 16 words
A catalyst composition, as claimed in claim 1, wherein the alkali metal hydroxide is lithium hydroxide.
Claim 11
Dependent Claim 16 words
A catalyst composition, as claimed in claim 1, wherein the alkali metal hydroxide is potassium hydroxide.
Claim 12
Dependent Claim 17 words
A catalyst composition, as claimed in claim 1, wherein the alkaline earth metal hydroxide is barium hydroxide.
Claim 13
Dependent Claim 22 words
A catalyst composition, as claimed in claim 1, wherein the slurried solution further contains a salt of alkali or alkaline earth metal.
Claim 14
Dependent Claim 18 words
A catalyst composition, as claimed in claim 12, wherein the salt of alkaline earth metal is barium nitrate.
Claim 15
Dependent Claim 18 words
A catalyst composition, as claimed in claim 12, wherein the salt of alkaline earth metal is barium lactate.
Claim 16
Dependent Claim 18 words
A catalyst composition, as claimed in claim 12, wherein the salt of alkaline earth metal is calcium nitrate.
Claim 17
Dependent Claim 18 words
A catalyst composition, as claimed in claim 12, wherein the salt of alkaline earth metal is calcium lactate.
Claim 18
Dependent Claim 14 words
A catalyst composition, as claimed in claim 1, wherein the slurried solution is aqueous.

References Cited (Backward Citations)

US2615899A Cited
US2615900A Cited
US3144416A Cited
US3205280A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1978-08-11 1979-02-10 1979-08-12 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1982-08-11 1983-02-10 1983-08-12 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1986-08-11 1987-02-10 1987-08-12 $7700.00 Window Closed / Lapsed

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