US3899445A
Expired / Lapsed
US
⏱️ 0.0 years remaining
Catalyst for oxidation of ethylene to ethylene oxide
Assignee: Toray Industries Inc
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Filing: 1973-01-08
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Granted: 1975-08-12
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Expires: 1993-01-08
Abstract
Abstract A silver catalyst composition containing, as a moderator, at least one metal selected from the group consisting of praseodymium, neodymium, terbium and dysprosium gives high selectivity in the oxidation of ethylene by molecular oxygen to ethylene oxide.
Inventors
- 👤 Tsunesuke Kajimoto
- 👤 Shigeru Wakamatsu
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-10-28 18:22
CPC Classifications
C; C07; C07D; C07D301/00; C07D301/02; C07D301/03; C07D301/04; C07D301/08; C07D301/10; B; B01; B01J; B01J23/00; B01J23/38; B01J23/54; B01J23/66
Claims Analysis
Total Claims: 18
Claim 1
Independent Claim
187 words
A CATALYST COMPOSITION FOR THE OXIDATION OF ETHYLENE TO ETHYLENE OXIDE WHICH COMPRISES SILVER CATALYST AND, AS A MODERATOR, AT LEAST ONE RARE EARTH METAL SELECTED FROM THE GROUP CONSISTING OF PRASEODYMIUM, NEODYMIUM, TERBIUM AND DYSPROSIUM WHICH IS PREPARED BY COATING A CARRIER WITH A SLURRIED SOLUTION WHICH CONTAINS REDUCED SILVER IN THE FORM OF SILVER POWDER AND A SALT OF AT LEAST ONE RARE EARTH METAL SELECTED FROM THE GROUP CONSISTING OF PRASODYMIUM, NEODYMIUM, TERBIUM AND DYSPROSIUM AND DRYING THE COATED CARRIER, WHEREIN SAID REDUCED SILVER IS PREPARED AS SILVER POWDER BY THE CHEMICAL REACTION OF SILVER OXIDE IN AN AQUEOUS SOLUTION, AND WHEREIN THE REDUCED SILVER AND THE SALT OF THE RARE EARTH METAL ARE PREVIOUSLY COMBINED BY IMMERSING THE REDUCED SILVER INTO AN AQUEOUS SOLUTION OF A SOLUBLE SALT OF SAID RARE EARTHMETAL, ADDING THERETO AN AQUEOUS SOLUTION OF ALKAL OR ALKALINE EARTH HYDROXIDE THEREBY CONVERTING SAID SOLUBLE SALT OF SAID RARE EARTH METAL INTO THE INSOLUBLE HYDROXIDE AND PRECIPITATING SAID INSOLUBLE HYDROXIDE ON THE REDUCED SILVER, FILTERING OFF THE COMBINED REDUCED SILVER AND PRECIPITATED RARE EARTH METAL HYDROXIDE, AND WASHIING THEM WITH WATER.
Claim 2
Dependent Claim
187 words
A CATALYST COMPOSITION FOR THE OXIDATION OF ETHYLENE TO ETHYLENE OXIDE WHICH COMPRISES SILVER CATALYST AND, AS A MODERATOR, AT LEAST ONE RARE EARTH METAL SELECTED FROM THE GROUP CONSISTING OF PRASEODYMIUM, NEODYMIUM, TERBIUM AND DYSPROSIUM WHICH IS PREPARED BY COATING A CARRIER WITH A SLURRIED SOLUTION WHICH CONTAINS REDUCED SILVER IN THE FORM OF SILVER POWDER AND A SALT OF AT LEAST ONE RARE EARTH METAL SELECTED FROM THE GROUP CONSISTING OF PRASODYMIUM, NEODYMIUM, TERBIUM AND DYSPROSIUM AND DRYING THE COATED CARRIER, WHEREIN SAID REDUCED SILVER IS PREPARED AS SILVER POWDER BY THE CHEMICAL REACTION OF SILVER OXIDE IN AN AQUEOUS SOLUTION, AND WHEREIN THE REDUCED SILVER AND THE SALT OF THE RARE EARTH METAL ARE PREVIOUSLY COMBINED BY IMMERSING THE REDUCED SILVER INTO AN AQUEOUS SOLUTION OF A SOLUBLE SALT OF SAID RARE EARTHMETAL, ADDING THERETO AN AQUEOUS SOLUTION OF ALKAL OR ALKALINE EARTH HYDROXIDE THEREBY CONVERTING SAID SOLUBLE SALT OF SAID RARE EARTH METAL INTO THE INSOLUBLE HYDROXIDE AND PRECIPITATING SAID INSOLUBLE HYDROXIDE ON THE REDUCED SILVER, FILTERING OFF THE COMBINED REDUCED SILVER AND PRECIPITATED RARE EARTH METAL HYDROXIDE, AND WASHIING THEM WITH WATER.
Claim 3
Dependent Claim
28 words
A catalyst composition as claimed in claim 1 wherein the amount of the moderator is from 0.001 to about 5.0 atomic % on the basis of silver atoms.
Claim 4
Dependent Claim
27 words
A catalyst composition as claimed in claim 1 wherein the amount of the moderator is from 0.01 to 1.0 atomic % on the basis of silver atoms.
Claim 5
Dependent Claim
25 words
A catalyst composition as claimed in claim 1, wherein the reduced silver is prepared by the reduction of silver oxide with formalin in alkaline solution.
Claim 6
Dependent Claim
19 words
A catalyst composition as claimed in claim 1, wherein the soluble salt of the rare earth metal is chloride.
Claim 7
Dependent Claim
19 words
A catalyst composition as claimed in claim 1, wherein the soluble salt of the rare earth metal is nitrate.
Claim 8
Dependent Claim
19 words
A catalyst composition, as claimed in claim 1, wherein the soluble salt of the rare earth metal is lactate.
Claim 9
Dependent Claim
16 words
A catalyst composition, as claimed in claim 1, wherein the alkali metal hydroxide is sodium hydroxide.
Claim 10
Dependent Claim
16 words
A catalyst composition, as claimed in claim 1, wherein the alkali metal hydroxide is lithium hydroxide.
Claim 11
Dependent Claim
16 words
A catalyst composition, as claimed in claim 1, wherein the alkali metal hydroxide is potassium hydroxide.
Claim 12
Dependent Claim
17 words
A catalyst composition, as claimed in claim 1, wherein the alkaline earth metal hydroxide is barium hydroxide.
Claim 13
Dependent Claim
22 words
A catalyst composition, as claimed in claim 1, wherein the slurried solution further contains a salt of alkali or alkaline earth metal.
Claim 14
Dependent Claim
18 words
A catalyst composition, as claimed in claim 12, wherein the salt of alkaline earth metal is barium nitrate.
Claim 15
Dependent Claim
18 words
A catalyst composition, as claimed in claim 12, wherein the salt of alkaline earth metal is barium lactate.
Claim 16
Dependent Claim
18 words
A catalyst composition, as claimed in claim 12, wherein the salt of alkaline earth metal is calcium nitrate.
Claim 17
Dependent Claim
18 words
A catalyst composition, as claimed in claim 12, wherein the salt of alkaline earth metal is calcium lactate.
Claim 18
Dependent Claim
14 words
A catalyst composition, as claimed in claim 1, wherein the slurried solution is aqueous.
References Cited (Backward Citations)
USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1978-08-11 | 1979-02-10 | 1979-08-12 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1982-08-11 | 1983-02-10 | 1983-08-12 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1986-08-11 | 1987-02-10 | 1987-08-12 | $7700.00 | Window Closed / Lapsed |