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US3899400A Expired / Lapsed US ⏱️ 0.0 years remaining

Surface treatment of aluminum and its alloys

Assignee: Produits Chimiques Ugine Kuhlmann
•
Filing: 1974-07-09
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Granted: 1975-08-12
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Expires: 1994-07-09
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Abstract

Abstract The surface of a piece of aluminum or aluminum alloy is decorated with a novel ''''lizardskin'''' appearance by passing an alternating electrolytic current at 5 to 50 volts between said piece used as an electrode, and a second electrode, both electrodes being submerged in an aqueous electrolyte bath containing 0.1 to 20 grams/liter of a suitable acid and 0.1 to 20 grams/liter of a polyfluorinated sulfonate surfactant.

Inventors

  • 👤 Jos Patrie
  • 👤 Jacques Lefebvre
  • 👤 Francois Allegret

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-24 15:24
CPC Classifications
C; C25; C25F; C25F3/00; C25F3/02; C25F3/04

Claims Analysis

Total Claims: 9
Claim 1
Independent Claim 75 words
A METHOD OF DECORATING THE SURFACE OF A PIECE OF ALUMINUM OR ALUMINUM ALLOY WITH A "LIZARDSKIN" APPEARANCE, WHICH METHOD COMPRISES PLACING SAID PIECE AS ONE ELECTRODE TOGETHER WITH A SECOND ELECTRODE IN AN AQUEOUS ELECTROLYTIC BATH AT ABOUT 5*-60*C AND CONTAINING FROM ABOUT 0.1 TO 20 GRAMS/LITER OF HYDROCHLORIDE ACID, NITRIC ACID, BORIC ACID OR FLUOROBORIC ACID AND FROM ABOUT 0.1 TO 20 GRAMS/LITER OF A POLYFLUORINATED SULFONATE SULFACTANT, AND PASSING AN ALTERNATING ELECTROLYTIC
Claim 2
Independent Claim 75 words
A METHOD OF DECORATING THE SURFACE OF A PIECE OF ALUMINUM OR ALUMINUM ALLOY WITH A "LIZARDSKIN" APPEARANCE, WHICH METHOD COMPRISES PLACING SAID PIECE AS ONE ELECTRODE TOGETHER WITH A SECOND ELECTRODE IN AN AQUEOUS ELECTROLYTIC BATH AT ABOUT 5*-60*C AND CONTAINING FROM ABOUT 0.1 TO 20 GRAMS/LITER OF HYDROCHLORIDE ACID, NITRIC ACID, BORIC ACID OR FLUOROBORIC ACID AND FROM ABOUT 0.1 TO 20 GRAMS/LITER OF A POLYFLUORINATED SULFONATE SULFACTANT, AND PASSING AN ALTERNATING ELECTROLYTIC
Claim 3
Dependent Claim 35 words
The method of claim 1 wherein the polyfluorinated sulfonate surfactant is CnF2n 1(CH2)bSO3Q, wherein n is 4 to 14, b is 2 or 4, and Q is H or any cation forming a water-soluble salt.
Claim 4
Dependent Claim 12 words
The method of claim 2 wherein the surfactant is 2-(tridecafluoro-n-hexyl)-ethyl sulfonic acid.
Claim 5
Dependent Claim 13 words
The method of claim 1 wherein the second electrode is an inert material.
Claim 6
Dependent Claim 31 words
The method of claim 1 wherein the second electrode also is a piece of aluminum or aluminum alloy, whereby the opposite surfaces of both electrodes are decorated with the lizardskin appearance.
Claim 7
Dependent Claim 21 words
The method of claim 1 wherein the lizardskin surface is subsequently protected by anodization or the application of a clear varnish.
Claim 8
Dependent Claim 12 words
The method of claim 1 wherein the lizardskin surface is subsequently colored.
Claim 9
Dependent Claim 17 words
A piece of aluminum or aluminum alloy whose surface is decorated by the method of claim 1.

References Cited (Backward Citations)

US2750337A Cited
US2871425A Cited
US2941930A Cited
US3073765A Cited
US3755116A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1978-08-11 1979-02-10 1979-08-12 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1982-08-11 1983-02-10 1983-08-12 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1986-08-11 1987-02-10 1987-08-12 $7700.00 Window Closed / Lapsed

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