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US3899360A Expired / Lapsed US ⏱️ 0.0 years remaining

Stabilized p-type lead telluride

Assignee: General Electric Co
•
Filing: 1971-03-01
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Granted: 1975-08-12
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Expires: 1991-03-01
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Abstract

Abstract It is disclosed that when power generating thermopiles comprised of lead telluride thermoelements are operated at temperatures above about 400*C, the metal electrodes in contact with the ends of the thermoelements tend to diffuse into the lead telluride. The metals used for the electrodes are n-type dopants and degrade the properties of the p-type thermoelements. Manganese telluride has a low solid solubility limit in lead telluride. By saturating the p-type lead telluride with manganese telluride, the diffusion of the electrode material into the lead telluride is substantially eliminated without materially reducing the electrical properties.

Inventors

  • 👤 James H Bredt
  • 👤 Jr Louis F Kendall

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-03 18:31
CPC Classifications
H; H10; H10N; H10N10/00; H10N10/80; H10N10/85; H10N10/851; H10N10/852

Claims Analysis

Total Claims: 3
Claim 1
Independent Claim 76 words
A THEMOELECTRIC GENERATOR COMPONENT FOR OPERATION AT A SELECTED TEMPERATURE ABOVE 400*C COMPRISING A SEMICONDUCTING THERMOELEMENT AND A METAL ELECTRODE IN INTIMATE ELECTRICAL CONTACT WITH THE THERMOELEMENT, SAID ELECTRODE BEING OF A METAL SELECTED FROM THE GROUP CONSISTING OF IRON AND IRON-BASE ALLOYS, AND SAID THERMOELEMENT CONSISTING ESSENTIALLY OF A SOLID SOLUTION OF A RELATIVELY SMALL AMOUNT OF MANGANESE TELLURIDE IN P-TYPE LEAD TELLURIDE WHICH SOLID SOLUTION IS SATURATED AT THE SELECTED OPERATING TEMPERATURE ABOVE 400*C.
Claim 2
Dependent Claim 76 words
A THEMOELECTRIC GENERATOR COMPONENT FOR OPERATION AT A SELECTED TEMPERATURE ABOVE 400*C COMPRISING A SEMICONDUCTING THERMOELEMENT AND A METAL ELECTRODE IN INTIMATE ELECTRICAL CONTACT WITH THE THERMOELEMENT, SAID ELECTRODE BEING OF A METAL SELECTED FROM THE GROUP CONSISTING OF IRON AND IRON-BASE ALLOYS, AND SAID THERMOELEMENT CONSISTING ESSENTIALLY OF A SOLID SOLUTION OF A RELATIVELY SMALL AMOUNT OF MANGANESE TELLURIDE IN P-TYPE LEAD TELLURIDE WHICH SOLID SOLUTION IS SATURATED AT THE SELECTED OPERATING TEMPERATURE ABOVE 400*C.
Claim 3
Dependent Claim 52 words
The thermoelectric generator component of claim 1 in which the selected operating temperature is about 600*C and the manganese telluride content of the semiconducting lead telluride thermoelement is about 4 mol per cent and the solid solution of manganese telluride in p-type lead telluRide is saturated at the said selected operating temperature.

References Cited (Backward Citations)

US2811569A Cited
US3403133A Cited
US3285019A Cited
US3480554A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1978-08-11 1979-02-10 1979-08-12 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1982-08-11 1983-02-10 1983-08-12 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1986-08-11 1987-02-10 1987-08-12 $7700.00 Window Closed / Lapsed

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