US3898155A
Expired / Lapsed
US
⏱️ 0.0 years remaining
Heavy oil demetallization and desulfurization process
Assignee: Chevron USA Inc
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Filing: 1973-12-19
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Granted: 1975-08-05
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Expires: 1993-12-19
Abstract
Abstract Heavy oils containing sulfur and at least 80 parts per million metals are simultaneously demetallized and desulfurized by contacting the oil under hydrogenation conditions with a catalyst composition comprising a Group VI-B metal and at least one Group VIII metal composited with alumina, said catalyst composition having an average pore diameter greater than 100 A units, from 10-40 percent of the total pore volume in macropores and from 6090 percent of the total pore volume in micropores, and at least 80 percent of the micropore volume being in pores having a diameter of at least 100 A units.
Inventors
- 👤 Geoffrey R Wilson
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-10-25 05:44
CPC Classifications
B; B01; B01J; B01J35/00; B01J35/60; B01J23/00; B01J23/70; B01J23/76; B01J23/84; B01J23/85; B01J35/61; B01J35/615; B01J35/63; B01J35/635; B01J35/64; B01J35/647; B01J35/651; B01J35/66; B01J35/69; C; C10; C10G; C10G2300/00; C10G2300/10; C10G2300/107
Claims Analysis
Total Claims: 7
Claim 1
Independent Claim
226 words
A PROCESS WHICH COMPRISES CONTACTING A HEAVY OIL HAVING AT LEAST 1.0 WEIGHT PERCENT SULFUR WHICH ALSO CONTAINS AT LEAST 50 PPM METALS WITH HYDROGEN AND WITH A CATALYST COMPOSITE AT A HYDROGEN PARTICLE PARTIAL PRESSURE IN THE RANGE OF 500 TO 3, AND AT A TEMPERATURE IN THE RANGE OF 600* TO 900*F, SAID CATALYST CONSISTING ESSENTIALLY OF A GROUP V1-B METAL AND AT LEAST ONE GROUP V111 METAL COMPOSITED WITH ALUMINA, SAID CATALYST HAVING FROM 10 TO 40 PERCENT OF THE TOTAL PORE VOLUME IN MACROPORES HAVING A PORE DIAMETER GREATER THAN 600 A UNITS, FROM 60 TO 90 PERCENT OF THE TOTAL OF PORE VOLUME BEING IN MICROPORES, AT LEAST 80 PERCENT OF THE MICROPORE VOLUME BEING IN PORES HAVING A DIAMETER OF AT LEAST 100 A UNITS, THE TOTAL PORE VOLUME OF SAID CATALYST BEING AT LEAST 0.5 MILLILITER PER GRAM, THE AVERAGE PORE DIAMETER OF SAID CATALYST BEING GREATER THAN 100 A UNITS, AND THE SURFACE AREA OF SAID CATALYST BEING AT LEAST 100 SQUARE METERS PER GRAM, THE CONCENTRATION OF THE GROUP V1 METAL EING IN THE RANGE FROM 5 TO 40 WEIGHT PERCENT OF SAID CATALYST COMPOSITE AND THE CONCENTRATION OF EACH GROUP V111 METAL BEING IN THE RANGE OF 0.01 TO 15 WEIGHT PERCENT OF SAID CATALYST COMPOSITE, AND RECOVERING THEREFROM A DEMETALLIZED AND DESULFURIZED HEAVY OIL PRODUCT.
Claim 2
Dependent Claim
226 words
A PROCESS WHICH COMPRISES CONTACTING A HEAVY OIL HAVING AT LEAST 1.0 WEIGHT PERCENT SULFUR WHICH ALSO CONTAINS AT LEAST 50 PPM METALS WITH HYDROGEN AND WITH A CATALYST COMPOSITE AT A HYDROGEN PARTICLE PARTIAL PRESSURE IN THE RANGE OF 500 TO 3, AND AT A TEMPERATURE IN THE RANGE OF 600* TO 900*F, SAID CATALYST CONSISTING ESSENTIALLY OF A GROUP V1-B METAL AND AT LEAST ONE GROUP V111 METAL COMPOSITED WITH ALUMINA, SAID CATALYST HAVING FROM 10 TO 40 PERCENT OF THE TOTAL PORE VOLUME IN MACROPORES HAVING A PORE DIAMETER GREATER THAN 600 A UNITS, FROM 60 TO 90 PERCENT OF THE TOTAL OF PORE VOLUME BEING IN MICROPORES, AT LEAST 80 PERCENT OF THE MICROPORE VOLUME BEING IN PORES HAVING A DIAMETER OF AT LEAST 100 A UNITS, THE TOTAL PORE VOLUME OF SAID CATALYST BEING AT LEAST 0.5 MILLILITER PER GRAM, THE AVERAGE PORE DIAMETER OF SAID CATALYST BEING GREATER THAN 100 A UNITS, AND THE SURFACE AREA OF SAID CATALYST BEING AT LEAST 100 SQUARE METERS PER GRAM, THE CONCENTRATION OF THE GROUP V1 METAL EING IN THE RANGE FROM 5 TO 40 WEIGHT PERCENT OF SAID CATALYST COMPOSITE AND THE CONCENTRATION OF EACH GROUP V111 METAL BEING IN THE RANGE OF 0.01 TO 15 WEIGHT PERCENT OF SAID CATALYST COMPOSITE, AND RECOVERING THEREFROM A DEMETALLIZED AND DESULFURIZED HEAVY OIL PRODUCT.
Claim 3
Dependent Claim
62 words
The process of claim 1 wherein said catalyst has from 15 to 40 percent of said total pore volume in macropores, from 60 to 85 percent of said total pore volume in micropores, said total pore volume of said catalyst being at least 0.7 milliliter per gram, and the surface area of said catalyst being at least 150 square meters per gram.
Claim 4
Dependent Claim
48 words
The process of claim 1 which includes a hydrogen gas circulation rate in the range of 2,000 to 10,000 standard cubic feet per barrel of said oil, and a space velocity in the range of 0.1 to 5.0 liquid volumes of oil per volume of catalyst per hour.
Claim 5
Dependent Claim
32 words
The process of claim 1 wherein said catalyst also includes from 0.1 to 5.0 weight percent of a metal selected from the group consisting of Group I, Group II and Group IV-B.
Claim 6
Dependent Claim
14 words
The process of claim 3 wherein said catalyst comprises nickel, cobalt, molybdenum and alumina.
Claim 7
Dependent Claim
11 words
The process of claim 5 wherein said catalyst also includes titanium.
References Cited (Backward Citations)
USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1978-08-04 | 1979-02-03 | 1979-08-05 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1982-08-04 | 1983-02-03 | 1983-08-05 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1986-08-04 | 1987-02-03 | 1987-08-05 | $7700.00 | Window Closed / Lapsed |