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US3898153A Expired / Lapsed US ⏱️ 0.0 years remaining

Catalytic reforming process with sulfur removal

Assignee: Sunoco Inc R&M
•
Filing: 1973-11-23
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Granted: 1975-08-05
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Expires: 1993-11-23
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Abstract

Abstract An improved catalytic reformer system wherein chloride compounds are removed from the feed, sulfur compounds contained in the total feed are converted to H2S in a hydrodesulfurization zone and the H2S is removed in an adsorbing zone containing a solid adsorbent.

Inventors

  • 👤 Kenneth E Louder
  • 👤 William A Ackerman
  • 👤 Irene F Kress

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-27 16:05
CPC Classifications
C; C10; C10G; C10G45/00; C10G45/02; C10G45/04; C10G2400/00; C10G2400/02

Claims Analysis

Total Claims: 7
Claim 1
Independent Claim 117 words
A PROCESS FOR CATALYTICALLY REFORMING A NAPHTA FEED STREAM CONTAINING SULFUR AND CHLORIDE COMPOUNDS IN THE PRESSENCE OF HYDROGEN WHICH COMPRISES A. PASSING THE FEED AND A HYDROGEN RECYCLE THROUGH A CHLORIDE REMOVAL ZONE, B. PASSING THE CHLORIDE FREE FEED AND HYDROGEN RECYCLE THROUGH A HYDRODESULFURIZATION ZONE WHEREIN THE SULFUR IS CONVERTED TO H2S AND A PACKED BED GRANULAR ZINZ OXIDE ABSORBENT WHEREIN THE H2S IS ADSORBED, C. PASSING SAID DESULFURIZED FEED THROUGH A CATAYTIC REFORMING ZONE UNDER REFORMING CONDITIONS WHEREIN REFORMING OF NAPHTHAS AND CONVERSION OF SULFUR COMPOUNDS TO H2S TAKES PLACE, D. WITHDRAWING FROM STEP (C) A GASEOUS STREAM TO BE RECYCLED TO STEP (A), AND E. WITHDRAWING A REFORMED NAPHTHA PRODUCT FROM STEP (C).
Claim 2
Dependent Claim 117 words
A PROCESS FOR CATALYTICALLY REFORMING A NAPHTA FEED STREAM CONTAINING SULFUR AND CHLORIDE COMPOUNDS IN THE PRESSENCE OF HYDROGEN WHICH COMPRISES A. PASSING THE FEED AND A HYDROGEN RECYCLE THROUGH A CHLORIDE REMOVAL ZONE, B. PASSING THE CHLORIDE FREE FEED AND HYDROGEN RECYCLE THROUGH A HYDRODESULFURIZATION ZONE WHEREIN THE SULFUR IS CONVERTED TO H2S AND A PACKED BED GRANULAR ZINZ OXIDE ABSORBENT WHEREIN THE H2S IS ADSORBED, C. PASSING SAID DESULFURIZED FEED THROUGH A CATAYTIC REFORMING ZONE UNDER REFORMING CONDITIONS WHEREIN REFORMING OF NAPHTHAS AND CONVERSION OF SULFUR COMPOUNDS TO H2S TAKES PLACE, D. WITHDRAWING FROM STEP (C) A GASEOUS STREAM TO BE RECYCLED TO STEP (A), AND E. WITHDRAWING A REFORMED NAPHTHA PRODUCT FROM STEP (C).
Claim 3
Dependent Claim 37 words
The process of claim 1 wherein said catalytic reforming utilizes catalyst selected from the group consisting of platinum on alumina, platinum and rhenium on alumina, platinum and iridium on alumina and platinum, rhenium and iridium on alumina.
Claim 4
Dependent Claim 25 words
The process of claim 2 wherein the hydrodesulfurization step utilizes a catalyst selected from the group consisting of cobalt-molybdenum on alumina and nickel-molybdenum on alumina.
Claim 5
Dependent Claim 31 words
The process of claim 3 wherein said chloride removal zone is a guard case containing a catalyst selected from the group consisting of copper on alumina and copper oxide on alumina.
Claim 6
Dependent Claim 20 words
The process of claim 4 wherein said adsorption takes place at a temperature in the range of 550* to 850*F.
Claim 7
Dependent Claim 67 words
The process of claim 5 wherein the reforming catalyst is selected from the group consisting of platinum on alumina, platinum and rhenium on alumina, platinum and iridium on alumina and platinum, rhenium and iridium on alumina, the adsorbent is zinc oxide and the chloride removal zone is a guard case containing a catalyst selected from the group consisting of copper on alumina and copper oxide on alumina.

References Cited (Backward Citations)

US2522065A Cited
US2769761A Cited
US2772212A Cited
US2856347A Cited
US2959538A Cited
US2967819A Cited
US3306841A Cited
US3574091A Cited
US3649524A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1978-08-04 1979-02-03 1979-08-05 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1982-08-04 1983-02-03 1983-08-05 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1986-08-04 1987-02-03 1987-08-05 $7700.00 Window Closed / Lapsed

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