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US3897275A Expired / Lapsed US ⏱️ 0.0 years remaining

Process for fabricating schottky barrier phototransistor

Assignee: Texas Instruments Inc
•
Filing: 1973-05-11
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Granted: 1975-07-29
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Expires: 1993-05-11
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Abstract

Abstract Disclosed is a phototransistor comprised of an indium arsenide n-type semiconductor substrate, a thin, relatively lightly doped p-type cadmium diffused region in the substrate forming a photosensitive diode junction, and a metal film in rectifying contact with the p-type diffused region to form a Schottky barrier. The method for fabricating the transistor comprises producing the shallow cadmium diffusion, etching the surface of the diffused region to a predetermined depth to reduce the doping level and the surface oxide level, and depositing the metal film on the etched surface of the diffused region.

Inventors

  • 👤 Sebastian R Borrelo
  • 👤 Jimmy D Sawyer

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-05 23:21
CPC Classifications
H; H10; H10F; H10F30/00; H10F30/20; H10F30/21; H10F30/24; H10F30/245; H10F99/00; H10F71/00; Y; Y10; Y10S; Y10S148/00; Y10S148/051; Y10S148/065

Claims Analysis

Total Claims: 19
Claim 1
Independent Claim 131 words
IN A PROCESS FOR FABRICATING A PHOTOTRANSISTOR, THE STEPS COMPRISING: DIFFUSING A P-TYPE IMPURITY INTO A PREDETERMINED AREA OF A SUBSTRATE OF III-V COMPOUND SEMICONDUCTOR MATERIAL OF N-TYPE TO FORM A P-TYPE REGION IN SAID N-TYPE SUBSTRATE SUCH THAT A PHOTOSENSITIVE DIODE JUNCTION IS PROVIDED BETWEEN THE P-TYPE REGION AND THE N-TYPE SUBSTRATE, REMOVING AT LEAST A PORTION OF THE SUBSTRATE IN SAID PREDETERMINED AREA COMPRISING THE P-TYPE REGION TO REMOVE SURFACE OXIDES THEREFROM AND TO REDUCE THE LEVEL OF P-TYPE IMPURITY CONCENTRATION BY EXPOSING THE P-TYPE RGION AT A DEPTH HAVING, A SUFFICIENTLY LOW IMPURITY CONCENTRATION FOR SUBSEQUENT FORMATION OF A RECTIFYING CONTACT WITH A METAL FILM TO BE DEPOSITED THEREON, AND DEPOSITING A METAL FILM ON SAID EXPOSED PORTION OF SAID P-TYPE REGION TO PRODUCE A RECTIFYING JUNCTION THEREWITH.
Claim 2
Dependent Claim 131 words
IN A PROCESS FOR FABRICATING A PHOTOTRANSISTOR, THE STEPS COMPRISING: DIFFUSING A P-TYPE IMPURITY INTO A PREDETERMINED AREA OF A SUBSTRATE OF III-V COMPOUND SEMICONDUCTOR MATERIAL OF N-TYPE TO FORM A P-TYPE REGION IN SAID N-TYPE SUBSTRATE SUCH THAT A PHOTOSENSITIVE DIODE JUNCTION IS PROVIDED BETWEEN THE P-TYPE REGION AND THE N-TYPE SUBSTRATE, REMOVING AT LEAST A PORTION OF THE SUBSTRATE IN SAID PREDETERMINED AREA COMPRISING THE P-TYPE REGION TO REMOVE SURFACE OXIDES THEREFROM AND TO REDUCE THE LEVEL OF P-TYPE IMPURITY CONCENTRATION BY EXPOSING THE P-TYPE RGION AT A DEPTH HAVING, A SUFFICIENTLY LOW IMPURITY CONCENTRATION FOR SUBSEQUENT FORMATION OF A RECTIFYING CONTACT WITH A METAL FILM TO BE DEPOSITED THEREON, AND DEPOSITING A METAL FILM ON SAID EXPOSED PORTION OF SAID P-TYPE REGION TO PRODUCE A RECTIFYING JUNCTION THEREWITH.
Claim 3
Dependent Claim 31 words
A process as set forth in claim 1, wherein the removal of at least a portion of the substrate in said predetermined area comprising the p-type region is accomplished by etching.
Claim 4
Dependent Claim 47 words
A process as set forth in claim 1, further including placing the substrate after deposit of said metal film on said exposed portion of said p-type region in a reducing atmosphere to reduce any oxide formed at the junction between said metal film and said p-type region.
Claim 5
Dependent Claim 28 words
The process defined in claim 1 wherein the p-type impurity is diffused from the vapor stage using a two zone process to produce an error function diffusion profile.
Claim 6
Dependent Claim 32 words
A process as set forth in claim 1, wherein the substrate of III-V compound semiconductor material of n-type is selected from the group consisting of indium arsenide, indium antimonide and gallium antimonide.
Claim 7
Dependent Claim 15 words
A process as set forth in claim 5, wherein said substrate is n-type indium arsenide.
Claim 8
Dependent Claim 31 words
A process as set forth in claim 5, wherein said p-type impurity diffused into said predetermined area of said substrate is selected from the group consisting of cadmium, zinc and magnesium.
Claim 9
Dependent Claim 14 words
A process as set forth in claim 7, wherein said p-type impurity is cadmium.
Claim 10
Dependent Claim 187 words
A process for fabricating a phototransistor comprising the steps of: selectively diffusing a p-type impurity into a predetermined area of an n-type substrate of III-V compound semiconductor material to form a p-type region in said n-type substrate such that a photosensitive diode junction is provided between said p-type region and said n-type substrate, removing at least a portion of said substrate in said predetermined area comprising the p-type region to remove surface oxides therefrom and to reduce the level of p-type impurity concentration by exposing the p-type region at a depth having a sufficiently low impurity concentration enabling said p-type region to be capable of producing a rectifying junction with a metal film to be deposited thereon, and depositing a patterned metal film on said exposed portion of said p-type region and on the surface of said n-type substrate at a position spaced from said p-type region so as to simultAneously produce a rectifying junction between said exposed portion of the p-type region and said metal film and an ohmic contact between said substrate surface and said metal film at the position spaced from said p-type region.
Claim 11
Dependent Claim 187 words
A process for fabricating a phototransistor comprising the steps of: selectively diffusing a p-type impurity into a predetermined area of an n-type substrate of III-V compound semiconductor material to form a p-type region in said n-type substrate such that a photosensitive diode junction is provided between said p-type region and said n-type substrate, removing at least a portion of said substrate in said predetermined area comprising the p-type region to remove surface oxides therefrom and to reduce the level of p-type impurity concentration by exposing the p-type region at a depth having a sufficiently low impurity concentration enabling said p-type region to be capable of producing a rectifying junction with a metal film to be deposited thereon, and depositing a patterned metal film on said exposed portion of said p-type region and on the surface of said n-type substrate at a position spaced from said p-type region so as to simultAneously produce a rectifying junction between said exposed portion of the p-type region and said metal film and an ohmic contact between said substrate surface and said metal film at the position spaced from said p-type region.
Claim 12
Dependent Claim 31 words
A process as set forth in claim 9, wherein the removal of at least a portion of the substrate in said predetermined area comprising the p-type region is accomplished by etching.
Claim 13
Dependent Claim 179 words
A process for fabricating a phototransistor comprising the steps of: providing a substrate of n-type indium arsenide material, placing said substrate and a p-type impurity consisting of cadmium into an evacuated chamber, heating said substrate to a first temperature and said cadmium to a second temperature lower than said first temperature within said evacuated chamber to diffuse said cadmium into a predetermined area of said substrate to form a p-type region therein such that a photosensitive diode junction is provided between the p-type region and said substrate having an error function diffusion profile, removing at least a portion of said substrate in said predetermined area comprising said p-type region to remove surface oxides therefrom and to reduce the level of p-type impurity concentration by exposing the p-type region at a depth having a sufficiently low impurity concentration within said error function diffusion profile to enable said p-type region to produce a rectifying junction with a metal film to be deposited thereon, and depositing a metal film on said exposed portion of the p-type region to produce a rectifying junction.
Claim 14
Dependent Claim 179 words
A process for fabricating a phototransistor comprising the steps of: providing a substrate of n-type indium arsenide material, placing said substrate and a p-type impurity consisting of cadmium into an evacuated chamber, heating said substrate to a first temperature and said cadmium to a second temperature lower than said first temperature within said evacuated chamber to diffuse said cadmium into a predetermined area of said substrate to form a p-type region therein such that a photosensitive diode junction is provided between the p-type region and said substrate having an error function diffusion profile, removing at least a portion of said substrate in said predetermined area comprising said p-type region to remove surface oxides therefrom and to reduce the level of p-type impurity concentration by exposing the p-type region at a depth having a sufficiently low impurity concentration within said error function diffusion profile to enable said p-type region to produce a rectifying junction with a metal film to be deposited thereon, and depositing a metal film on said exposed portion of the p-type region to produce a rectifying junction.
Claim 15
Dependent Claim 75 words
A process as set forth in claim 11, wherein said metal film is simultaneously deposited on said exposed portion of said p-type region and on the surface of said substrate at a position spaced from said p-type region to produce said rectifying junction between said exposed portion of said p-type region and said metal film and an ohmic contact between said substrate surface and said metal film at the position spaced from said p-type region.
Claim 16
Dependent Claim 36 words
A process as set forth in claim 11, wherein said portion of said substrate in said predetermined area comprising said p-type region is removed until the final thickness of said p-type region is approximately 10 microns.
Claim 17
Dependent Claim 42 words
A process as set forth in claim 11, wherein said substrate and said cadmium are subjected to heating at said first and second temperatures respectively until said p-type region has a surface concentration of about 8 X 1016 atoms per cubic centimeter.
Claim 18
Dependent Claim 29 words
A process as set forth in claim 11, wherein said metal film is deposited on said exposed portion of said p-type region to a thickness of approximately 5,000 angstroms.
Claim 19
Dependent Claim 32 words
A process as set forth in claim 11, wherein said substrate is heated to a first temperature of approximately 650*C and said cadmium is heated to a second temperature of approximately 600*C.

References Cited (Backward Citations)

US3018539A Cited
US3309553A Cited
US3436549A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1978-07-28 1979-01-27 1979-07-29 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1982-07-28 1983-01-27 1983-07-29 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1986-07-28 1987-01-27 1987-07-29 $7700.00 Window Closed / Lapsed

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